What absorbs at 1134 cm⁻¹ in an FTIR spectrum?
A band near 1134 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Réponse rapide
A band near 1134 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Attributions possibles de groupes fonctionnels
| Groupe fonctionnel | Faits à l'appui | Sources citées | Confiance maximale |
|---|---|---|---|
| Methoxy (OCH3) | 5 | 5 | 1,0 |
| Methacrylate | 5 | 5 | 1,0 |
| C-O single bond | 5 | 5 | 1,0 |
| Acetate | 5 | 5 | 1,0 |
| Hydroxyl (O-H) | 2 | 2 | 1,0 |
| Alkyl C-H | 2 | 2 | 1,0 |
| S eq o | 2 | 2 | 0,8 |
| Silanol (Si-OH) | 1 | 1 | 1,0 |
| Silicon hydride | 1 | 1 | 1,0 |
| Phosphate (PO4) | 1 | 1 | 1,0 |
| Secondary amine | 1 | 1 | 1,0 |
| C n single bond | 1 | 1 | 1,0 |
| Amide | 1 | 1 | 1,0 |
| Siloxane (Si-O-Si) | 1 | 1 | 1,0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 1,0 |
Le classement reflète les preuves bibliographiques accumulées, et non une règle faisant autorité. Confirmez toujours dans le contexte de votre échantillon.
Matériaux possibles
| Matériel | Pics de support | Groupes chevauchants | Sources citées |
|---|---|---|---|
| cellulose | 1134, 1735, 1650 | Acetate, Methacrylate, C-O single bond | 2 |
| hemicellulose | 1134, 1730, 897 | Methacrylate, Acetate, C-O single bond | 1 |
| kraft lignin | 1134, 1744, 1710 | Methacrylate, Acetate, Methoxy (OCH3) | 1 |
Les matériaux sont affichés uniquement lorsque le même ensemble de littérature soutient cette bande et au moins un pic caractéristique supplémentaire.
Logique du spectre
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1134 cm⁻¹ is usually not enough for material identification by itself.
Utilisation réelle
Ce type de requête est courant dans l'identification des polymères, le criblage des plastiques inconnus, le dépannage du contrôle qualité, la vérification des matériaux recyclés et l'examen de l'attribution des pics appuyée par la littérature.
Erreurs courantes
- Traiter une bande isolée comme preuve d'un matériau sans vérifier au moins un ou deux pics de support.
- Ignorer le chevauchement : plusieurs groupes fonctionnels peuvent contribuer près du même nombre d'onde.
- Sauter la validation lorsque des additifs, des mélanges, l'oxydation ou la contamination peuvent déformer le spectre.
Conseil de vérification
Lorsque l'ambiguïté persiste, validez l'hypothèse avec DSC, GC-MS ou TGA, en particulier pour les mélanges, les échantillons dégradés et les polymères chargés.
Bibliographie derrière ces attributions
-
Acetate confiance 1,0
“RPMI peak at 1134 has also appeared representing the C-O commedium was then removedfrom wells and discarded,cells were ponent of an ester bond.”
Broderick 等 - 2006 - The characterisation of a novel, covalently modifi DOI: 10.1016/j.jcis.2005.12.026 -
confiance 1,0
“-NH O-C at 1103.2 and 1088.1 Weak absorption of aryl appears at 1627 and 1593 cm-1 OTES-APTS polymer shows sharp absorption at 1134.1 and 1033.8 as an asymmetric stretching of -CH Si-O-Si and Si-O-C respectively.”
Wahyuningsih 等 - 2018 - Synthesis of Optode Thin Layer using Sol Gel Hybri DOI: 10.1088/1757-899X/333/1/012021 -
Acetate confiance 1,0
“Zanoni por contribuições cm-1 éster, grupo C-O-C de atribuídas à banda em 1134 (nC-O-C);”
Barbosa 等 - 2022 - RAPID ASSESSMENT OF TRANSFORMER INSULATING VEGETAB DOI: 10.21577/0100-4042.20170914 -
Acetate confiance 1,0
“The band observed at 1134 is 9 associated with C-O due to the secondary alcohol, which can show the presence of the functional group of lignin, cellulose,”
Cheng 等 - 2018 - A new approach to improve mechanical properties an DOI: 10.1016/j.conbuildmat.2018.05.134 -
Amide confiance 1,0
“The FTIR spectrum of the parent NSB-G Department of Genetic Engineering and Biotechnology, Shahjalal Unicm(cid:1)1, S¼O C-N represented the stretching vibrations of at 1134 at versity of Science and Technology, Sylhet-3114, Bangladesh.”
Biodegradation of reactive textile dye Novacron Super Black G by free cells of newly isolated Alcaligenes faecalis AZ26 and Bacillus spp obtained from textile effluents DOI: 10.1016/j.heliyon.2019.e02068 -
Phosphate (PO4) confiance 1,0
“cm-1 Furthermore, the characteristic peak at 1134 was ascribed to the absorption of -P=O in PCF.”
Polybenzoxazine Resins with Cellulose Phosphide: Preparation, Flame Retardancy and Mechanisms DOI: 10.3390/polym13244288 -
Acetate confiance 1,0
“The band 1134 are assigned to the immunohistochemistry images of connective tissue in Atlantic cod C-O-S asymmetric stretching vibration in GAGs [40, 46],”
The use of FTIR spectroscopy to characterize connective tissue components in skeletal muscle of Atlantic cod (Gadus morhua L.) DOI: 10.1002/jbio.201800436 -
Alkyl C-H confiance 1,0
“2013), while the band at 1134 was assigned to CH in-plane deformation (Faix 1991;”
Vidal 等 - 2021 - Sulfomethylation of Radiata Pine Kraft Lignin and DOI: 10.1016/j.biotechadv.2016.10.001
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