What absorbs at 1219 cm⁻¹ in an FTIR spectrum?
A band near 1219 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Quick answer
A band near 1219 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能的官能团归属
| 官能团 | 支持性事实 | 引用来源 | 最高置信度 |
|---|---|---|---|
| Methacrylate | 7 | 6 | 1.0 |
| Acetate | 7 | 6 | 1.0 |
| Methoxy (OCH3) | 6 | 5 | 1.0 |
| C-O single bond | 6 | 5 | 1.0 |
| Amide | 4 | 4 | 1.0 |
| Alkyl C-H | 3 | 3 | 1.0 |
| Carboxyl (COOH) | 3 | 3 | 1.0 |
| Secondary amine | 2 | 2 | 1.0 |
| C n single bond | 2 | 2 | 1.0 |
| Hydroxyl (O-H) | 2 | 2 | 1.0 |
| Ketone | 2 | 2 | 1.0 |
| Ester | 2 | 2 | 1.0 |
| Carbonyl (C=O) | 2 | 2 | 1.0 |
| Chlorine | 1 | 1 | 1.0 |
| C c single bond | 1 | 1 | 1.0 |
| S eq o | 1 | 1 | 1.0 |
| Aromatic ring | 1 | 1 | 1.0 |
| Ring structure | 1 | 1 | 1.0 |
| Sulfonyl | 1 | 1 | 0.9 |
排名反映了累积的文献证据，而非单一的权威规则。请始终对照您的样品背景进行确认。
Possible materials
| 材料 | 支持峰 | Overlapping groups | 引用来源 |
|---|---|---|---|
| TiO2 | 1219, 1700, 1093 | Methacrylate, Acetate, C-O single bond | 1 |
| kraft lignin | 1219, 1744, 1710 | Methacrylate, Acetate, Methoxy (OCH3) | 1 |
| PMMA | 1219, 1722, 1383 | Methacrylate, Acetate, Methoxy (OCH3) | 1 |
| ZnO nanoparticles | 1219, 1726, 1568 | Methacrylate, Acetate, C-O single bond | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1219 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
这些分配背后的文献
-
Acetate 置信度 1.0
“characteristics ester carbonyl C=O stretch vibration of PMMA was also appeared at 1766 cm-1, cm-1 The stretching modes were detected at 1219 and 703 assigned to C-O and C=O bonds, respectively.”
Carrier mechanism of ZnO nanoparticles-embedded PMMA nanocomposite organic bistable memory device DOI: 10.1016/j.solidstatesciences.2019.106046 -
置信度 1.0
“Bands depicting amide II were found at 1517, cm-1, 1586, 1514, and 1522 whereas amide III bands were registered at 1221, 1219, 1227, cm-1 and 1229 for all tested protocol extracts (P1, P2, P3, and P4 respectively) (Figure 3B).”
Comparison of Different Methods for Spongin-like Collagen Extraction from Marine Sponges (Chondrilla caribensis and Aplysina fulva): Physicochemical Properties and In Vitro Biological Analysis DOI: 10.3390/membranes11070522 -
Ring structure 置信度 1.0
“The former one (peak D) can be ing, bond at 1219 assigned to the ring vibrations is obascribed to the C=O bonds pertaining to carboxylic groups, served for samples EG and EG-3Ph reg but not for EG-3Ph.”
Regeneration of expanded graphite electrodes by joined electrochemical and ozone treatment in liquid phase DOI: 10.1007/s10008-018-4098-5 -
Amide 置信度 1.0
“Shore A hardness cm-1 (C-O (cis-) bending (rocking)), 1105 (aliphatic saturated cm-1 (C-N CvO Hardness of HMA7 was measured with a handheld Precision ether)), 1282 (secondary amide, III) + (carbocm-1 (C-N Instrument Shore A digital duromete”
Bhullar 等 - 2021 - Advanced spectroscopy, microscopy, diffraction and DOI: 10.1039/d0py01348j -
S eq o 置信度 1.0
“The absorptions at 1219, decreases, making the more tortuous path by ethanol due cm-1 1076, and 1020 were assigned to the sulfonic acid to inorganic phase presence and possible TiO particles”
Dutra Filho 等 - 2014 - Nanostructured Polyelectrolytes Based on SPEEKTiO DOI: 10.4322/polimeros.2014.069 -
Hydroxyl (O-H) 置信度 1.0
“rR@SrTiO rR@BaTiO (1900 to 900 In contrast, the FTIR spectra of 3-OH-A and 3cm-1, OH-A showed strong absorptions at 1219, 1141, and 1100 and at 1200 and 1091 respectively, due to the presence of H 2SO on the NP surface.”
Freimann 等 - 2023 - Nanoparticulate Perovskites for Photocatalytic Wat DOI: 10.3390/nano13142094 -
Acetate 置信度 1.0
“The peak cm-1 at 1219 could be assigned to the C-O stretching in the ether or alcohol groups [38].”
Analysis of Chemical Structure and Antibiofilm Properties of Exopolysaccharides from Lactiplantibacillus plantarum EIR/IF-1 Postbiotics DOI: 10.3390/microorganisms10112200 -
Acetate 置信度 1.0
“C-C, C=C (aromatic skeleton), stretching C-C, C=C (aromatic skeleton), stretching 1379 1379 - - 1396 1379 1379 - - 1396 - - - 1271 1270 1272 C-O (guaiacyl unit) stretching - - - 1271 1270 1272 C-O (guaiacyl unit) stretching - - - 1219 1221”
Activation of Magnesium Lignosulfonate and Kraft Lignin: Influence on the Properties of Phenolic Resin-Based Composites for Potential Applications in Abrasive Materials DOI: 10.3390/ijms18061224
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