What absorbs at 3614 cm⁻¹ in an FTIR spectrum?
A band near 3614 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 5 cited sources
Jawapan pantas
A band near 3614 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Penetapan kumpulan berfungsi yang mungkin
| Kumpulan berfungsi | Fakta sokongan | Sumber dipetik | Keyakinan tertinggi |
|---|---|---|---|
| Hydroxyl (O-H) | 4 | 4 | 1.0 |
| Metal hydroxyl | 2 | 1 | 1.0 |
| Hydrogen bond | 1 | 1 | 1.0 |
Pemeringkatan mencerminkan bukti literatur terkumpul, bukan satu peraturan berwibawa. Sentiasa sahkan terhadap konteks sampel anda.
Bahan yang mungkin
| Bahan | Puncak sokongan | Kumpulan bertindih | Sumber dipetik |
|---|---|---|---|
| LDPE | 3614, 1720, 1737 | Hydroxyl (O-H) | 1 |
Bahan hanya dipaparkan apabila kumpulan literatur yang sama menyokong jalur ini dan sekurang-kurangnya satu puncak ciri tambahan.
Logik spektrum
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 3614 cm⁻¹ is usually not enough for material identification by itself.
Penggunaan dunia sebenar
Jenis pertanyaan ini biasa dalam pengenalpastian polimer, saringan plastik tidak diketahui, penyelesaian masalah QC, pengesahan bahan kitar semula, dan semakan tugasan puncak yang disokong oleh literatur.
Kesilapan biasa
- Menganggap satu jalur terpencil sebagai bukti bahan tanpa memeriksa sekurang-kurangnya satu atau dua puncak sokongan.
- Mengabaikan pertindihan: pelbagai kumpulan berfungsi boleh menyumbang berhampiran nombor gelombang yang sama.
- Melangkau pengesahan apabila bahan tambahan, campuran, pengoksidaan, atau pencemaran boleh memesongkan spektrum.
Nasihat pengesahan
Apabila kekaburan masih ada, sahkan hipotesis dengan DSC, GC-MS, atau TGA, terutamanya untuk campuran, sampel terdegradasi, dan polimer terisi.
Literatur di sebalik penetapan ini
-
Hydroxyl (O-H) keyakinan 1.0
“(2005) (3619 Based on these observations we classify the FTIR absorption H/106Si cm-1 at C = 2300 and 3614 at 50 000 and 15 000 peaks in the OH vibration region into 4 classes.”
Nishihara 等 - 2008 - Effect of chemical environment on the hydrogen-rel DOI: 10.2138/am.2008.2653 -
Hydroxyl (O-H) keyakinan 1.0
“These findings suggest that CPEF-6 has the ability to degrade polyethylene, and thus For the control, critical characteristic absorption bands were assigned from 3752 to can cause certain damage to the surface of LDPE, while heat-treated LD”
Gong 等 - 2023 - Biodegradation of Low Density Polyethylene by the DOI: 10.3390/jof9060605 -
Hydroxyl (O-H) keyakinan 1.0
“For sample plates addition to the primary OH absorption bands of muscovite 3614cm-1, with large interference fringes, we attempted to reduce their (Fig.”
Kronenberg 等 - 2017 - Synchrotron FTIR imaging of OH in quartz mylonites DOI: 10.5194/se-8-1025-2017 -
Hydrogen bond keyakinan 1.0
“The peak at 3614 cm-1 represents the interlayer hydrogen bonding, corresponding Polymers2021,13,897 7of22 to the stretching vibration of the OH coordinated octahedral layer of Al+Mg [18].”
On the Use of OPEFB-Derived Microcrystalline Cellulose and Nano-Bentonite for Development of Thermoplastic Starch Hybrid Bio-Composites with Improved Performance DOI: 10.3390/polym13060897 -
keyakinan 1.0
“Na-ATP has characteristic peaks at 3614 and 3545 which are attributed to the stretching vibrations of Al-OH and Fe-OH, respectively.”
Investigation on the Potential Application of Na-Attapulgite as an Excipient in Domperidone Sustained-Release Tablets DOI: 10.3390/molecules27238266
Ada spektrum dengan jalur ini?
Muat naik spektrum FTIR anda dan dapatkan laporan tafsiran penuh — penetapan puncak dengan petikan literatur, padanan perpustakaan, dan rantaian bukti berkadar keyakinan — dalam beberapa saat.