What absorbs at 745 cm⁻¹ in an FTIR spectrum?
A band near 745 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Ātra atbilde
A band near 745 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Iespējamie funkcionālo grupu piešķīrumi
| Funkcionālā grupa | Atbalstošie fakti | Citētie avoti | Augstākā pārliecība |
|---|---|---|---|
| Alkyl C-H | 3 | 3 | 1,0 |
| Metal oxygen | 3 | 3 | 1,0 |
| Chlorine | 3 | 3 | 1,0 |
| Hydroxyl (O-H) | 2 | 2 | 1,0 |
| C-O single bond | 2 | 2 | 1,0 |
| Hydrogen bond | 1 | 1 | 1,0 |
| Phosphate (PO4) | 1 | 1 | 1,0 |
| C-S single bond | 1 | 1 | 1,0 |
| Siloxane (Si-O-Si) | 1 | 1 | 1,0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 1,0 |
| Silicon (Si) | 1 | 1 | 1,0 |
| Boron nitrogen | 1 | 1 | 0,9 |
| Aromatic ring | 1 | 1 | 0,7 |
Rangs atspoguļo uzkrātos literatūras pierādījumus, nevis vienu autoritatīvu noteikumu. Vienmēr apstipriniet atbilstoši parauga kontekstam.
Iespējamie materiāli
| Materiāls | Atbalstošie pīķi | Pārklājošās grupas | Citētie avoti |
|---|---|---|---|
| TiO2 | 745, 1700, 1093 | Metal oxygen, Hydroxyl (O-H), Alkyl C-H | 1 |
| TiO | 745, 1730, 1699 | Alkyl C-H, Hydroxyl (O-H), Metal oxygen | 1 |
Materiāli tiek parādīti tikai tad, ja šo joslu un vismaz vienu papildu raksturīgo pīķi atbalsta tā pati literatūras kopa.
Spektra loģika
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 745 cm⁻¹ is usually not enough for material identification by itself.
Reālās pasaules izmantošana
Šāda veida vaicājums ir izplatīts polimēru identificēšanā, nezināmas plastmasas skrīningā, kvalitātes kontroles problēmu risināšanā, pārstrādāto materiālu pārbaudē un ar literatūru pamatotā pīķu piešķīruma pārskatā.
Biežākās kļūdas
- Vienas izolētas joslas uzskatīšana par materiāla pierādījumu, nepārbaudot vismaz vienu vai divus atbalsta pīķus.
- Ignorējot pārklāšanos: vairākas funkcionālās grupas var dot ieguldījumu tuvu tam pašam viļņa skaitlim.
- Izlaist validāciju, ja piedevas, maisījumi, oksidācija vai piesārņojums var izkropļot spektru.
Verifikācijas padoms
Ja joprojām pastāv neskaidrība, apstipriniet hipotēzi ar DSC, GC-MS vai TGA, īpaši maisījumiem, noārdītiem paraugiem un pildītiem polimēriem.
Literatūra aiz šiem piešķīrumiem
-
Silicon (Si) pārliecība 1,0
“In the Al-MCM-41/UiO-66 (2) spectra, the absorption peak cm-1 appeared at wave number 744.55 indicates the vibration of the Si-O-Si molecule.”
Synthesis and catalytic activity of mesoporous Al-MCM-41/UiO-66 for esterification of oleic acid DOI: 10.1063/1.5082500 -
Alkyl C-H pārliecība 1,0
“ran'sstrongestvibrationalband,theν vibrationalbandnear As stated, a second method was also used to analyze 19 745cm-1 C-H corresponding to the out-of-plane bend (Shiand/or corroborate the different stages of the burn, whereby manouchi, 1972”
Banach 等 - 2021 - Dynamic infrared gas analysis from longleaf pine f DOI: 10.5194/amt-14-2359-2021 -
pārliecība 1,0
“cm-1 cm-1 cm-1 3284.2 (N-H stretching), 1672.0 (C=O stretching), 1591.8 (N-H bending), 1322.5 stretching), 1442.1 cm-1 (S-O stretching) and 744.6 cm-1 (C-Cl stretching).”
Garbacz 和 Wesolowski - 2018 - DSC, FTIR and Raman Spectroscopy Coupled with Mult DOI: 10.3390/molecules23092136 -
C-O single bond pārliecība 1,0
“and the lowest peak shifted from 745 to from 773 to concentration is due to (1) dilution of ether groups with the 740cm-1.”
Kim 等 - 2020 - Lithium Salt Dissociation in Diblock Copolymer Ele DOI: 10.3389/fenrg.2020.569442 -
C-S single bond pārliecība 1,0
“LiTFSI spectrum manifests two weak peaks at 745 and 804 The first peak is S-N stretching mode, whereas the latter peak is a combination of C-S stretching and S-N asymmetric Polymers 2016, 8, 179 10 of 16”
Liew 等 - 2016 - Poly(Acrylic acid)-Based Hybrid Inorganic-Organic DOI: 10.3390/polym8050179 -
Metal oxygen pārliecība 1,0
“In the spectrum of ZnMOF-BTA, metallic-oxygen bands are observed at 435 cm-1 and 463 cm-1 and are assigned to stretching vibrations of Zn-O bonds in the MOF [32], and bands observed at 745 cm-1 and 753 cm-1 correspond to the characteristic”
Synthesis, Characterization and Investigation of Anticorrosion Properties of an Innovative Metal–Organic Framework, ZnMOF-BTA, on Carbon Steel in HCl Solution DOI: 10.3390/coatings12091288 -
Phosphate (PO4) pārliecība 1,0
“The bands at around 745 assigned to asymmetric stretching vibrations of the P-O- (Moustafa et al., P rings 1998) The bands at around cm-1 910 are related to P-O-P symmetric stretch-”
Saddeek 和 Abo-Naf - 2012 - Influence of MoO3 on the Structure of Lithium Alum DOI: 10.2478/v10168-012-0043-2 -
C-O single bond pārliecība 1,0
“cm-1 cm-1 C-OH is related to of primary and secondary The advent frequency bands at 745 and 540”
Enhanced sunlight photocatalytic activity and biosafety of marine-driven synthesized cerium oxide nanoparticles DOI: 10.1038/s41598-021-94327-w
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