What absorbs at 834 cm⁻¹ in an FTIR spectrum?
A band near 834 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
クイックアンサー
A band near 834 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能性のある官能基アサイン
| 官能基 | 裏付け事実 | 引用元 | 最高信頼度 |
|---|---|---|---|
| Silicon-oxygen (Si-O) | 3 | 3 | 1.0 |
| Silicon (Si) | 3 | 3 | 1.0 |
| Alkyl C-H | 3 | 3 | 1.0 |
| C c single bond | 2 | 2 | 1.0 |
| Carbonyl (C=O) | 2 | 2 | 1.0 |
| Chlorine | 2 | 2 | 1.0 |
| Ring structure | 2 | 2 | 1.0 |
| Imide | 1 | 1 | 1.0 |
| Acetyl | 1 | 1 | 1.0 |
| Methacrylate | 1 | 1 | 1.0 |
| Ketone | 1 | 1 | 1.0 |
| Ester | 1 | 1 | 1.0 |
| Carboxyl (COOH) | 1 | 1 | 1.0 |
| Amide | 1 | 1 | 1.0 |
| Acetate | 1 | 1 | 1.0 |
| N h | 1 | 1 | 1.0 |
| Aromatic ring | 1 | 1 | 1.0 |
| Lipid | 1 | 1 | 1.0 |
| Hydroxyl (O-H) | 1 | 1 | 1.0 |
| Silanol (Si-OH) | 1 | 1 | 1.0 |
| Siloxane (Si-O-Si) | 1 | 1 | 1.0 |
| C-O single bond | 1 | 1 | 0.9 |
| Metal oxygen | 1 | 0 | 0.9 |
| Oxygen heterocycle | 1 | 0 | 0.9 |
ランキングは蓄積された文献証拠を反映しており、単一の権威あるルールではありません。常にサンプルのコンテキストと照合して確認してください。
可能性のある材料
| 素材 | 補助ピーク | 重複グループ | 引用元 |
|---|---|---|---|
| PVC | 834, 1195, 1100 | Alkyl C-H | 3 |
| PMMA | 834, 1722, 1383 | Alkyl C-H | 1 |
| silica | 834, 1100, 1080 | Silicon-oxygen (Si-O), Silicon (Si), Alkyl C-H | 1 |
| SiO2 | 834, 1739, 699 | Silicon-oxygen (Si-O), Alkyl C-H, Silicon (Si) | 1 |
| silver nanoparticles | 834, 1636, 1631 | Alkyl C-H | 1 |
同じ文献プールがこのバンドと少なくとも1つの追加の特性ピークをサポートする場合にのみ、材料が表示されます。
スペクトルロジック
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 834 cm⁻¹ is usually not enough for material identification by itself.
実使用例
この種のクエリは、ポリマー識別、未知のプラスチックスクリーニング、QCトラブルシューティング、リサイクル材料の検証、および文献に基づいたピーク帰属のレビューで一般的です。
よくある間違い
- 少なくとも1～2つの支持ピークを確認せずに、1つの孤立したバンドを材料の証拠として扱うこと。
- 重複を無視: 複数の官能基が同じ波数付近に寄与することがあります。
- 添加剤、ブレンド、酸化、または汚染がスペクトルを歪める可能性がある場合に検証を省略すること。
検証アドバイス
曖昧さが残る場合は、特にブレンド、劣化サンプル、充填ポリマーについて、DSC、GC-MS、またはTGAで仮説を検証してください。
これらのアサインの根拠となる文献
-
Silicon (Si) 信頼度 1.0
“While, absorption at 834 shows the Si-O-Si asymmetric of silanol (Si-OH) at 966 cm-1 there were absorption stretching [24].”
Ismail 等 - 2015 - Effect of Radiation on Properties of ENRPVCSiO2 DOI: 10.1063/1.4931308 -
C c single bond 信頼度 1.0
“Besides, the bands between 600 cm-1 and 700 cm-1, 834 cm-1 could be attributed cm-1 ascribed to the C-C stretching and -CH wagging, respectively.”
Understanding Hydrothermal Dechlorination of PVC by Focusing on the Operating Conditions and Hydrochar Characteristics DOI: 10.3390/app7030256 -
信頼度 1.0
“For PVC, C H stretching mode can be S.Rameshetal./SpectrochimicaActaPartA66(2007)1237-1242 1239 Table2 VibrationalmodesandwavenumbersexhibitedbyPMMA Wavenumbers(cm-1) Descriptionofvibrations References C Hstretching 2927-2986 [30,32] C Ostr”
Ramesh 等 - 2007 - FTIR studies of PVCPMMA blend based polymer elect DOI: 10.1016/j.saa.2006.06.012 -
信頼度 1.0
“The pronounced in the Synth1 sample, where the three bands are cm-1 strong and sharp peaks at 834 and 705 are assigned to the not anymore identifiable and a unique broad band is observed, n2 n4 out-of-plane OCO bending mode and to the antis”
Investigation of the hydrozincite structure by infrared and solid-state NMR spectroscopy DOI: 10.2138/am.2013.4158 -
Alkyl C-H 信頼度 1.0
“cm1 cm1 stretching at 671.43 and 892.51 The peaks at 834.50 and 798.47 indicate C-H deformation and ring stretching of trisubstituted benzene.”
Agrawal 等 - 2023 - Biotreatment of azo dye containing textile industr DOI: 10.21203/rs.3.rs-1876766/v2 -
Lipid 信頼度 1.0
“Medium-weak bands, only detectable in the FTIR spectrum of carnauba wax at 1634, 1607, 1515 and 834 cm-1, are attributed to the skeletal ring breathing modes of aromatic groups [30,47].”
Characterization of Waxes in the Roman Wall Paintings of the Herculaneum Site (Italy) DOI: 10.3390/app122111264 -
信頼度 1.0
“The cm(cid:1)1 N-H peak at 834 is due to the out-of-plane bending”
Facile simultaneous synthesis of tetraaniline nanostructures/silver nanoparticles as heterogeneous catalyst for the efficient catalytic reduction of 4-nitrophenol to 4-aminophenol DOI: 10.1039/d0ra03327h -
信頼度 1.0
“It was 1089.6cm-1 (S=O stretching vibration) and 1136.8, and also observed that some peaks shown by pure etoricoxib 639.22009cm-1 (C-Cl stretching vibra834.0, 777.1, and were absent, and the intensity of peaks of these etoricoxib tion).”
Das 等 - 2011 - Solubility and dissolution enhancement of etoricox DOI: 10.5402/2011/819765
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