What absorbs at 1138 cm⁻¹ in an FTIR spectrum?
A band near 1138 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Ātra atbilde
A band near 1138 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Iespējamie funkcionālo grupu piešķīrumi
| Funkcionālā grupa | Atbalstošie fakti | Citētie avoti | Augstākā pārliecība |
|---|---|---|---|
| Metal oxygen | 2 | 2 | 1,0 |
| Methoxy (OCH3) | 2 | 2 | 1,0 |
| Methacrylate | 2 | 2 | 1,0 |
| C-O single bond | 2 | 2 | 1,0 |
| Acetate | 2 | 2 | 1,0 |
| Thiol | 1 | 1 | 1,0 |
| Hydroxyl (O-H) | 1 | 1 | 1,0 |
| Phosphate (PO4) | 1 | 1 | 1,0 |
| Carbonyl (C=O) | 1 | 1 | 1,0 |
| Amide | 1 | 1 | 1,0 |
Rangs atspoguļo uzkrātos literatūras pierādījumus, nevis vienu autoritatīvu noteikumu. Vienmēr apstipriniet atbilstoši parauga kontekstam.
Iespējamie materiāli
| Materiāls | Atbalstošie pīķi | Pārklājošās grupas | Citētie avoti |
|---|---|---|---|
| CeO2 | 1138, 1554, 1630 | Methacrylate, Methoxy (OCH3), C-O single bond | 1 |
| PEG | 1138, 1650, 1342 | Methacrylate, C-O single bond, Methoxy (OCH3) | 1 |
Materiāli tiek parādīti tikai tad, ja šo joslu un vismaz vienu papildu raksturīgo pīķi atbalsta tā pati literatūras kopa.
Spektra loģika
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1138 cm⁻¹ is usually not enough for material identification by itself.
Reālās pasaules izmantošana
Šāda veida vaicājums ir izplatīts polimēru identificēšanā, nezināmas plastmasas skrīningā, kvalitātes kontroles problēmu risināšanā, pārstrādāto materiālu pārbaudē un ar literatūru pamatotā pīķu piešķīruma pārskatā.
Biežākās kļūdas
- Vienas izolētas joslas uzskatīšana par materiāla pierādījumu, nepārbaudot vismaz vienu vai divus atbalsta pīķus.
- Ignorējot pārklāšanos: vairākas funkcionālās grupas var dot ieguldījumu tuvu tam pašam viļņa skaitlim.
- Izlaist validāciju, ja piedevas, maisījumi, oksidācija vai piesārņojums var izkropļot spektru.
Verifikācijas padoms
Ja joprojām pastāv neskaidrība, apstipriniet hipotēzi ar DSC, GC-MS vai TGA, īpaši maisījumiem, noārdītiem paraugiem un pildītiem polimēriem.
Literatūra aiz šiem piešķīrumiem
-
Acetate pārliecība 1,0
“cm-1 strong band at 792 Bands at 1138 and 610 are assigned to C-O and 2 3 m Ti-O, respectively.”
Errington 等 - 2010 - Synthesis and Structure of the Alkoxido-Titanium P DOI: 10.1007/s10876-010-0329-3 -
Amide pārliecība 1,0
“*** II/COO(cid:3) Amide stretching 1188.83±0.08 1195.40±0.05 0.466±0.025 0.324±0.011 *** *** II/COO(cid:3) Amide stretching 1137.97±0.14 1141.26±0.12 0.649±0.012 0.275±0.010 II/COO(cid:3) Amide stretching 1065.34±0.23 1.084±0.012”
Differentiation in MALDI-TOF MS and FTIR spectra between two pathovars of Xanthomonas oryzae DOI: 10.1016/j.saa.2014.06.056 -
Acetate pārliecība 1,0
“The ratio A/B also increases for all the 1297 associated with chain vibrations, and the cm-1 cm-1 films, treated as there exist more non-hydrogen-bonded bands at 1138 and 832 assigned to the asymunmodified C-O-C carbonyls, in comparison to”
Effect of PEG grafting density on surface properties of polyurethane substrata and the viability of osteoblast and fibroblast cells DOI: 10.1007/s10856-022-06668-1 -
Phosphate (PO4) pārliecība 1,0
“12, the bands at 1138 and 1059 are P-O-C assigned to the stretching vibration of and PO 2/PO 3”
Functional group effect on flame retardancy, thermal, and mechanical properties of organophosphorus-based magnesium oxysulfate whiskers as a flame retardant in polypropylene DOI: 10.1039/c7ra02863f -
pārliecība 1,0
“Moreover, the bands at 1009, 1122, and at 1138cm-1 region [21, 22], absorption peaks related to Er doping in were ascribed to stretching of Ti-O-C [17].”
Gokdemir 等 - 2014 - Structural Modification of Sol-Gel Synthesized V2O DOI: 10.1155/2014/795384 -
Hydroxyl (O-H) pārliecība 1,0
“cm-1), cm-1), biomarkers were (~980 Oligosaccharide C-OH stretching band (~1138 IntegrativeBiologyAcceptedManuscript cm-1), cm-1), Deoxyribose (~1188 Amide III (~1242 In-plane CH bending vibration from the”
Jin 等 - 2017 - Fingerprinting microbiomes towards screening for m DOI: 10.1039/C7IB00009J. -
Thiol pārliecība 1,0
“in the intensity of this band correlates with one of 1138 Thus, it is obviously that this band is associated with n(SH) coordinated H 2S.”
Martirosyan 等 - 2021 - Low Temperature Spectroscopic Study of the Sulfide DOI: 10.6060/mhc214035m -
pārliecība 0,5
“From table 1, incomplete assignment”
Antioxidant and antidiabetic properties of biocompatible ceria oxide (CeO2) nanoparticles in mouse fibroblast NIH3T3 and insulin resistant HepG2 cells DOI: 10.1016/j.ceramint.2020.11.230
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