What absorbs at 2001 cm⁻¹ in an FTIR spectrum?
A band near 2001 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Quick answer
A band near 2001 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能的官能团归属
| 官能团 | 支持性事实 | 引用来源 | 最高置信度 |
|---|---|---|---|
| Alkyl C-H | 3 | 3 | 1.0 |
| Methoxy (OCH3) | 3 | 3 | 1.0 |
| Methacrylate | 3 | 3 | 1.0 |
| C-O single bond | 3 | 3 | 1.0 |
| Acetate | 3 | 3 | 1.0 |
| C c single bond | 2 | 2 | 1.0 |
| Hydroxyl (O-H) | 2 | 2 | 1.0 |
| Amide | 1 | 1 | 1.0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 1.0 |
| C#c | 1 | 1 | 1.0 |
| Phosphate (PO4) | 1 | 1 | 1.0 |
| Ester | 1 | 1 | 1.0 |
排名反映了累积的文献证据，而非单一的权威规则。请始终对照您的样品背景进行确认。
Possible materials
| 材料 | 支持峰 | Overlapping groups | 引用来源 |
|---|---|---|---|
| gold nanoparticles | 2001, 1638, 3252 | Alkyl C-H, Methacrylate | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 2001 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
这些分配背后的文献
-
Alkyl C-H 置信度 1.0
“(2011) irradiated CH usually assigned to C-O stretching in alcohols (Socrates, 2001).”
Barakoti 等 - 2021 - Formaldehyde Analysis in Non-Aqueous Methanol Solu DOI: 10.3389/fchem.2021.678112 -
Hydroxyl (O-H) 置信度 1.0
“Nuclear Instruments and Methods in Physics Research shows the direction of increase in absorbance of OH stretching 2001;B181:367-71.”
Determination of eugenol diffusion through LLDPE using FTIR-ATR flow cell and HPLC techniques DOI: 10.1016/j.polymer.2009.01.026 -
Acetate 置信度 1.0
“The peak at 1030 sponds to C O and C C stretching vibrations (Ray & Sarkar, 2001).”
Kasyapi 等 - 2013 - Bionanowhiskers from jute Preparation and charact DOI: 10.1016/j.carbpol.2012.10.021 -
Alkyl C-H 置信度 1.0
“CH stretching aldehyde - cm-1 2001 N=C=C carbodiamide N=C=C carbodiamide cm-1 1728 Weak CH bending aromatic compound Weak CH bending aromatic compound”
Leemarose 等 - 2021 - Sustainable Synthesis of Gold Nanoparticles and it DOI: 10.13005/ojc/370216 -
Ester 置信度 1.0
“ν(C=O) corresponds to the vibration of the residue E286 tochangesintheglycerolbackboneofthesurroundinglipids.The ν(C=O) undergoing a change in hydrogen bonding (Nyquist et al., light-induced change in absorption of the ester vibration 2001;”
Baserga 等 - 2022 - Membrane Protein Activity Induces Specific Molecul DOI: 10.3389/fmolb.2022.915328 -
Acetate 置信度 1.0
“phospholipids (PO symmetric stretch)/C-O stretch, and finally the output variables, i.e., microbial populations, were reduced 2 cm-1 cm-1) at 1,044 corresponding to lipids and polysaccharides from 900 (wavelength 1,800-900 to less than 110”
Rapid Microbial Quality Assessment of Chicken Liver Inoculated or Not With Salmonella Using FTIR Spectroscopy and Machine Learning DOI: 10.3389/fmicb.2020.623788 -
Hydroxyl (O-H) 置信度 1.0
“The band at 3258 is due to the stretching vibrations of the O-H groups while bands cm-1, cm-1, cm-1 at 2001 2291 and 2318 are characteristic of the C-C triple bond of alkynes.”
Fawzy - 2021 - Flotation separation of dravite from phlogopite us DOI: 10.37190/ppmp/138587 -
Alkyl C-H 置信度 1.0
“Journal Pre-proof could also be associated with an overtone of the CH deformation vibration (Socrates, 2001).”
Huang 等 - 2021 - Prediction of biochemical methane potential of urb DOI: 10.1016/j.scitotenv.2021.147959
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