What absorbs at 762 cm⁻¹ in an FTIR spectrum?
A band near 762 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Ātra atbilde
A band near 762 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Iespējamie funkcionālo grupu piešķīrumi
| Funkcionālā grupa | Atbalstošie fakti | Citētie avoti | Augstākā pārliecība |
|---|---|---|---|
| Metal oxygen | 1 | 1 | 1,0 |
| C c single bond | 1 | 1 | 1,0 |
| Carbohydrate | 1 | 1 | 1,0 |
| Methoxy (OCH3) | 1 | 1 | 1,0 |
| Methacrylate | 1 | 1 | 1,0 |
| C-O single bond | 1 | 1 | 1,0 |
| Acetate | 1 | 1 | 1,0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 1,0 |
| Alkyl C-H | 1 | 1 | 1,0 |
| Silicon silicon | 1 | 1 | 1,0 |
| Silicon (Si) | 1 | 1 | 1,0 |
| C-S single bond | 1 | 1 | 1,0 |
| Alkene (C=C) | 1 | 0 | 1,0 |
| Siloxane (Si-O-Si) | 1 | 0 | 0,9 |
Rangs atspoguļo uzkrātos literatūras pierādījumus, nevis vienu autoritatīvu noteikumu. Vienmēr apstipriniet atbilstoši parauga kontekstam.
Iespējamie materiāli
| Materiāls | Atbalstošie pīķi | Pārklājošās grupas | Citētie avoti |
|---|---|---|---|
| Cellulose | 762, 1735, 1650 | Methoxy (OCH3), Carbohydrate | 1 |
Materiāli tiek parādīti tikai tad, ja šo joslu un vismaz vienu papildu raksturīgo pīķi atbalsta tā pati literatūras kopa.
Spektra loģika
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 762 cm⁻¹ is usually not enough for material identification by itself.
Reālās pasaules izmantošana
Šāda veida vaicājums ir izplatīts polimēru identificēšanā, nezināmas plastmasas skrīningā, kvalitātes kontroles problēmu risināšanā, pārstrādāto materiālu pārbaudē un ar literatūru pamatotā pīķu piešķīruma pārskatā.
Biežākās kļūdas
- Vienas izolētas joslas uzskatīšana par materiāla pierādījumu, nepārbaudot vismaz vienu vai divus atbalsta pīķus.
- Ignorējot pārklāšanos: vairākas funkcionālās grupas var dot ieguldījumu tuvu tam pašam viļņa skaitlim.
- Izlaist validāciju, ja piedevas, maisījumi, oksidācija vai piesārņojums var izkropļot spektru.
Verifikācijas padoms
Ja joprojām pastāv neskaidrība, apstipriniet hipotēzi ar DSC, GC-MS vai TGA, īpaši maisījumiem, noārdītiem paraugiem un pildītiem polimēriem.
Literatūra aiz šiem piešķīrumiem
-
C-S single bond pārliecība 1,0
“Copolymer (aqueous) (cm-1) (cm-1) Functional group Wave number Functional group Wave number S bending 762 C S stretching 532 C”
Dey Sadhu 等 - 2020 - Preparation and characterization of polyanilinea DOI: 10.1002/pc.25738 -
Silicon (Si) pārliecība 1,0
“The peaks at 1139.24 cm-1 and 1095.99 cm-1 are assigned to stretching vibration of Si-O, the peaks at 1031.25 cm-1 and 1008.16 cm-1 are assigned to stretching vibration of Si(Al)-O, the peaks at 787.56 cm-1 and 761.71 cm-1 are assigned to s”
Effects and Mechanism of Fe3+ on Flotation Separation of Feldspar and Epidote with Sodium Oleate at Natural pH DOI: 10.3390/separations9050110 -
pārliecība 1,0
“α-Phase are 762”
Abdullah 等 - 2014 - Effect of annealing process on the phase formation DOI: 10.1063/1.4895187 -
Alkyl C-H pārliecība 1,0
“Peaks at 762 and 721 cm-1 corresponded to out-of-plane symmetric deformations of the COOgroup and outof-plane C-H vibrations of bonded benzoate [47,48].”
Butova 等 - 2023 - In Situ FTIR Spectroscopy for Scanning Accessible DOI: 10.3390/nano13101675 -
pārliecība 1,0
“cm-1 absorption range was between 1100 to 400 and its characteristic absorption band at 951 is cm-1 cm-1 attributed to the Si-O group, while absorption band at 762 (Al-O group), 667 (Al-O-Al), 532, cm-1 and 459 (Si-O group) (Anton Beran, 20”
Fawzy - 2021 - Flotation separation of dravite from phlogopite us DOI: 10.37190/ppmp/138587 -
Acetate pārliecība 1,0
“1313.37 (C-N asymmetric bending), 1228.74 (C-O-C stretching), 1008.19 (C-O-C asymmetric stretching), 761.61 (Aromatic region in finger print).”
Kumar 等 - 2018 - Identification of Degradant Products of Saroglitaz DOI: 10.5530/ijper.52.4.74 -
Carbohydrate pārliecība 1,0
“The temperature programs for Comparison between commercial cellulose (CC) and 25∘ C dynamic tests were run from ambient temperature cellulose fiber (CF) shows that both celluloses have identical 700∘ 762cm-1 C.”
Liew 等 - 2015 - Synthesis and Characterization of Cellulose from G DOI: 10.1155/2015/212158 -
C c single bond pārliecība 1,0
“LLM confirmed rule peak-group candidate”
Miranda Sechi 和 Marques - 2017 - Preparation and Physicochemical, Structural and Mo DOI: 10.1590/1980-5373-MR-2016-1008
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