What absorbs at 1296 cm⁻¹ in an FTIR spectrum?

クイックアンサー

A band near 1296 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.

可能性のある官能基アサイン

ランキングは蓄積された文献証拠を反映しており、単一の権威あるルールではありません。常にサンプルのコンテキストと照合して確認してください。

可能性のある材料

同じ文献プールがこのバンドと少なくとも1つの追加の特性ピークをサポートする場合にのみ、材料が表示されます。

スペクトルロジック

This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1296 cm⁻¹ is usually not enough for material identification by itself.

実使用例

この種のクエリは、ポリマー識別、未知のプラスチックスクリーニング、QCトラブルシューティング、リサイクル材料の検証、および文献に基づいたピーク帰属のレビューで一般的です。

よくある間違い

• 少なくとも1～2つの支持ピークを確認せずに、1つの孤立したバンドを材料の証拠として扱うこと。
• 重複を無視: 複数の官能基が同じ波数付近に寄与することがあります。
• 添加剤、ブレンド、酸化、または汚染がスペクトルを歪める可能性がある場合に検証を省略すること。

検証アドバイス

曖昧さが残る場合は、特にブレンド、劣化サンプル、充填ポリマーについて、DSC、GC-MS、またはTGAで仮説を検証してください。

これらのアサインの根拠となる文献

• Amide 信頼度 1.0

  “The charfrom cm-1 acteristic peak at 1296 indicates the C N stretching vibration of the aromatic Downloaded amine units.”

  A facile synthesis of poly(aniline-co-o-bromoaniline) copolymer: Characterization and application as semiconducting material DOI: 10.1142/S0217979216500089
• 信頼度 1.0

  “It is clear that carbon, oxygen, and phosof GNP-g-APP shows a peak at 1296 correspectrum”

  Phosphorization of exfoliated graphite for developing flame retardant ethylene vinyl acetate composites DOI: 10.1016/j.jmrt.2020.04.085
• Amide 信頼度 1.0

  “cm21 is generally agreed that the band at 1296 is caused by C-N single, C vN double, and C wN triple bonds were obsp21sp3 b-C”

  Wei - 2001 - Formation of beta-C3N4 crystals at low temperature DOI: 10.1063/1.1327603
• Amide 信頼度 1.0

  “The bands at 1296 implied the stretching mode of C-N, which is associated with the presence of povidone.”

  Assiry 等 - 2023 - Microstructural and Elemental Characterization of DOI: 10.3390/app13074517
• 信頼度 1.0

  “A negative band at 1296 is assigned C b g to the C-F stretching modes of fluorotyrosine in wild-type”

  Hydrogen Bonding in Human Manganese Superoxide Dismutase Containing 3-Fluorotyrosine DOI: 10.1529/biophysj.105.060616
• Alkyl C-H 信頼度 1.0

  “The Raman 3 cm-1 bands located at 1296 and 1454 originated from CH and CH deformation vibrations, respectively.”

  Optical photothermal infrared spectroscopy with simultaneously acquired Raman spectroscopy for two-dimensional microplastic identification DOI: 10.1038/s41598-022-23318-2
• C=n 信頼度 1.0

  “Comparatively strong doublet ATR-FTIR bands at ~1557 and ~1542 cm-1 and bands at 1296 and cm-1 814 of layers #2 and #5 (ascribed by a solid heart sign in inset (a) of Figure S1) were assigned to the -C=N, asymmetric -C-N, symmetric -C-N, an”

  Multi-Modal Compositional Analysis of Layered Paint Chips of Automobiles by the Combined Application of ATR-FTIR Imaging, Raman Microspectrometry, and SEM/EDX DOI: 10.3390/molecules24071381
• Acetate 信頼度 1.0

  “Furcm-1 (origithermore, the intensity of band at 1296 nating from the C-O stretching vibrations of phenoFigure 6.”

  Radoman 等 - 2015 - Effect of surface modified TiO2 nanoparticles on t DOI: 10.3144/expresspolymlett.2015.83