What absorbs at 3105 cm⁻¹ in an FTIR spectrum?
A band near 3105 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 5 cited sources
Quick answer
A band near 3105 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能的官能团归属
| 官能团 | 支持性事实 | 引用来源 | 最高置信度 |
|---|---|---|---|
| Alkyl C-H | 2 | 2 | 1.0 |
| Sulfur heterocycle | 1 | 1 | 1.0 |
| Ring structure | 1 | 1 | 1.0 |
| Nitrogen heterocycle | 1 | 1 | 1.0 |
| N h | 1 | 1 | 1.0 |
| C c single bond | 1 | 1 | 1.0 |
排名反映了累积的文献证据，而非单一的权威规则。请始终对照您的样品背景进行确认。
Possible materials
| 材料 | 支持峰 | Overlapping groups | 引用来源 |
|---|---|---|---|
| ionic liquids | 3105, 938, 1040 | Alkyl C-H, Ring structure | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 3105 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
这些分配背后的文献
-
C c single bond 置信度 1.0
“al.29 band at 3105 reported by Pace et who assigned it as the combination band of the C-C 47 48 cm-1) cm-1).”
Blue-Shifted Hydrogen Bonding in the Gas Phase CH/D3CN●●●HCCl3 Complexes DOI: 10.1021/acs.jpca.8b12200 -
置信度 1.0
“Cell Component Peak Maxima Molecular Vibration Chitin/chitosan 3261 N-H stretching 3105”
Metal and Phosphate Ions Show Remarkable Influence on the Biomass Production and Lipid Accumulation in Oleaginous Mucor circinelloides DOI: 10.3390/jof6040260 -
Alkyl C-H 置信度 1.0
“On the other hand, SR-g-VIM showed a peak at 3105 due to the cm-1 stretching vibration of C-H from the imidazole ring, a signal at 1657 assigned to the stretching cm-1 vibration of aromatic C=C, bands, peaks at 1495 and 1416 corresponding t”
Obando-Mora 等 - 2015 - Synthesis of a pHand ThermoResponsive Binary C DOI: 10.3390/coatings5040758 -
Alkyl C-H 置信度 1.0
“There cm-1 was an intense band at 3300 assigned to NH stretching vibrations of urea moieties, cm-1 cm-1 and several weak bands at ~3105 (=CH stretching in thiophene ring), ~3045”
Voltammetric Detection of Vanillylmandelic Acid and Homovanillic Acid Using Urea-Derivative-Modified Graphite Electrode DOI: 10.3390/s23073727 -
置信度 0.8
“Text: 'peak at 3105 cm-1 and some wavenumber shifts for various mode'”
Moumene 等 - 2014 - Vibrational spectroscopic study of ionic liquids DOI: 10.1016/j.molstruc.2014.02.034
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