What absorbs at 824 cm⁻¹ in an FTIR spectrum?

Quick answer

A band near 824 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.

可能的官能团归属

排名反映了累积的文献证据，而非单一的权威规则。请始终对照您的样品背景进行确认。

Possible materials

Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.

Spectrum logic

This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 824 cm⁻¹ is usually not enough for material identification by itself.

Real-world usage

This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.

Common mistakes

• Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
• Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
• Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.

Verification advice

When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.

这些分配背后的文献

• Oxygen heterocycle 置信度 1.0

  “LLM confirmed rule peak-group candidate”

  Mudri 等 - 2020 - Comparative Study of Aromatic and Cycloaliphatic I DOI: 10.3390/polym12071494
• Silicon (Si) 置信度 1.0

  “ences corresponding increase in absorption peaks at 824 and 1055 In the mean time, a non-porous sample (c-Si) showed insignificant to the Si O Si vibration mode.”

  A combination of electroless and electrochemical etching methods for enhancing the uniformity of porous silicon substrate for light detection application DOI: 10.1016/j.apsusc.2012.03.056
• Alkyl C-H 置信度 1.0

  “C-H rocking of pure PVA is considered the cm-1 peak at 824 [31].”

  From Green Remediation to Polymer Hybrid Fabrication with Improved Optical Band Gaps DOI: 10.3390/ijms20163910
• 置信度 1.0

  “The peaks at 746 and 824 cm-1 in the UiO-66 framework, Zr-µ3-OH stretching and OH bending modes, respectively [46].”

  Butova 等 - 2023 - In Situ FTIR Spectroscopy for Scanning Accessible DOI: 10.3390/nano13101675
• C c single bond 置信度 1.0

  “In the spectra obtained after the cut-off at 3 kDa, the only signals related to proteins are the out-of-ring breathing of cm-1), cm-1), tyrosine (824 the C-C stretching of the proline ring (926 the C-C stretching cm-1),”

  The Role of the Preanalytical Step for Human Saliva Analysis via Vibrational Spectroscopy DOI: 10.3390/metabo13030393
• Alkyl C-H 置信度 1.0

  “In order to perform semi-quantitative analyses, the peaks were normalised cm-1 using the peak located at ~824 attributed to the C-H deformation of the PPTA sequence aging duration.”

  Derombise 等 - 2009 - Degradation of Technora aramid fibres in alkaline DOI: 10.1016/j.polymdegradstab.2009.07.021
• Alkyl C-H 置信度 1.0

  “Figure 4: FTIR spectrum of as-received Technora T240 fibres cm-1 The peaks were normalised using the peak located at ~824 attributed to the C-H deformation of”

  Influence of finish treatment on the durability of aramid fibers aged under an alkaline environment DOI: 10.1002/app.31534
• C-S single bond 置信度 1.0

  “The peak cm-1 824 is responsible for the C-S stretching vibrations at 7.35 ppm (peak j) is attributed to the protons at position of thiophene structures.”

  Doan 等 - 2022 - Synthesis of Conjugated Molecules Based on Dithien DOI: 10.21577/0103-5053.20220031