What absorbs at 3079 cm⁻¹ in an FTIR spectrum?
A band near 3079 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 5 cited sources
Réponse rapide
A band near 3079 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Attributions possibles de groupes fonctionnels
| Groupe fonctionnel | Faits à l'appui | Sources citées | Confiance maximale |
|---|---|---|---|
| Alkyl C-H | 2 | 2 | 1,0 |
| Alkene (C=C) | 2 | 1 | 1,0 |
| Ring structure | 1 | 1 | 1,0 |
| Sulfur heterocycle | 1 | 1 | 1,0 |
| Protein | 1 | 1 | 1,0 |
| Carboxyl (COOH) | 1 | 1 | 1,0 |
| Amide | 1 | 1 | 1,0 |
| N h | 1 | 1 | 1,0 |
| C c single bond | 1 | 1 | 1,0 |
Le classement reflète les preuves bibliographiques accumulées, et non une règle faisant autorité. Confirmez toujours dans le contexte de votre échantillon.
Logique du spectre
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 3079 cm⁻¹ is usually not enough for material identification by itself.
Utilisation réelle
Ce type de requête est courant dans l'identification des polymères, le criblage des plastiques inconnus, le dépannage du contrôle qualité, la vérification des matériaux recyclés et l'examen de l'attribution des pics appuyée par la littérature.
Erreurs courantes
- Traiter une bande isolée comme preuve d'un matériau sans vérifier au moins un ou deux pics de support.
- Ignorer le chevauchement : plusieurs groupes fonctionnels peuvent contribuer près du même nombre d'onde.
- Sauter la validation lorsque des additifs, des mélanges, l'oxydation ou la contamination peuvent déformer le spectre.
Conseil de vérification
Lorsque l'ambiguïté persiste, validez l'hypothèse avec DSC, GC-MS ou TGA, en particulier pour les mélanges, les échantillons dégradés et les polymères chargés.
Bibliographie derrière ces attributions
-
C c single bond confiance 1,0
“The C C bonds appear in the weak bands 2931 and 3079cm-1 ∼1635cm-1 at (C C H) and (C C).”
Font 等 - 2007 - Fourier transform infrared spectroscopy as a suita DOI: 10.1016/j.aca.2007.07.021 -
confiance 1,0
“In GaAs grown by liquid encapsulation Czochralski (LEC), the peaks at 3079.2 and 983.3cm(cid:2)1 due to the stretching and wagging mode of N-H were observed at 7K, where its concentration was in 1013cm(cid:2)3 1012 the range from to [15].”
Nishimura 等 - 2007 - Electrical properties of GaAsN film grown by chemi DOI: 10.1016/j.physb.2007.08.183 -
Amide confiance 1,0
“The absorption of amide B at 3079 showed acid soluble collagen content of 3.7 ± 0.8% of was related to the asymmetric stretching vibrations of C-H the wet mass weight of the skin and protein content of”
Valorization of Salmo salar Skin Waste for the Synthesis of Angiotensin Converting Enzyme-1 (ACE1) Inhibitory Peptides DOI: 10.1007/s12649-023-02141-4 -
Alkyl C-H confiance 1,0
“LLM confirmed rule peak-group candidate”
Rapid Classification and Recognition Method of the Species and Chemotypes of Essential Oils by ATR-FTIR Spectroscopy Coupled with Chemometrics DOI: 10.3390/molecules27175618 -
Sulfur heterocycle confiance 1,0
“A peak at 3079 cm-1 in the FTIR spectra of monomer TEBS is due to cm´1 thiophene ring.”
Enzyme-Catalyzed Synthesis of Water-Soluble [1.0]Conjugated Poly[2-(3-thienyl)-Ethoxy-4-Butylsulfonate] DOI: 10.3390/polym8040139
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