What absorbs at 911 cm⁻¹ in an FTIR spectrum?
A band near 911 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Schnelle Antwort
A band near 911 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Mögliche Funktionsgruppenzuweisungen
| Funktionelle Gruppe | Unterstützende Fakten | Zitierte Quellen | Höchstes Vertrauen |
|---|---|---|---|
| Alkyl C-H | 4 | 4 | 1,0 |
| Ring structure | 2 | 2 | 1,0 |
| Silicon-oxygen (Si-O) | 2 | 2 | 1,0 |
| Metal oxygen | 1 | 1 | 1,0 |
| Hydroxyl (O-H) | 1 | 1 | 1,0 |
| Bromine | 1 | 1 | 1,0 |
| N h | 1 | 1 | 1,0 |
| C c single bond | 1 | 1 | 1,0 |
| Methoxy (OCH3) | 1 | 1 | 1,0 |
| Methacrylate | 1 | 1 | 1,0 |
| C-O single bond | 1 | 1 | 1,0 |
| Acetate | 1 | 1 | 1,0 |
| Aromatic ring | 1 | 1 | 1,0 |
| Ammonium | 1 | 1 | 1,0 |
| Styrene | 1 | 0 | 1,0 |
Das Ranking spiegelt die gesammelte Literatur Evidenz wider, nicht eine einzelne maßgebliche Regel. Bestätigen Sie immer anhand Ihres Probenkontexts.
Spektrumslogik
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 911 cm⁻¹ is usually not enough for material identification by itself.
Praktische Anwendung
Diese Art von Abfrage ist üblich bei der Polymeridentifikation, dem Screening unbekannter Kunststoffe, der Fehlersuche in der Qualitätskontrolle, der Verifizierung von Recyclingmaterial und der literaturgestützten Überprüfung der Peakzuordnung.
Häufige Fehler
- Behandlung einer isolierten Bande als Beweis für ein Material, ohne mindestens einen oder zwei unterstützende Peaks zu überprüfen.
- Überlappung ignorieren: Mehrere funktionelle Gruppen können nahe der gleichen Wellenzahl beitragen.
- Überspringen der Validierung, wenn Additive, Mischungen, Oxidation oder Verunreinigungen das Spektrum verfälschen können.
Beratung zur Verifizierung
Wenn weiterhin Mehrdeutigkeit besteht, validieren Sie die Hypothese mit DSC, GC-MS oder TGA, insbesondere bei Mischungen, degradierten Proben und gefüllten Polymeren.
Literatur hinter diesen Zuweisungen
-
Alkyl C-H Vertrauen 1,0
“These peaks represent C-H (PB).33,34 cm(cid:3)1 Another peak was observed around 911 bending of trans-alkene in polybutadiene wave number for the LP of CRMA interacted at 190-50 that represents the C-H bending of PB.34 At the aforementioned”
Effect of used motor oil as a rejuvenator on crumb rubber modifier’s released components to asphalt binder DOI: 10.1177/1477760620918600 -
Alkyl C-H Vertrauen 1,0
“910a 914b P-O-(C) stretch/CH wagging 911 909 3 10071”
Gillens 和 Powell - 2013 - Rapid quantification of TBP and TBP degradation pr DOI: 10.1007/s10967-012-2147-6 -
Vertrauen 1,0
“795.33cm(cid:2)1 (Si-O stretch) and absorption from trioctahedrals), 910.81cm(cid:2)1 (Al 2OH bending) shown in Fig.”
Ultrasonic extraction of arsenic and selenium from rocks associated with mountaintop removal/valley fills coal mining: Estimation of bioaccessible concentrations DOI: 10.1016/j.chemosphere.2010.01.020 -
Ammonium Vertrauen 1,0
“In the present work, the spectral study of the solution UNIVERSITY 21 209 prepared using ammonium molybdate salt shows strong (broad and sharp) absorption bands at 911±2, 889±2 22 cm-1 cm-1 210 23 and 856±2 (Fig.”
Sen 等 - 2015 - Nanogram level quantification of molybdenum(VI) by DOI: 10.1039/C5AY01801C. -
Alkyl C-H Vertrauen 1,0
“The last peaks (910.91 and cm-1) 877.69 correspond to a bending out of plane vibration =CH (aromatic ring).”
Belo 等 - 2018 - Development of a Black Liquor Electrolyzer for Lig DOI: 10.1149/08604.0003ecst -
Acetate Vertrauen 1,0
“by the presence of C-O stretching at 911 Other characteristic IR bands can be”
Thermal and surface properties of hybrid materials obtained from epoxy-functional urethane and siloxane DOI: 10.1007/s00289-015-1545-7 -
C c single bond Vertrauen 1,0
“u n cm-1 The wavenumbers separating normal tissue from meningioma are 911 (C-C stretching d e cm-1 cm-1 r ≈964”
Gajjar 等 - 2013 - Diagnostic segregation of human brain tumours usin DOI: 10.1039/C2AY25544H. -
Vertrauen 1,0
“On the other hand, the weak negative band cm-1 at 911 was assigned to the C15-H and N-H HOOP vibrations of the original state of BR [35].”
Kawanabe 和 Kandori - 2009 - Photoreactions and Structural Changes of Anabaena DOI: 10.3390/s91209741
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