What absorbs at 2120 cm⁻¹ in an FTIR spectrum?
A band near 2120 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Hurtigt svar
A band near 2120 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Mulige funktionelle gruppetildelinger
| Funktionel gruppe | Understøttende fakta | Citerede kilder | Højeste tillid |
|---|---|---|---|
| Silicon hydride | 4 | 3 | 1,0 |
| C#c | 3 | 3 | 1,0 |
| N h | 2 | 1 | 1,0 |
| Silicon (Si) | 2 | 1 | 1,0 |
| C c single bond | 1 | 1 | 1,0 |
| Ester | 1 | 1 | 1,0 |
| Borate | 1 | 1 | 1,0 |
| Boron nitrogen | 1 | 1 | 1,0 |
| Adsorbed carbon monoxide | 1 | 1 | 1,0 |
| Secondary amine | 1 | 0 | 1,0 |
Rangering afspejler akkumulerede litteraturbeviser, ikke en enkelt autoritativ regel. Bekræft altid mod din prøvekontekst.
Spektrumlogik
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 2120 cm⁻¹ is usually not enough for material identification by itself.
Anvendelse i virkeligheden
Denne type forespørgsel er almindelig ved polymeridentifikation, screening af ukendt plast, fejlfinding i kvalitetskontrol, verifikation af genanvendt materiale og litteraturunderstøttet gennemgang af peak-tildeling.
Almindelige fejl
- Behandling af et isoleret bånd som bevis på et materiale uden at kontrollere mindst en eller to understøttende toppe.
- Ignorerer overlap: flere funktionelle grupper kan bidrage nær samme bølgetal.
- Spring validering over, når additiver, blandinger, oxidation eller forurening kan forvrænge spektret.
Verifikationsrådgivning
Når tvetydighed fortsat består, valider hypotesen med DSC, GC-MS eller TGA, især for blandinger, nedbrudte prøver og fyldte polymerer.
Litteratur bag disse tildelinger
-
Adsorbed carbon monoxide tillid 1,0
“over Pt/SiO 2 Otherauthors,however,eitherhavenotobservedapeak The oxidation of carbon monoxide is one of the most incm¡1 at all (1, 12) or have not observed the peak to at 2120 tensely studied reactions in the history of catalysis.”
Fanson 等 - 2001 - Island formation during kinetic rate oscillations DOI: 10.1006/jcat.2001.3369 -
Boron nitrogen tillid 1,0
“=𝜇(1282cm-1)/𝜇(2120cm-1) × 5.5 × 16.5, out h-BN additive displayed typical yellow due to the 𝜇(1130cm-1), 𝜇(1282cm-1) 𝜇(2120cm-1) involvement of nitrogen impurities, which is inevitable where and 2120cm-1, in the synthesis cell.”
B–C Bond in Diamond Single Crystal Synthesized with h-BN Additive at High Pressure and High Temperature DOI: 10.1088/0256-307X/33/2/028101 -
Silicon (Si) tillid 1,0
“The 3 USC cm-1 absorption at around 2120 is always assigned to Si-H stretching vibrations.”
Peter 等 - 2013 - FTIR analysis of a-SiCNH films deposited by PECVD DOI: 10.1016/j.vacuum.2013.04.014 -
Ester tillid 1,0
“diesel treated wastewater shifted to 2120.26 This peak shift denotes the dilution and electron transfer effect of methyl ester in biodiesel to pure distilled water.”
Chemometric analysis of cow dung ash as an adsorbent for purifying biodiesel from waste cooking oil DOI: 10.1038/s41598-017-09881-z -
Silicon hydride tillid 1,0
“Explicit assignment: 'absorption peak at 2,120 corresponds to Si-H'”
Chen 等 - 2021 - Synthesis of a novel UV-curable prepolymer 1,3-bis DOI: 10.2478/msp-2021-0030 -
tillid 1,0
“In the presence of L-Arg, the ν CO cm-1, positive partial charge, most likely the neutral terminal amino group absorption bands are centered on 2120 and 2131 and there are cm-1.”
Horn 等 - 2014 - Fourier transform infrared spectroscopy study ofli DOI: 10.12688/f1000research.5836.1 -
C#c tillid 1,0
“Finally, the peaks at 2120 cm-1 that can be observed in the FTIR spectra of BC, HBC, and HBC/nZVI corresponded to the C≡C bonds in the Materials2022,15,6055 7of16 biochars [28].”
Biochar Nanocomposite as an Inexpensive and Highly Efficient Carbonaceous Adsorbent for Hexavalent Chromium Removal DOI: 10.3390/ma15176055 -
C#c tillid 1,0
“LLM confirmed rule peak-group candidate”
Phelan 等 - 2020 - Tracking glycosylation in live cells using FTIR sp DOI: 10.1016/j.talanta.2020.120737
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