What absorbs at 854 cm⁻¹ in an FTIR spectrum?
A band near 854 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Quick answer
A band near 854 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能的官能团归属
| 官能团 | 支持性事实 | 引用来源 | 最高置信度 |
|---|---|---|---|
| Metal oxygen | 3 | 3 | 1.0 |
| Hydroxyl (O-H) | 2 | 2 | 1.0 |
| Methacrylate | 2 | 2 | 1.0 |
| Acetate | 2 | 2 | 1.0 |
| Methoxy (OCH3) | 1 | 1 | 1.0 |
| C-O single bond | 1 | 1 | 1.0 |
| C c single bond | 1 | 1 | 1.0 |
| Ketone | 1 | 1 | 1.0 |
| Ester | 1 | 1 | 1.0 |
| Carboxyl (COOH) | 1 | 1 | 1.0 |
| Carbonyl (C=O) | 1 | 1 | 1.0 |
| Amide | 1 | 1 | 1.0 |
| Fluorine (C-F) | 1 | 1 | 1.0 |
| Alkyl C-H | 1 | 1 | 1.0 |
| Silicon (Si) | 1 | 1 | 1.0 |
| Alkene (C=C) | 1 | 1 | 1.0 |
排名反映了累积的文献证据，而非单一的权威规则。请始终对照您的样品背景进行确认。
Possible materials
| 材料 | 支持峰 | Overlapping groups | 引用来源 |
|---|---|---|---|
| nanocomposite | 854, 2921, 3300 | Hydroxyl (O-H), Methacrylate, Acetate | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 854 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
这些分配背后的文献
-
Hydroxyl (O-H) 置信度 1.0
“- 1218 1216 - In plane and out of plane OH bands 854”
Green Synthesis, Structural Characterization and Photocatalytic Activities of Chitosan-ZnO Nano‐composite DOI: 10.1007/s10904-021-01988-1 -
Metal oxygen 置信度 1.0
“Two peaks observed at ~729 and ~854 cm-1 are due to the stretching vibration mode of Ce-O-Ce (Cerium -oxygen) with a lower”
Oxygen vacancies and F+ centre tailored room temperature ferromagnetic properties of CeO2 nanoparticles with Pr doping concentrations and annealing in hydrogen environment DOI: 10.1016/j.jallcom.2020.156079 -
Silicon (Si) 置信度 1.0
“The peak at 854 is assigned Hf O Si stretching vibration [36], which means that interfacial to”
Yu 等 - 2012 - The structure and electrical properties of HfTaON DOI: 10.1016/j.apsusc.2011.11.015 -
Metal oxygen 置信度 1.0
“cm-1 and bending vibrations of the H-C-H group, Peaks appearing at ~ 854 show the vibrational mode which relates to the stretching mode of the O-Ti-O system in the ceramic samples that confirmed the structures22.”
Structural, optical and microwave dielectric properties of Ba(Ti1−xSnx)4O9, 0 ≤ x ≤ 0.7 ceramics DOI: 10.1038/s41598-021-97584-x -
Fluorine (C-F) 置信度 1.0
“Explicit assignment in text.”
Inamuddin 和 Kashmery - 2019 - Polyvinylidene fluoridesulfonated graphene oxide DOI: 10.1038/s41598-019-46305-6 -
Acetate 置信度 1.0
“in primary alcohols, C=O stretching (unconjugated) 854 C-H of G units”
Malric-Garajova 等 - 2023 - Modification of a Marine Pine Kraft Lignin Sample DOI: 10.3390/molecules28124873 -
C c single bond 置信度 1.0
“The Raman band at 486 and 498 are the 3, s(O-C-O) mode in the lead oxalate, the 854 cm-1 cm-1 cm-1 ν ν(C-C), ν ν and 891 band are assigned to the 2, 1436 and 1478 are assigned to the 1, s(C-O), and”
Removal mechanism of Pb(II) by Penicillium polonicum: immobilization, adsorption, and bioaccumulation DOI: 10.1038/s41598-020-66025-6 -
Hydroxyl (O-H) 置信度 1.0
“All these results implied that CEMP was prepared 854cm-1 out-of-plane O-H and the bending of around successfully.”
Yu 等 - 2020 - Synthesis of a novel modified chitosan as an intum DOI: 10.1515/epoly-2020-0036
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