What absorbs at 1348 cm⁻¹ in an FTIR spectrum?
A band near 1348 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
クイックアンサー
A band near 1348 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能性のある官能基アサイン
| 官能基 | 裏付け事実 | 引用元 | 最高信頼度 |
|---|---|---|---|
| N-O bond | 2 | 2 | 1.0 |
| Carboxyl (COOH) | 1 | 1 | 1.0 |
| Hydroxyl (O-H) | 1 | 1 | 1.0 |
| Nitro (NO2) | 1 | 1 | 1.0 |
| Secondary amine | 1 | 1 | 1.0 |
| C n single bond | 1 | 1 | 1.0 |
| Amide | 1 | 1 | 1.0 |
| Protein | 1 | 1 | 1.0 |
| Alkyl C-H | 1 | 1 | 1.0 |
ランキングは蓄積された文献証拠を反映しており、単一の権威あるルールではありません。常にサンプルのコンテキストと照合して確認してください。
可能性のある材料
| 素材 | 補助ピーク | 重複グループ | 引用元 |
|---|---|---|---|
| activated carbon | 1348, 1575, 1210 | Hydroxyl (O-H), Carboxyl (COOH) | 1 |
同じ文献プールがこのバンドと少なくとも1つの追加の特性ピークをサポートする場合にのみ、材料が表示されます。
スペクトルロジック
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1348 cm⁻¹ is usually not enough for material identification by itself.
実使用例
この種のクエリは、ポリマー識別、未知のプラスチックスクリーニング、QCトラブルシューティング、リサイクル材料の検証、および文献に基づいたピーク帰属のレビューで一般的です。
よくある間違い
- 少なくとも1～2つの支持ピークを確認せずに、1つの孤立したバンドを材料の証拠として扱うこと。
- 重複を無視: 複数の官能基が同じ波数付近に寄与することがあります。
- 添加剤、ブレンド、酸化、または汚染がスペクトルを歪める可能性がある場合に検証を省略すること。
検証アドバイス
曖昧さが残る場合は、特にブレンド、劣化サンプル、充填ポリマーについて、DSC、GC-MS、またはTGAで仮説を検証してください。
これらのアサインの根拠となる文献
-
Alkyl C-H 信頼度 1.0
“Component loadings indicate that POM has a tendency for higher absorbance than the cm-1, silt at the broad peak around 1348 that indicates aliphatics and phenolics.”
Calderon 等 - 2011 - Chemical Differences in Soil Organic Matter Fracti DOI: 10.2136/sssaj2009.0375 -
N-O bond 信頼度 1.0
“The metastable solid phase transition from the initial solid to a metastable solid phase of NaNO (cid:3)87% (cid:3)96% deliquesced completely in the region from to RH according to the fact that the (cid:2) 3cm-1 3-NO band showed two overlap”
Lu 等 - 2008 - Molecular events in deliquescence and efflorescenc DOI: 10.1063/1.2973623(cid:5) -
信頼度 1.0
“Not identified by CR isotope labeling of the of lysine, but was assigned to a related mode cm-1 with the 1348 band of BR.”
Maeda 等 - 1999 - Chromophore-protein-water interactions in the L in DOI: 10.1021/bi9907072 -
Protein 信頼度 1.0
“Stained sections were 1348cm1 and associated with collagen as well as the peak at”
Maribel Mata-Miranda 等 - 2019 - Characterization of the Biological Fingerprint and DOI: 10.1155/2019/1241452 -
Amide 信頼度 1.0
“0.0001 1452.136 1451.171 8 3 str 0.506 1401.995 9 1401.995 -COOC=O of 0.036 1345.106 10 Carboxyl groups COO and asymmetric C-N stretching 1347.998 3-)”
Martinez-Cuazitl 等 - 2023 - Clinical, Biochemical, and ATR-FTIR Spectroscopic DOI: 10.1155/2023/3423183 -
信頼度 1.0
“Explicit assignment: 'characteristic peaks at ~1348 cm-1 (D band)'.”
Effect of Iron Loading on the Catalytic Activity of Fe/N-Doped Reduced Graphene Oxide Catalysts via Irradiation DOI: 10.3390/app11010205 -
N-O bond 信頼度 1.0
“The band experienced at 1348 can be attributed adsorption capacity of activated carbon for the adsorption to the N - O symmetric stretch in the nitro compounds.”
Rutto 等 - 2019 - Adsorption of lead ions onto chemically activated DOI: 10.24425/aep.2019.130245 -
Hydroxyl (O-H) 信頼度 1.0
“[37] found that the ATR-FTIR spectra of 2O 3-adsorbed 1617 cm-1, 1458 cm-1, and 436 cm-1, respectively, indicating that Fe-O, CH3/COO and -OH in HFO cm-1 humic acid showed two new bands at 1348 and 1470 during the initial time points, which”
Removal of Tetracycline by Hydrous Ferric Oxide: Adsorption Kinetics, Isotherms, and Mechanism DOI: 10.3390/ijerph16224580
このバンドを持つスペクトルがありますか？
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