What absorbs at 3349 cm⁻¹ in an FTIR spectrum?
A band near 3349 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Ātra atbilde
A band near 3349 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Iespējamie funkcionālo grupu piešķīrumi
| Funkcionālā grupa | Atbalstošie fakti | Citētie avoti | Augstākā pārliecība |
|---|---|---|---|
| Hydroxyl (O-H) | 6 | 6 | 1,0 |
| N h | 3 | 3 | 1,0 |
| Secondary amine | 2 | 2 | 1,0 |
| Methoxy (OCH3) | 1 | 1 | 1,0 |
| Methacrylate | 1 | 1 | 1,0 |
| Acetate | 1 | 1 | 1,0 |
| C c single bond | 1 | 1 | 1,0 |
| C-O single bond | 1 | 1 | 1,0 |
| Protein | 1 | 1 | 1,0 |
| Hydrogen bond | 1 | 1 | 1,0 |
Rangs atspoguļo uzkrātos literatūras pierādījumus, nevis vienu autoritatīvu noteikumu. Vienmēr apstipriniet atbilstoši parauga kontekstam.
Iespējamie materiāli
| Materiāls | Atbalstošie pīķi | Pārklājošās grupas | Citētie avoti |
|---|---|---|---|
| TiO2 | 3349, 1700, 1093 | Hydroxyl (O-H), Methoxy (OCH3) | 1 |
| GO | 3349, 1720, 1182 | Hydroxyl (O-H), Methoxy (OCH3) | 1 |
| chitosan | 3349, 1650, 1655 | Hydroxyl (O-H), N h, Methoxy (OCH3) | 1 |
| TiO2 nanoparticles | 3349, 1700, 455 | Hydroxyl (O-H), Methoxy (OCH3), N h | 1 |
Materiāli tiek parādīti tikai tad, ja šo joslu un vismaz vienu papildu raksturīgo pīķi atbalsta tā pati literatūras kopa.
Spektra loģika
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 3349 cm⁻¹ is usually not enough for material identification by itself.
Reālās pasaules izmantošana
Šāda veida vaicājums ir izplatīts polimēru identificēšanā, nezināmas plastmasas skrīningā, kvalitātes kontroles problēmu risināšanā, pārstrādāto materiālu pārbaudē un ar literatūru pamatotā pīķu piešķīruma pārskatā.
Biežākās kļūdas
- Vienas izolētas joslas uzskatīšana par materiāla pierādījumu, nepārbaudot vismaz vienu vai divus atbalsta pīķus.
- Ignorējot pārklāšanos: vairākas funkcionālās grupas var dot ieguldījumu tuvu tam pašam viļņa skaitlim.
- Izlaist validāciju, ja piedevas, maisījumi, oksidācija vai piesārņojums var izkropļot spektru.
Verifikācijas padoms
Ja joprojām pastāv neskaidrība, apstipriniet hipotēzi ar DSC, GC-MS vai TGA, īpaši maisījumiem, noārdītiem paraugiem un pildītiem polimēriem.
Literatūra aiz šiem piešķīrumiem
-
Hydrogen bond pārliecība 1,0
“The strong peak at 3349 attributed to the intra-molecular hydrogen bonds for (3)O-H-O(5), as shown in Fig.”
Manuscript Preparation Instruction for Publishing in Computer Modeling in Engineering and Science (CMES) DOI: 10.3970/cmc.2018.03608 -
Hydroxyl (O-H) pārliecība 1,0
“After modification, a strong and wide band of O-H that overlapped with N-H band (3349 cm-1) cm-1.”
Synthesis and characterizations of o-nitrochitosan based biopolymer electrolyte for electrochemical devices DOI: 10.1371/journal.pone.0212066 -
Secondary amine pārliecība 1,0
“In peak at 1746 cm-1 cm-1 M4T2,the broad PVP peak FTIR spectrum at 3349 represents the stretching vibration M4T2,the broad PVP peak FTIR spectrum at 3349 cm-1 represents the stretching vibracm-1 of the secondary amine N-H group present in P”
TiO2 Nanoparticle Filler-Based Mixed-Matrix PES/CA Nanofiltration Membranes for Enhanced Desalination DOI: 10.3390/membranes11060433 -
N h pārliecība 1,0
“cm-1 vibration of the sulphonamide (3395 in pure furosemide, 3397 in physical mixtures), NH stretchingvibrationofthesecondaryaminegroup(3348cm-1 3349cm-1 inpurefurosemide, inphysical”
Kovacs 等 - 2020 - Influence of Aqueous Solubility-Enhancing Excipien DOI: 10.3390/pharmaceutics12040385 -
pārliecība 1,0
“3357 and Cd (3353 A decrease in the peak wavenumbers occurred in the spectra for Cu for Cu assigned at a band of 3349 cm-1, Pb (3330 cm-1) and Zn (3341 cm-1).”
Sensitivity and Calibration of the FT-IR Spectroscopy on Concentration of Heavy Metal Ions in River and Borehole Water Sources DOI: 10.3390/app10217785 -
Protein pārliecība 1,0
“The bands between 3349 and 3374 represents the secondary structure of the protein skeleton, which is often used for the quan-”
Tomczynska-Mleko 等 - 2023 - Co-Gelation of Pumpkin-Seed Protein with Egg-White DOI: 10.3390/foods12102030 -
Hydroxyl (O-H) pārliecība 1,0
“LLM confirmed rule peak-group candidate”
Reduced graphene Oxide/NiO based nano-composites for the efficient removal of alizarin dye, indigo dye and reduction of nitro aromatic compounds DOI: 10.1016/j.heliyon.2023.e17162 -
Hydroxyl (O-H) pārliecība 0,9
“Broadest absorption peak around 3349 mainly assigned to O-H stretching.”
Geng 等 - 2020 - Quality Attributes and Microstructure of Cell Wall DOI: 10.3136/fstr.26.281
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