What absorbs at 1181 cm⁻¹ in an FTIR spectrum?

クイックアンサー

A band near 1181 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.

可能性のある官能基アサイン

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可能性のある材料

同じ文献プールがこのバンドと少なくとも1つの追加の特性ピークをサポートする場合にのみ、材料が表示されます。

スペクトルロジック

This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1181 cm⁻¹ is usually not enough for material identification by itself.

実使用例

この種のクエリは、ポリマー識別、未知のプラスチックスクリーニング、QCトラブルシューティング、リサイクル材料の検証、および文献に基づいたピーク帰属のレビューで一般的です。

よくある間違い

• 少なくとも1～2つの支持ピークを確認せずに、1つの孤立したバンドを材料の証拠として扱うこと。
• 重複を無視: 複数の官能基が同じ波数付近に寄与することがあります。
• 添加剤、ブレンド、酸化、または汚染がスペクトルを歪める可能性がある場合に検証を省略すること。

検証アドバイス

曖昧さが残る場合は、特にブレンド、劣化サンプル、充填ポリマーについて、DSC、GC-MS、またはTGAで仮説を検証してください。

これらのアサインの根拠となる文献

• C c single bond 信頼度 1.0

  “carbon).37a,b stretching, where the apex denotes a chain bance-frequency spectrum, when the data are collected cm-1 cm-1 A peak at 1181 has contributions from aromatic at a nominal resolution of 4 (see Figure 2 and C-C¢ C-H in-plane bending”

  Musto 等 - 2005 - Host-guest interactions and crystalline structure DOI: 10.1021/ma0477899
• Acetate 信頼度 1.0

  “Figure 8(b) shows that the peaks observed at 1064 maycorrespondto-C-O-C-,whilepeaksobservedbetween1181.33cm(cid:6)1 binding density that characterizes the number of non-electronic-sharing cm(cid:6)1 C-O interactions between atoms such as io”

  Optical characterizations of PMMA/metal oxide nanoparticles thin films: bandgap engineering using a novel derived model DOI: 10.1016/j.heliyon.2021.e05952
• Oxygen heterocycle 信頼度 1.0

  “The decrease of the absorption band near 1181 cm-1, which was derived from the bridge between the benzene rings [40], indicates that the backbone chains of epoxy resin can be cut by thermal aging.”

  Reinforced Structure Effect on Thermo-Oxidative Stability of Polymer-Matrix Composites: 2-D Plain Woven Composites and 2.5-D Angle-Interlock Woven Composites DOI: 10.3390/polym14173454
• Hydroxyl (O-H) 信頼度 1.0

  “0.6 3523cm-1 3000 , O-H deformation vibrastretching vibration at 1441cm-1 1181cm-1 tion at”

  Li 和 Yang - 2014 - Fabrication and Characterization of Electrospun Wo DOI: 10.1155/2014/163678
• 信頼度 1.0

  “cm-1 2847 cm-1 due to the alkyl groups, a peak at 1648 cm-1 related to the N-H bending belonging to -NH2 2847 due to the alkyl groups, a peak at 1648 related to the N-H bending belonging to -NH 2 cm-1 groups, and peaks at around 1181 and 10”

  Acrylic Pressure-Sensitive Adhesive Reinforced with Aluminum Nitride and Its Thermal Properties: Effect of Surface Treatment and Particle Size DOI: 10.3390/coatings10020188
• Acetate 信頼度 1.0

  “1181 which is the C-O stretching in -CH-O and micro (< 2 mm) residues.”

  Degradation of Film and Rigid Bioplastics During the Thermophilic Phase and the Maturation Phase of Simulated Composting DOI: 10.1007/s10924-021-02098-2
• Acetate 信頼度 1.0

  “cm-1 cm-1, cm-1, In addition, the most significant absorptions are observed at 1737 and 1092 1181 cm-1 1274 corresponding to the C=O and C-O-C respectively [12], indicating the existence of ester 1H group.”

  Wen 等 - 2018 - A novel oligomer containing DOPO and ferrocene gro DOI: 10.1016/j.polymdegradstab.2018.08.010
• Acetate 信頼度 1.0

  “The absorption peak at 1181 was the anti-symmetric stretching of the C-O-C of the ester substance [47].”

  Nano Catalysis of Biofuels and Biochemicals from Cotinus coggygria Scop. Wood for Bio-Oil Raw Material DOI: 10.3390/polym14214610