What absorbs at 1251 cm⁻¹ in an FTIR spectrum?
A band near 1251 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Quick answer
A band near 1251 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Mulige funktionelle gruppetildelinger
| Funktionel gruppe | Understøttende fakta | Citerede kilder | Højeste tillid |
|---|---|---|---|
| Methacrylate | 6 | 6 | 1,0 |
| Acetate | 6 | 6 | 1,0 |
| Methoxy (OCH3) | 5 | 5 | 1,0 |
| C-O single bond | 5 | 5 | 1,0 |
| Amide | 3 | 2 | 1,0 |
| Alkyl C-H | 2 | 2 | 1,0 |
| Aromatic ring | 2 | 2 | 1,0 |
| Carbonyl (C=O) | 2 | 2 | 1,0 |
| Carboxyl (COOH) | 2 | 2 | 1,0 |
| Ring structure | 2 | 2 | 1,0 |
| Ester | 2 | 2 | 1,0 |
| Phosphate (PO4) | 2 | 1 | 1,0 |
| C c single bond | 1 | 1 | 1,0 |
| Ketone | 1 | 1 | 1,0 |
| Oxygen heterocycle | 1 | 1 | 1,0 |
| Borate | 1 | 1 | 1,0 |
| N h | 1 | 1 | 1,0 |
| Carbohydrate | 1 | 1 | 0,8 |
| Phosphorus | 1 | 0 | 1,0 |
| Nitrogen heterocycle | 1 | 0 | 0,9 |
Rangering afspejler akkumulerede litteraturbeviser, ikke en enkelt autoritativ regel. Bekræft altid mod din prøvekontekst.
Possible materials
| Materiale | Understøttende toppe | Overlapping groups | Citerede kilder |
|---|---|---|---|
| PVA | 1251, 1660, 2930 | Acetate, Methacrylate, C-O single bond | 1 |
| Fe3O4 | 1251, 2358, 1673 | Methacrylate, Acetate | 1 |
| ZnS | 1251, 1650, 1116 | Acetate, Methacrylate | 1 |
| Fe3O4 nanoparticles | 1251, 1673, 1470 | Methacrylate, Acetate | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1251 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
Litteratur bag disse tildelinger
-
tillid 1,0
“The moderate cm-1 belongs to N-H stretching absorption peak at 1251”
In-doped ZnS nanoparticles: structural, morphological, optical and antibacterial properties DOI: 10.1007/s00339-021-04425-9 -
Borate tillid 1,0
“cm-1 *1251 The band centered at is attributed to B-O The resulted IR data were used in this research in order to stretching vibrations in [BO 3] units from boroxol cm-1”
Rada 等 - 2009 - Structural and electronic properties of tellurite DOI: 10.1007/s10853-009-3433-8 -
Acetate tillid 1,0
“cm-1 C-O stretching 1251 cm-1”
Influence of Polyvinyl Alcohol (PVA) on PVA-Poly-N-hydroxyethyl-aspartamide (PVA-PHEA) Microcrystalline Solid Dispersion Films DOI: 10.1208/s12249-020-01811-z -
Oxygen heterocycle tillid 1,0
“For spectrum, the main peaks located at 1251 and 877 LENR cm-1 are assigned for symmetric and asymmetric stretching of epoxide ring, respectively.”
Azhar 等 - 2017 - Epoxidation and Hydroxylation of Liquid Natural Ru DOI: 10.17576/jsm-2017-4603-17 -
Amide tillid 1,0
“resents another alternative by accurately quantifying ligand The maximum amide peaking at 1653, 1546 and 1251 cm-1 density, but such techniques require matrix digestion [50].”
Boulet-Audet 等 - 2015 - Cleaning-in-place of immunoaffinity resins monitor DOI: 10.1007/s00216-015-8871-3) -
Acetate tillid 1,0
“the C-O-C peaks of the ester bond at 1251 and cm-1 1024 also confirm this.”
Synthesis and Application of Tackifying Dispersant Poly (Vinyl Alcohol-Acrylic Acid-Triallyl Cyanate) DOI: 10.3390/polym14030557 -
Phosphate (PO4) tillid 1,0
“Furthermore, an cm-1) ester bond in the FTIR spectra (C=O stretching at 1745 was selected for the estimation cm-1) of lipids and a phosphate functional group bond (P=O stretching at 1251 was selected for the estimation of polyphosphates.”
Calcium Affects Polyphosphate and Lipid Accumulation in Mucoromycota Fungi DOI: 10.3390/jof7040300 -
Acetate tillid 1,0
“(b) (c) and The main vibrations, where the greatest changes in the wood occurred, were identified at the peaks at 1251 cm-1, which is related to the C-O stretching vibration;”
Moya 等 - 2022 - In Situ Synthesis of Fe3O4 Nanoparticles and Wood DOI: 10.3390/ma15093394
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