What absorbs at 2363 cm⁻¹ in an FTIR spectrum?
A band near 2363 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 7 cited sources
Hurtigt svar
A band near 2363 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Mulige funktionelle gruppetildelinger
| Funktionel gruppe | Understøttende fakta | Citerede kilder | Højeste tillid |
|---|---|---|---|
| Carbon dioxide | 3 | 3 | 1,0 |
| Ammonium | 1 | 1 | 1,0 |
| Secondary amine | 1 | 1 | 1,0 |
| N h | 1 | 1 | 1,0 |
| Nitrile | 1 | 1 | 1,0 |
| Methacrylate | 1 | 1 | 1,0 |
| Ketone | 1 | 1 | 1,0 |
| Ester | 1 | 1 | 1,0 |
| Carboxyl (COOH) | 1 | 1 | 1,0 |
| Carbonyl (C=O) | 1 | 1 | 1,0 |
| Amide | 1 | 1 | 1,0 |
| Acetate | 1 | 1 | 1,0 |
| Anhydride | 1 | 1 | 1,0 |
| Metal oxygen | 1 | 1 | 1,0 |
| Hydrogen bond | 1 | 0 | 1,0 |
| Hydroxyl (O-H) | 1 | 0 | 1,0 |
Rangering afspejler akkumulerede litteraturbeviser, ikke en enkelt autoritativ regel. Bekræft altid mod din prøvekontekst.
Mulige materialer
| Materiale | Understøttende toppe | Overlappende grupper | Citerede kilder |
|---|---|---|---|
| Polyurethane | 2363, 2270, 1700 | N h | 1 |
Materialer vises kun, når den samme litteraturpulje understøtter dette bånd og mindst en yderligere karakteristisk top.
Spektrumlogik
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 2363 cm⁻¹ is usually not enough for material identification by itself.
Anvendelse i virkeligheden
Denne type forespørgsel er almindelig ved polymeridentifikation, screening af ukendt plast, fejlfinding i kvalitetskontrol, verifikation af genanvendt materiale og litteraturunderstøttet gennemgang af peak-tildeling.
Almindelige fejl
- Behandling af et isoleret bånd som bevis på et materiale uden at kontrollere mindst en eller to understøttende toppe.
- Ignorerer overlap: flere funktionelle grupper kan bidrage nær samme bølgetal.
- Spring validering over, når additiver, blandinger, oxidation eller forurening kan forvrænge spektret.
Verifikationsrådgivning
Når tvetydighed fortsat består, valider hypotesen med DSC, GC-MS eller TGA, især for blandinger, nedbrudte prøver og fyldte polymerer.
Litteratur bag disse tildelinger
-
Carbon dioxide tillid 1,0
“The band at 2363 is due to cm-1 CO2, which is generally observed in IR spectra.”
Choubey 等 - 2007 - Influence of doping on OH absorption in LiNbO3 cry DOI: 10.1002/crat.200610894 -
Metal oxygen tillid 1,0
“The bands that appear in the range 1148-1464 occur as a result of Metal-Oxygen-Metal (M-O-M) such 14 cm-1 as Fe-O-Fe and Co-O-Co [28].The presence of CO is evident by the observation of the band at 2363 15 2”
Mohammed 等 - 2018 - Effect of heat-treatment on the magnetic and optic DOI: 10.1088/2053-1591/aad1e5 -
Carbon dioxide tillid 1,0
“LLM confirmed rule peak-group candidate”
Singh 等 - 2012 - Detection of Defects in ZnO Nanoparticles by Spect DOI: 10.1063/1.4736887 -
Carbon dioxide tillid 1,0
“The significant peak at 1628 cm-1 around 2363 might have been due to stretching O=C=O in CO 2.”
Mesoporous Magnetic Cysteine Functionalized Chitosan Nanocomposite for Selective Uranyl Ions Sorption: Experimental, Structural Characterization, and Mechanistic Studies DOI: 10.3390/polym14132568 -
Nitrile tillid 1,0
“A strong peak at 2363 can be attributed cm-1 C≡N to stretching in nitriles [55] and O=C=O stretching in CO [56].”
Thermal Hazard and Smoke Toxicity Assessment of Building Polymers Incorporating TGA and FTIR—Integrated Cone Calorimeter Arrangement DOI: 10.3390/fire5050139 -
N h tillid 1,0
“After modified by 2-aminoethanol, the FTIR Polymers 2020, 12, x FOR PEER REVIEW 4 of 13 peaks at 2363 cm-1 and 2342 cm-1, which are assigned to NH+ in rhodamine 6G, disappear.”
A Fluorescent Polyurethane with Covalently Cross-Linked Rhodamine Derivatives DOI: 10.3390/polym12091989 -
tillid 0,7
“Band at 2363 associated with Lewis acid centers.”
Comparative study of the strongest solid Lewis acids known: ACF and HS-AlF3 DOI: 10.1039/c8dt03279c
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