What absorbs at 535 cm⁻¹ in an FTIR spectrum?
A band near 535 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
クイックアンサー
A band near 535 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能性のある官能基アサイン
| 官能基 | 裏付け事実 | 引用元 | 最高信頼度 |
|---|---|---|---|
| Metal oxygen | 4 | 4 | 1.0 |
| Methoxy (OCH3) | 2 | 2 | 1.0 |
| Methacrylate | 2 | 2 | 1.0 |
| C-O single bond | 2 | 2 | 1.0 |
| Acetate | 2 | 2 | 1.0 |
| Silicon (Si) | 2 | 2 | 1.0 |
| Ketone | 1 | 1 | 1.0 |
| Ester | 1 | 1 | 1.0 |
| Carboxyl (COOH) | 1 | 1 | 1.0 |
| Carbonyl (C=O) | 1 | 1 | 1.0 |
| Amide | 1 | 1 | 1.0 |
| Metal oxo | 1 | 1 | 1.0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 1.0 |
| Water (H2O) | 1 | 1 | 1.0 |
| Hydroxyl (O-H) | 1 | 0 | 1.0 |
| Protein | 1 | 0 | 1.0 |
ランキングは蓄積された文献証拠を反映しており、単一の権威あるルールではありません。常にサンプルのコンテキストと照合して確認してください。
可能性のある材料
| 素材 | 補助ピーク | 重複グループ | 引用元 |
|---|---|---|---|
| NiO | 535, 1006, 1450 | Metal oxygen, C-O single bond, Methoxy (OCH3) | 1 |
| nanotubes | 535, 1735, 1630 | Methacrylate, Methoxy (OCH3) | 1 |
同じ文献プールがこのバンドと少なくとも1つの追加の特性ピークをサポートする場合にのみ、材料が表示されます。
スペクトルロジック
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 535 cm⁻¹ is usually not enough for material identification by itself.
実使用例
この種のクエリは、ポリマー識別、未知のプラスチックスクリーニング、QCトラブルシューティング、リサイクル材料の検証、および文献に基づいたピーク帰属のレビューで一般的です。
よくある間違い
- 少なくとも1~2つの支持ピークを確認せずに、1つの孤立したバンドを材料の証拠として扱うこと。
- 重複を無視: 複数の官能基が同じ波数付近に寄与することがあります。
- 添加剤、ブレンド、酸化、または汚染がスペクトルを歪める可能性がある場合に検証を省略すること。
検証アドバイス
曖昧さが残る場合は、特にブレンド、劣化サンプル、充填ポリマーについて、DSC、GC-MS、またはTGAで仮説を検証してください。
これらのアサインの根拠となる文献
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Silicon (Si) 信頼度 1.0
“cm(cid:3)1 cm(cid:3)1 Al with the presence of two peaks at 535 and 462 assigned to 0.66(cid:1)0.05 8.24(cid:1)0.22 1.69(cid:1)0.07 disulfides Si iodo and brominated compounds and group, respectively this 0.49(cid:1)0.04”
El-Sayed 和 Ismail - 2022 - Physico-chemodiversity variation between the most DOI: 10.1016/j.heliyon.2022.e12457 -
Metal oxygen 信頼度 1.0
“The two peaks at 535 and 567 attributed to the opposing excursion of the external apical oxygen atoms of TiO octahedral.”
Fabrication of the flexible nanogenerator from BTO nanopowders on graphene coated PMMA substrates by sol-gel method DOI: 10.1016/j.matchemphys.2017.02.002 -
Metal oxygen 信頼度 1.0
“Fe-O This further characteristic IR bands of at ~ 535 and ~ 450 conforms the presence of iron oxide [21].”
Antibacterial and antiproliferation activity of green synthesized nanoparticles from rhizome extract of Alpinia galangal (L.) Wild DOI: 10.1016/j.inoche.2021.108854 -
Acetate 信頼度 1.0
“(ii) an AZA XPS O1s spectrum, which shows an intense band at 532 eV accompanied by a band of low intensity at 535 eV, associated with shows an intense band at 532 eV accompanied by a band of low intensity at 535 eV, associintense band at 53”
Photodegradation of Azathioprine in the Presence of Sodium Thiosulfate DOI: 10.3390/ijms23073975 -
Silicon (Si) 信頼度 1.0
“cm-1 The PAO "NLMK" sample also exhibited a triplet in the 540-500 region with cm-1, absorption maxima at 535, 514, and 504 corresponding to the strain vibrations of Si-O-Al and Si-O (SiO 4) [27,28,30].”
Identification of the Elemental Composition of Granulated Blast Furnace Slag by FTIR-Spectroscopy and Chemometrics DOI: 10.3390/pr10112166 -
Metal oxygen 信頼度 1.0
“The spectrum of pristine NVO contains a few pronounced bands associated with cm-1 cm-1) the vibrations of V-O bonds: symmetric and asymmetric stretching of V-O-V (535 and 740 and cm-1)30.”
New light on the photocatalytic performance of NH4V4O10 and its composite with rGO DOI: 10.1038/s41598-023-31130-9 -
信頼度 1.0
“Accounting for the quantification of the chemical states in C1s (Table 2) overestimating the overall oxygen content, the oxidation should be connected to the generation of more carbons bonding to oxygen, such as C-O-C or (C=O)-C-O*-C bonds,”
Electrospinning of Ethylene Vinyl Acetate/Carbon Nanotube Nanocomposite Fibers DOI: 10.3390/polym11030550 -
信頼度 1.0
“The peak position at 529.3 was the spectrum has five deconvoluted peaks at 535.0 (O1), 532.6 (O2), 531.4 (O3), 530.4 (O4), and 529.3 Ni-O-Ni/C-O-Ni attributed to the oxygen in NiO, and 530.4 corresponds to the formation of through eV(O5).”
Phytogenic Generation of NiO Nanoparticles Using Stevia Leaf Extract and Evaluation of Their In-Vitro Antioxidant and Antimicrobial Properties DOI: 10.3390/biom10010089
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