What absorbs at 1135 cm⁻¹ in an FTIR spectrum?
A band near 1135 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 320,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Quick answer
A band near 1135 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Possible functional-group assignments
| Functional group | Supporting facts | Cited sources | Top confidence |
|---|---|---|---|
| C-O single bond | 6 | 6 | 1.0 |
| Acetate | 6 | 6 | 1.0 |
| Methoxy (OCH3) | 5 | 5 | 1.0 |
| Methacrylate | 5 | 5 | 1.0 |
| Ester | 3 | 3 | 1.0 |
| Silicon-oxygen (Si-O) | 3 | 2 | 1.0 |
| Silicon (Si) | 3 | 2 | 1.0 |
| Ring structure | 2 | 2 | 1.0 |
| Carbohydrate | 2 | 2 | 1.0 |
| Alkyl C-H | 2 | 2 | 1.0 |
| Siloxane (Si-O-Si) | 2 | 1 | 1.0 |
| Carbonyl (C=O) | 1 | 1 | 1.0 |
| Aromatic ring | 1 | 1 | 1.0 |
Ranking reflects accumulated literature evidence, not a single fixed rule. Always confirm against your sample context.
Possible materials
| Material | Supporting peaks | Overlapping groups | Cited sources |
|---|---|---|---|
| Cellulose | 1135, 1735, 1730 | Acetate, Methacrylate, C-O single bond | 1 |
| cellulose acetate | 1135, 1741, 1368 | Acetate, Methacrylate, Methoxy (OCH3) | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1135 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
Literature behind these assignments
-
Aromatic ring
- Reported band
- 1135 cm-1
- Assignment
- Aromatic ring
- Material / context
- 4-Nitrophenol; [DEIm][Br]; MOF-5
-
Alkyl C-H
- Reported band
- 1135 cm-1
- Assignment
- Alkyl C-H
- Material / context
- Cellulose Nanofibers; HMIMBF4 ionic liquid
-
C-O single bond
- Reported band
- 1135 cm-1
- Assignment
- C-O single bond
- Material / context
- tablet-coating; HPMC polymer; pharmaceutical preparations
-
Alkyl C-H
- Reported band
- 1135 cm-1
- Assignment
- Alkyl C-H
- Material / context
- Styrene-Ethylene-Butadiene-Styrene; SEBS copolymer
-
Acetate
- Reported band
- 1135 cm-1
- Assignment
- Acetate
- Material / context
- calcium-binding heptapeptide; Hydrolysate of Tilapia Bone
-
Silicon (Si)
- Reported band
- 1135 cm-1
- Assignment
- Silicon (Si)
- Material / context
- cotton fabric coated with N-containing hybrid composites
-
Carbonyl (C=O)
- Reported band
- 1135 cm-1
- Assignment
- Carbonyl (C=O)
- Material / context
- clay-based nano pigments of Safranin O; colored polymeric membrane
-
Carbohydrate
- Reported band
- 1135 cm-1
- Assignment
- Carbohydrate
- Material / context
- Aminosilane; Cellulose; cellulose acetate
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