What absorbs at 862 cm⁻¹ in an FTIR spectrum?
A band near 862 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Resposta rápida
A band near 862 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Possíveis atribuições de grupos funcionais
| Grupo funcional | Fatos de suporte | Fontes citadas | Maior confiança |
|---|---|---|---|
| Methacrylate | 3 | 3 | 1,0 |
| C-O single bond | 3 | 3 | 1,0 |
| Acetate | 3 | 3 | 1,0 |
| Carbonate | 3 | 3 | 1,0 |
| Aromatic ring | 2 | 2 | 1,0 |
| Metal oxygen | 2 | 2 | 1,0 |
| Hydroxyl (O-H) | 2 | 2 | 1,0 |
| Methoxy (OCH3) | 2 | 2 | 1,0 |
| Amide | 2 | 2 | 1,0 |
| Borate | 1 | 1 | 1,0 |
| Alkyl C-H | 1 | 1 | 1,0 |
| Alkene (C=C) | 1 | 1 | 1,0 |
| Secondary amine | 1 | 1 | 1,0 |
| C n single bond | 1 | 1 | 1,0 |
| Hydrogen bond | 1 | 1 | 1,0 |
| Ketone | 1 | 1 | 1,0 |
| Ester | 1 | 1 | 1,0 |
| Carboxyl (COOH) | 1 | 1 | 1,0 |
| Carbonyl (C=O) | 1 | 1 | 1,0 |
A classificação reflete a evidência acumulada da literatura, não uma única regra autoritária. Sempre confirme com o contexto da sua amostra.
Materiais possíveis
| Material | Picos de suporte | Grupos sobrepostos | Fontes citadas |
|---|---|---|---|
| starch | 862, 1650, 1540 | Methacrylate, Acetate, C-O single bond | 1 |
| cotton fabric | 862, 900, 2000 | Methacrylate, Acetate, C-O single bond | 1 |
Os materiais são mostrados apenas quando o mesmo conjunto de literatura suporta esta banda e pelo menos um pico característico adicional.
Lógica do espectro
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 862 cm⁻¹ is usually not enough for material identification by itself.
Uso no mundo real
Este tipo de consulta é comum em identificação de polímeros, triagem de plásticos desconhecidos, solução de problemas de CQ, verificação de materiais reciclados e revisão de atribuição de picos apoiada pela literatura.
Erros comuns
- Tratar uma banda isolada como prova de um material sem verificar pelo menos um ou dois picos de suporte.
- Ignorando sobreposição: vários grupos funcionais podem contribuir próximo ao mesmo número de onda.
- Ignorar a validação quando aditivos, misturas, oxidação ou contaminação podem distorcer o espectro.
Conselho de verificação
Quando a ambiguidade persistir, valide a hipótese com DSC, GC-MS ou TGA, especialmente para misturas, amostras degradadas e polímeros carregados.
Literatura por trás destas atribuições
-
C-O single bond confiança 1,0
“LLM confirmed rule peak-group candidate”
Two potential uses for silver nanoparticles coated with Solanum nigrum unripe fruit extract: Biofilm inhibition and photodegradation of dye effluent DOI: 10.1016/j.micpath.2017.08.039 -
Metal oxygen confiança 1,0
“The absorption band at around 742 and strong cm-1 4]2band at 862 are attributed to the O-W-O stretches of the [WO tetrahedron, because the”
Abozaid 等 - 2018 - Characterization of Neodymium Doped Calcium Tungst DOI: 10.2298/SOS1804445A -
Acetate confiança 1,0
“at 862 and 879 Both bands could be assigned to C=O vibration in carbonate 879 cm-1.”
Impact of NaOH Concentration on Deweaving of Cotton Fabric in Aqueous Solutions DOI: 10.3390/su13042015 -
Acetate confiança 1,0
“cm-1 cm-1 stretching, 1485 to the CH bending of an alkyl group, 1150 to the C-O stretching 2 6 ACCEPTED MANUSCRIPT cm-1 C-N+ of an aliphatic ketone group, and 862 to a symmetric stretching.”
Delgado-Mellado 等 - 2018 - Thermal stability of choline chloride deep eutecti DOI: 10.1016/j.molliq.2018.03.076 -
Acetate confiança 1,0
“skeletal stretch glyceraldehyde, 860.83, 764.60, 930.25, 709.34 glucopyranoside OH, C=O stretch, OH bend, Citric acid L (-)-glyceraldehyde, Glycerol 3368.50, 2932.94, 2058.91, CH 2, OH bond scissoring, molecule substitution anhydrous phosph”
Influence of physical and chemical modifications on granule size frequency distribution, fourier transform infrared (FTIR) spectra and adsorption isotherms of starch from four yam (Dioscorea spp.) cultivars DOI: 10.1007/s13197-021-05200-7 -
Alkene (C=C) confiança 1,0
“The peaks at 862.12 cm-1 and 810.04 cm-1 correspond to =C-H during production and transportation.”
Evaluating the Effect of Hydrophobic Nanosilica on the Viscoelasticity Property of Asphalt and Asphalt Mixture DOI: 10.3390/ma11112328 -
confiança 1,0
“cm-1 strong yet narrow peak at 530.42 due to wellThe infrared spectrum of n-hexane fraction cm-1 defined absorption for the halogen-substituted of Inflorescence showed, 719.45 and 862.18 cm-1 cm-1 aromatic compound.”
Ishtiaq 等 - 2020 - Antioxidant potential and chemical characterizatio DOI: 10.1590/0001-3765202020190387 -
Borate confiança 1,0
“Therefore, the bands cm-1 appearing in the region 862-1155 were due to the vibrations of the B-O bond stretching of BO structural units, which were overlapped with phosphate bands [23].”
The Influence of CoO/P2O5 Substitutions on the Structural, Mechanical, and Radiation Shielding of Boro-Phosphate Glasses DOI: 10.3390/ma14216632
Tem um espectro com esta banda?
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