What absorbs at 1950 cm⁻¹ in an FTIR spectrum?
A band near 1950 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 5 cited sources
Quick answer
A band near 1950 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Penetapan kumpulan berfungsi yang mungkin
| Kumpulan berfungsi | Fakta sokongan | Sumber dipetik | Keyakinan tertinggi |
|---|---|---|---|
| Carbonyl (C=O) | 2 | 2 | 1.0 |
| Nitrile | 1 | 1 | 1.0 |
| Methacrylate | 1 | 1 | 1.0 |
| Ketone | 1 | 1 | 1.0 |
| Ester | 1 | 1 | 1.0 |
| Carboxyl (COOH) | 1 | 1 | 1.0 |
| Amide | 1 | 1 | 1.0 |
| Acetate | 1 | 1 | 1.0 |
| Alkyl C-H | 1 | 0 | 1.0 |
| Alkene (C=C) | 1 | 0 | 1.0 |
Pemeringkatan mencerminkan bukti literatur terkumpul, bukan satu peraturan berwibawa. Sentiasa sahkan terhadap konteks sampel anda.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1950 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
Literatur di sebalik penetapan ini
-
Acetate keyakinan 1.0
“≅960+1000 combination band C=O stretching shoulder Weak 1950 SiO2 1880-1866 ≅697+1163 SiO2 combination band”
FTIR photoacoustic spectroscopy for identification and assessment of soil components_ Chernozems and their size fractions DOI: 10.1016/j.pacs.2020.100162 -
Carbonyl (C=O) keyakinan 1.0
“Although CO (or H Re-CO bands, if present, indicate larger clusters of Re on the cm-1 were found on CoRe(N), carbonyl bands around 1950 surface.”
Kumar 等 - 2011 - In Situ FT-IR Study on the Effect of Cobalt Precur DOI: 10.1021/jp104878e -
keyakinan 1.0
“Based on these former reports [56,57,62,66,67], as described 1950cm-1 above we assigned the new band at on Pt/C and 1960cm-1 on Pt-B to asymmetric bridged CO, CO(B) asym., which might be adsorbed on (100) terraces exposed on nano-”
Sato 等 - 2007 - Adsorptionoxidation of CO on highly dispersed Pt DOI: 10.1016/j.electacta.2007.05.007 -
Nitrile keyakinan 1.0
“cm-1 Three novel CO bands were detected at 1950, 1936, and 1927 alongside a larger number of cyanide bands.”
Infrared Characterization of the Bidirectional Oxygen-Sensitive [NiFe]-Hydrogenase from E. coli DOI: 10.3390/catal8110530 -
keyakinan 0.4
“Text: '1950cm-1 ν (M´' (incomplete, likely carbonyl stretching)”
Duchatelet 等 - 2009 - An approach to retrieve information on the carbony DOI: 10.1029//2005GL022386
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