What absorbs at 1306 cm⁻¹ in an FTIR spectrum?
A band near 1306 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Quick answer
A band near 1306 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Возможные назначения функциональных групп
| Функциональная группа | Подтверждающие факты | Цитируемые источники | Максимальная достоверность |
|---|---|---|---|
| Amide | 5 | 5 | 1,0 |
| Secondary amine | 4 | 4 | 1,0 |
| C n single bond | 4 | 4 | 1,0 |
| Methacrylate | 2 | 2 | 1,0 |
| Acetate | 2 | 2 | 1,0 |
| Carboxyl (COOH) | 2 | 2 | 1,0 |
| C c single bond | 2 | 2 | 1,0 |
| Carbonyl (C=O) | 2 | 2 | 1,0 |
| Methoxy (OCH3) | 1 | 1 | 1,0 |
| C-O single bond | 1 | 1 | 1,0 |
| Hydroxyl (O-H) | 1 | 1 | 1,0 |
| Alkyl C-H | 1 | 1 | 1,0 |
| Ketone | 1 | 1 | 1,0 |
| Ester | 1 | 1 | 1,0 |
| N h | 1 | 1 | 1,0 |
| Chitosan | 1 | 1 | 1,0 |
| Nucleic acid | 1 | 1 | 1,0 |
Ранжирование отражает накопленные литературные данные, а не единственное авторитетное правило. Всегда проверяйте в контексте вашего образца.
Possible materials
| Материал | Поддерживающие пики | Overlapping groups | Цитируемые источники |
|---|---|---|---|
| polyurethane | 1306, 2270, 1700 | Methacrylate, Amide | 1 |
| Polypyrrole | 1306, 1700, 400 | Amide, Secondary amine, C n single bond | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1306 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
Литература, лежащая в основе этих назначений
-
Nucleic acid достоверность 1,0
“1338cm(cid:2)1, 993cm(cid:2)1 which was not seen in Bacilwhich is due to nucleic acids, and the which located at that reason the peak at 1306 S.”
Use of Fourier transform infrared spectroscopy for rapid comparative analysis of Bacillus and Micrococcus isolates DOI: 10.1016/j.foodchem.2008.08.063 -
Amide достоверность 1,0
“The peak at 1306.3cm(cid:1)1(-C-N-) are assigned to the asymmetric and symfibers were washed and dried to obtain chitosan/polypyrrole metric stretching vibration of the polypyrrole (PPy), respectcomposite fibers and coded as CS-PPy1.”
Fabrication and Properties of Conductive Chitosan/Polypyrrole Composite Fibers DOI: 10.1080/03602559.2014.935420 -
Amide достоверность 1,0
“As isolated finish enable the peak located at ~2923 Technora fibres contain PPTA sequences similar to Twaron fibres, the spectra display some cm-1 peaks related to the amide functions in common [10]: the peak located at ~1639 is cm-1 is rel”
Derombise 等 - 2009 - Degradation of Technora aramid fibres in alkaline DOI: 10.1016/j.polymdegradstab.2009.07.021 -
Amide достоверность 1,0
“As Technora fibres contain PPTA sequences, Technora and Twaron fibres cm-1 spectra have some peaks related to the amide functions in common: the peak located at ~1639 cm-1 is related to the C=O vibration and the peak at ~1306 is related to”
Influence of finish treatment on the durability of aramid fibers aged under an alkaline environment DOI: 10.1002/app.31534 -
Amide достоверность 1,0
“chalcone carbonyl carbon symmetrical stretching absorption appeared at 1727 An cm-1 absorption band that appeared around 1306 corresponds to C-N stretching and the cm-1 sharp absorption bands that appeared around 1012 and 771 are due to imi”
Synthesis and In Vitro Antimicrobial Evaluation of Photoactive Multi—Block Chalcone Conjugate Phthalimide and 1,8-Naphthalimide Novolacs DOI: 10.3390/polym13111859 -
Amide достоверность 1,0
“Another indication that a trans-form of the secondary cm-1 acyclic amide gives band at 1306 was attributable to amide III band, of (CN)”
Ilic-Stojanovic 等 - 2018 - Thermosensitive hydrogels for modified release of DOI: 10.1080/00914037.2017.1354202 -
C c single bond достоверность 1,0
“cm-1 cm-1 V from C-COO stretching, 1098/1065 cm-1 (amorphous/crystalline) from C-O-C stretching, at β-(1→4) β-(1→4) from glycosidic linkage from inulin, at 1059 and 1270 cm-1 from C-O-C, C-O, and C-C glycosidic linkage from inulin, at 1059”
Synthesis and Characterization of Inulin-Based Responsive Polyurethanes for Breast Cancer Applications DOI: 10.3390/polym12040865 -
Hydroxyl (O-H) достоверность 1,0
“(C-O)h (O-H)h 1696 (O-H)c stretch (C-O)c bending bending stretch 1306 DP-M”
Somphon 和 Makatan - 2019 - Characterization of donepezil prepared by cogrindi DOI: 10.2306/scienceasia1513-1874.2019.45.028
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