What absorbs at 665 cm⁻¹ in an FTIR spectrum?
A band near 665 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Snel antwoord
A band near 665 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Mogelijke functionele-groeptoewijzingen
| Functionele groep | Ondersteunende feiten | Geciteerde bronnen | Hoogste vertrouwen |
|---|---|---|---|
| Alkyl C-H | 3 | 3 | 1,0 |
| N h | 3 | 3 | 1,0 |
| Ring structure | 2 | 2 | 1,0 |
| Hydroxyl (O-H) | 2 | 1 | 1,0 |
| Metal oxygen | 2 | 1 | 1,0 |
| Amide | 1 | 1 | 1,0 |
| Methoxy (OCH3) | 1 | 1 | 1,0 |
| Methacrylate | 1 | 1 | 1,0 |
| C-O single bond | 1 | 1 | 1,0 |
| Acetate | 1 | 1 | 1,0 |
| Carbonate | 1 | 1 | 1,0 |
| Hydrogen bond | 1 | 1 | 1,0 |
| Metalloid oxygen | 1 | 1 | 0,85 |
| Alkene (C=C) | 1 | 1 | 0,8 |
| Sulfur | 1 | 0 | 1,0 |
| Thiol | 1 | 0 | 0,9 |
Ranglijst weerspiegelt cumulatief literatuurbewijs, niet één gezaghebbende regel. Bevestig altijd aan de hand van uw monsterecontext.
Mogelijke materialen
| Materiaal | Ondersteunende pieken | Overlappende groepen | Geciteerde bronnen |
|---|---|---|---|
| Chitosan | 665, 1650, 1655 | Alkyl C-H, Hydroxyl (O-H), N h | 2 |
| ZnO | 665, 1400, 3430 | Hydroxyl (O-H), Alkyl C-H | 1 |
| sodium alginate | 665, 1636, 1080 | Hydroxyl (O-H), Alkyl C-H | 1 |
Materialen worden alleen getoond wanneer dezelfde literatuurpool deze band en ten minste één extra karakteristieke piek ondersteunt.
Spectrumlogica
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 665 cm⁻¹ is usually not enough for material identification by itself.
Gebruik in de praktijk
Dit type query komt vaak voor bij polymeeridentificatie, screening van onbekende kunststoffen, probleemoplossing bij QC, verificatie van gerecycled materiaal en literatuurondersteunde beoordeling van piektoewijzing.
Veelgemaakte fouten
- Het behandelen van een enkele geïsoleerde band als bewijs van een materiaal zonder ten minste een of twee ondersteunende pieken te controleren.
- Overlap negeren: meerdere functionele groepen kunnen bijdragen rond hetzelfde golfgetal.
- Validatie overslaan wanneer additieven, mengsels, oxidatie of verontreiniging het spectrum kunnen verstoren.
Advies voor verificatie
Wanneer dubbelzinnigheid blijft bestaan, valideer de hypothese met DSC, GC-MS of TGA, vooral voor mengsels, gedegradeerde monsters en gevulde polymeren.
Literatuur achter deze toewijzingen
-
vertrouwen 1,0
“Er3+ with increasing the concentration of ions in the glass (300-665cm-1) termediate region which is ascribed to deformation of ΔT (>100°C) as well the higher values (which are higher than other the vibrational modes of the glass network wi”
Structural and optical properties of TeO2-Li2O-ZnO-Nb2O5-Er2O3 glass system DOI: 10.1016/j.jnoncrysol.2018.08.011 -
vertrouwen 1,0
“assigned to chain axis O(3) vibrations”
Khan 等 - 2004 - Effects of post-annealing on the infrared active p DOI: 10.1016/j.physc.2004.04.029 -
Metal oxygen vertrouwen 1,0
“665cm-1 confirmed Zn-O stretching vibrations A broad band at (2.5% Mn-doped ZnO), 3.61eV (5% Mn-doped ZnO), and (Almehizia et al., 2021).”
Khan 等 - 2022 - Microwave-Assisted Green Synthesis of Pure and Mn- DOI: 10.3389/fmats.2021.710155 -
Alkyl C-H vertrouwen 1,0
“The obvious peaks at 2926 and 2859 cm-1 correspond to organic compounds that cm-1 cm-1 The flattened peak at 1422 and the medium one at 665 are attributed to The flattened peak at 1422 cm-1 and the medium one at 665 cm-1 are attributed to c”
Technological and Functional Approaches Applied to Miniature Vessels with Pigment Traces: Two Middle Bronze Age Case Studies from Eastern Subcarpathians of Romania DOI: 10.3390/app13042093 -
Hydroxyl (O-H) vertrouwen 1,0
“amide-IV al.14 et by Gonzaga The broad and strong band located 665 amide-V cm-1 between 3490 and 3256 in the FTIR spectrum is attributed to the axial stretching of the O-H and N-H”
Gonzaga 等 - 2020 - Chitosan and Agaricus brasiliensis Polysaccharides DOI: 10.21577/0103-5053.20190264 -
vertrouwen 1,0
“The A magnification of this eV region cm-1 N-H peak observed at 665”
Gurumendi 等 - 2023 - Enhanced Chitosan Photoluminescence by Incorporati DOI: 10.1021/acsomega.2c08072 -
Ring structure vertrouwen 1,0
“The peak at 665 is assigned to out of plane vibrations involving ring structures (Jaouadi, M'sahli & Sakli, 2009), cm-1 the peak at 894 can be attributed to the presence of b-glycosidic linkages between the monosaccharides (Reddy, Ashok, Re”
Maache 等 - 2017 - Characterization of a novel natural cellulosic fib DOI: 10.1016/j.carbpol.2017.04.096 -
Alkyl C-H vertrouwen 1,0
“cm-1 The absorption at 1352 corresponding to the stretching,40 vibration of S=O and the presence of fucoidan Composite films sodium alginate-based elaborated cm-1 reported.41 sulfate groups at 835 was Also, the band cm-1 around 665 is attri”
Villacres 等 - 2023 - Preparation of Composite Films of Sodium Alginate- DOI: 10.21577/0103-5053.20230064
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