What absorbs at 2349 cm⁻¹ in an FTIR spectrum?
A band near 2349 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
빠른 답변
A band near 2349 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
가능한 작용기 할당
| 작용기 | 지원 사실 | 인용 출처 | 최고 신뢰도 |
|---|---|---|---|
| Carbon dioxide | 9 | 7 | 1.0 |
| Carboxyl (COOH) | 3 | 3 | 1.0 |
| Methacrylate | 3 | 3 | 1.0 |
| Acetate | 3 | 3 | 1.0 |
| Ketone | 2 | 2 | 1.0 |
| Ester | 2 | 2 | 1.0 |
| Carbonyl (C=O) | 2 | 2 | 1.0 |
| Amide | 2 | 2 | 1.0 |
| Water (H2O) | 1 | 1 | 1.0 |
| Methoxy (OCH3) | 1 | 1 | 1.0 |
| C-O single bond | 1 | 1 | 1.0 |
| Alkyl C-H | 1 | 1 | 1.0 |
| Adsorbed carbon monoxide | 1 | 0 | 1.0 |
순위는 단일 권위 규칙이 아닌 축적된 문헌 증거를 반영합니다. 항상 샘플 상황에 대해 확인하세요.
가능한 재료
동일한 문헌 풀이 이 밴드와 하나 이상의 추가 특징 피크를 지원하는 경우에만 물질이 표시됩니다.
스펙트럼 로직
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 2349 cm⁻¹ is usually not enough for material identification by itself.
실제 사용
이러한 유형의 질의는 고분자 식별, 미지 플라스틱 스크리닝, QC 문제 해결, 재활용 재료 검증 및 문헌 기반 피크 할당 검토에서 일반적입니다.
일반적인 실수
- 하나의 고립된 밴드를 재료의 증거로 취급하고 최소 하나 또는 두 개의 지원 피크를 확인하지 않는 것.
- 겹침 무시: 여러 작용기가 동일한 파수 근처에서 기여할 수 있습니다.
- 첨가제, 혼합물, 산화 또는 오염이 스펙트럼을 왜곡할 수 있는 경우 검증을 건너뜁니다.
검증 조언
모호성이 남아 있는 경우, 특히 혼합물, 분해된 시료 및 충전 폴리머의 경우 DSC, GC-MS 또는 TGA로 가설을 검증하십시오.
이 할당의 배경이 되는 문헌
-
Alkyl C-H 신뢰도 1.0
“proportion.19,30 the concentration in equal Consequently, all the (n (n cm(cid:2)1) cm(cid:2)1) band at 2349 and CH band at 3018 at a bulk 3 4 3 quantitative data will be expressed either in ''ppm m'' or in pressure of 1.2 bar.”
Cailteau 等 - 2011 - In situ gas monitoring in clay rocks mathematical DOI: 10.1039/c0ay00622j -
Carbon dioxide 신뢰도 1.0
“Inspection of the list of infrared and Raman active modes for gaseous CO (see Table 56 in Herzberg, 1956) shows that carbon dioxide 2 displays, besides a very strong v antisymmetric stretching at 3 cm-1, cm-1, 2349.3 two infrared active ban”
FTIR microspectroscopy and SIMS study of water-poor cordierite from El Hoyazo, Spain: Application to mineral and melt devolatilization DOI: 10.1016/j.lithos.2009.05.031 -
신뢰도 1.0
“The band at 2349 was due to O C O stretching concentration increases which may be due to a decrease in oxygen vacancy concentration [44].”
Fabbiyola 等 - 2017 - Optical and magnetic properties of Ni-doped ZnO na DOI: 10.1016/j.jallcom.2016.10.022 -
Carbon dioxide 신뢰도 1.0
“The band at 2349 was due to O=C=O stretchof dye sensitised solar cells were done using Keithley source ing vibrations which confirms the existence of CO while meter (Model No.”
Structural, optical and electrical properties of Ni doped ZnO nanostructures synthesized by solution combustion method DOI: 10.1007/s10854-017-8038-4 -
Carbon dioxide 신뢰도 1.0
“Moreover, the presence of 3 2 and 2349 cm-1 caused by the asymmetric stretch ν3 of the CO2 molecule [41].”
Thermal and Plasma-Assisted CO2 Methanation over Ru/Zeolite: A Mechanistic Study Using In-Situ Operando FTIR DOI: 10.3390/catal13030481 -
Carbon dioxide 신뢰도 1.0
“Results were grouped based on the mass of Carbon dioxide Antisymmetric stretching 2349”
Gordon 和 Sephton - 2016 - Organic Matter Detection on Mars by Pyrolysis-FTIR DOI: 10.1089/ast.2016.1485 -
신뢰도 1.0
“Explicit assignment: 'peak located at 2349cm-1 corresponding to the anti-symmetric stretch in carbon dioxide'”
Gordon 和 Sephton - 2018 - A Method for Choosing the Best Samples for Mars Sa DOI: 10.1089/ast.2017.1744 -
Water (H2O) 신뢰도 1.0
“For carbon dioxide and water the areas of cm-1 corresponding to the anti-symmetric characteristic peaks were recorded - one located at 2349 cm-1 arising from a stretching mode of water.”
Gordon 和 Sephton - 2016 - Rapid habitability assessment of Mars samples by p DOI: 10.1016/j.pss.2015.11.019
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