What absorbs at 1775 cm⁻¹ in an FTIR spectrum?
A band near 1775 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
クイックアンサー
A band near 1775 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能性のある官能基アサイン
| 官能基 | 裏付け事実 | 引用元 | 最高信頼度 |
|---|---|---|---|
| Carbonyl (C=O) | 6 | 5 | 1.0 |
| Methacrylate | 5 | 5 | 1.0 |
| Carboxyl (COOH) | 5 | 5 | 1.0 |
| Acetate | 5 | 5 | 1.0 |
| Ketone | 4 | 4 | 1.0 |
| Ester | 4 | 4 | 1.0 |
| Amide | 4 | 4 | 1.0 |
| Alkyl C-H | 2 | 2 | 1.0 |
| Methoxy (OCH3) | 2 | 2 | 1.0 |
| C-O single bond | 2 | 2 | 1.0 |
| Carbohydrate | 2 | 2 | 1.0 |
| Ring structure | 1 | 1 | 1.0 |
| Imide | 1 | 1 | 1.0 |
| Metal oxygen | 1 | 1 | 1.0 |
| Alkene (C=C) | 1 | 1 | 1.0 |
| Hydroxyl (O-H) | 1 | 1 | 1.0 |
ランキングは蓄積された文献証拠を反映しており、単一の権威あるルールではありません。常にサンプルのコンテキストと照合して確認してください。
可能性のある材料
| 素材 | 補助ピーク | 重複グループ | 引用元 |
|---|---|---|---|
| PVA | 1775, 1660, 2930 | Acetate, Methacrylate, Carbonyl (C=O) | 2 |
| cellulose nanocrystals | 1775, 1110, 1640 | Acetate, Methacrylate, Carbonyl (C=O) | 1 |
| magnetite | 1775, 1740, 1263 | Carboxyl (COOH), Methacrylate, Acetate | 1 |
| honey | 1775, 2005, 1199 | Methacrylate, Acetate | 1 |
| GO | 1775, 1720, 1182 | Methacrylate, Acetate, Carboxyl (COOH) | 1 |
同じ文献プールがこのバンドと少なくとも1つの追加の特性ピークをサポートする場合にのみ、材料が表示されます。
スペクトルロジック
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1775 cm⁻¹ is usually not enough for material identification by itself.
実使用例
この種のクエリは、ポリマー識別、未知のプラスチックスクリーニング、QCトラブルシューティング、リサイクル材料の検証、および文献に基づいたピーク帰属のレビューで一般的です。
よくある間違い
- 少なくとも1~2つの支持ピークを確認せずに、1つの孤立したバンドを材料の証拠として扱うこと。
- 重複を無視: 複数の官能基が同じ波数付近に寄与することがあります。
- 添加剤、ブレンド、酸化、または汚染がスペクトルを歪める可能性がある場合に検証を省略すること。
検証アドバイス
曖昧さが残る場合は、特にブレンド、劣化サンプル、充填ポリマーについて、DSC、GC-MS、またはTGAで仮説を検証してください。
これらのアサインの根拠となる文献
-
Carboxyl (COOH) 信頼度 1.0
“Spectrum FTIR Carboxymethyl kappa-carrageenan Based on the FTIR spectrum, it appears that some of the hydroxyl groups have been replaced with carboxyl cm-1 cm-1 and 1417 confirming groups, indicated by the appearance of absorption peaks at”
The capability of nanomagnetite carboxymethyl kappa-carrageenan coated to adsorp metal ions DOI: 10.1063/5.0000680 -
Acetate 信頼度 1.0
“The absence of the vibration band located around 1775 is attributed to the elongated vibrations of the specific C=O bond of the hemicellulose residues”
Part A: Biodegradable Bio-Composite Film Reinforced with Cellulose Nanocrystals from Chaetomorpha linum into Thermoplastic Starch Matrices DOI: 10.3390/polym15061542 -
Carbohydrate 信頼度 1.0
“Sci.2022,12,9645 5of9 and 1775 cm-1 which are attributed to the carbohydrates and O-H stretching vibrations”
Botanical Origin Assessment of Honey Based on ATR-IR Spectroscopy: A Comparison between the Efficiency of Supervised Statistical Methods and Artificial Intelligence DOI: 10.3390/app12199645 -
Hydroxyl (O-H) 信頼度 1.0
“cm-1, cm-1, O-H, C=O, C=C, -CH 2, C-O stretching, and C-H bending at 3741.18 1774.84 cm-1, cm-1, cm-1, cm-1, 1689.04 1511.76 1182.03 and 882.79 respectively.”
Evaluation of Structural and Optical Properties of Graphene Oxide-Polyvinyl Alcohol Thin Film and Its Potential for Pesticide Detection Using an Optical Method DOI: 10.3390/photonics9050300 -
Acetate 信頼度 1.0
“1153cm(cid:3)1 which the carbonyl stretching vibration of six-membered cyclic (C-O stretching of ester) and (C-N stretching of aliphatic ester).17,18 1760cm(cid:3)1, anhydrides exhibited unique peaks at 1800 and amine and/or C-O stretching”
DSC-FTIR microspectroscopy used to investigate the heat-induced intramolecular cyclic anhydride formation between Eudragit E and PVA copolymer DOI: 10.1038/pj.2011.15; -
Acetate 信頼度 1.0
“The absorption bands observed at 1775 cm-1 and 1716 were attributed to the asymmetric and symmetric stretching of C=O in the imide ring, Polymers2017,9,734”
Preparation and Evaluation of a Polyimide-Coated Ultrafine Gilt Molybdenum Wire and Its Knitted Mesh Used for Electromagnetic Reflectors DOI: 10.3390/polym9120734 -
Alkyl C-H 信頼度 1.0
“In the Figure 4 (A) the shows crystalline and 2850 (CH stretching), 1775 (C=O stretchIndian Journal of Pharmaceutical Education and Research | Vol 52 | Issue 4 [Suppl] | Oct-Dec, 2018”
Udapurkar 等 - 2018 - Diosmin Phytosomes Development, Optimization and DOI: 10.5530/ijper.52.4s.73 -
信頼度 0.8
“Attributed to specific vibration of thiophene.”
Surface Characterization of Modified Electrodes Based on 4-(Azulen-1-yl)-2,6-bis((E)-2-(thiophen-2-yl)vinyl)pyridine DOI: 10.3390/sym14122506
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