What absorbs at 824 cm⁻¹ in an FTIR spectrum?
A band near 824 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Snel antwoord
A band near 824 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Mogelijke functionele-groeptoewijzingen
| Functionele groep | Ondersteunende feiten | Geciteerde bronnen | Hoogste vertrouwen |
|---|---|---|---|
| Alkyl C-H | 7 | 7 | 1,0 |
| Aromatic ring | 2 | 2 | 1,0 |
| Carbon dioxide | 1 | 1 | 1,0 |
| N h | 1 | 1 | 1,0 |
| Secondary amine | 1 | 1 | 1,0 |
| C n single bond | 1 | 1 | 1,0 |
| Amide | 1 | 1 | 1,0 |
| Nitro (NO2) | 1 | 1 | 1,0 |
| Alkene (C=C) | 1 | 1 | 1,0 |
| C-S single bond | 1 | 1 | 1,0 |
| C c single bond | 1 | 1 | 1,0 |
| Hydroxyl (O-H) | 1 | 1 | 1,0 |
| Siloxane (Si-O-Si) | 1 | 1 | 1,0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 1,0 |
| Silicon (Si) | 1 | 1 | 1,0 |
| Oxygen heterocycle | 1 | 1 | 1,0 |
| C=n | 1 | 0 | 1,0 |
Ranglijst weerspiegelt cumulatief literatuurbewijs, niet één gezaghebbende regel. Bevestig altijd aan de hand van uw monsterecontext.
Mogelijke materialen
| Materiaal | Ondersteunende pieken | Overlappende groepen | Geciteerde bronnen |
|---|---|---|---|
| polyurethane | 824, 2270, 1700 | Alkyl C-H, N h | 1 |
| saliva | 824, 1648, 1664 | Alkyl C-H | 1 |
Materialen worden alleen getoond wanneer dezelfde literatuurpool deze band en ten minste één extra karakteristieke piek ondersteunt.
Spectrumlogica
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 824 cm⁻¹ is usually not enough for material identification by itself.
Gebruik in de praktijk
Dit type query komt vaak voor bij polymeeridentificatie, screening van onbekende kunststoffen, probleemoplossing bij QC, verificatie van gerecycled materiaal en literatuurondersteunde beoordeling van piektoewijzing.
Veelgemaakte fouten
- Het behandelen van een enkele geïsoleerde band als bewijs van een materiaal zonder ten minste een of twee ondersteunende pieken te controleren.
- Overlap negeren: meerdere functionele groepen kunnen bijdragen rond hetzelfde golfgetal.
- Validatie overslaan wanneer additieven, mengsels, oxidatie of verontreiniging het spectrum kunnen verstoren.
Advies voor verificatie
Wanneer dubbelzinnigheid blijft bestaan, valideer de hypothese met DSC, GC-MS of TGA, vooral voor mengsels, gedegradeerde monsters en gevulde polymeren.
Literatuur achter deze toewijzingen
-
Oxygen heterocycle vertrouwen 1,0
“LLM confirmed rule peak-group candidate”
Mudri 等 - 2020 - Comparative Study of Aromatic and Cycloaliphatic I DOI: 10.3390/polym12071494 -
Silicon (Si) vertrouwen 1,0
“ences corresponding increase in absorption peaks at 824 and 1055 In the mean time, a non-porous sample (c-Si) showed insignificant to the Si O Si vibration mode.”
A combination of electroless and electrochemical etching methods for enhancing the uniformity of porous silicon substrate for light detection application DOI: 10.1016/j.apsusc.2012.03.056 -
Alkyl C-H vertrouwen 1,0
“C-H rocking of pure PVA is considered the cm-1 peak at 824 [31].”
From Green Remediation to Polymer Hybrid Fabrication with Improved Optical Band Gaps DOI: 10.3390/ijms20163910 -
vertrouwen 1,0
“The peaks at 746 and 824 cm-1 in the UiO-66 framework, Zr-µ3-OH stretching and OH bending modes, respectively [46].”
Butova 等 - 2023 - In Situ FTIR Spectroscopy for Scanning Accessible DOI: 10.3390/nano13101675 -
C c single bond vertrouwen 1,0
“In the spectra obtained after the cut-off at 3 kDa, the only signals related to proteins are the out-of-ring breathing of cm-1), cm-1), tyrosine (824 the C-C stretching of the proline ring (926 the C-C stretching cm-1),”
The Role of the Preanalytical Step for Human Saliva Analysis via Vibrational Spectroscopy DOI: 10.3390/metabo13030393 -
Alkyl C-H vertrouwen 1,0
“In order to perform semi-quantitative analyses, the peaks were normalised cm-1 using the peak located at ~824 attributed to the C-H deformation of the PPTA sequence aging duration.”
Derombise 等 - 2009 - Degradation of Technora aramid fibres in alkaline DOI: 10.1016/j.polymdegradstab.2009.07.021 -
Alkyl C-H vertrouwen 1,0
“Figure 4: FTIR spectrum of as-received Technora T240 fibres cm-1 The peaks were normalised using the peak located at ~824 attributed to the C-H deformation of”
Influence of finish treatment on the durability of aramid fibers aged under an alkaline environment DOI: 10.1002/app.31534 -
C-S single bond vertrouwen 1,0
“The peak cm-1 824 is responsible for the C-S stretching vibrations at 7.35 ppm (peak j) is attributed to the protons at position of thiophene structures.”
Doan 等 - 2022 - Synthesis of Conjugated Molecules Based on Dithien DOI: 10.21577/0103-5053.20220031
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