What absorbs at 1306 cm⁻¹ in an FTIR spectrum?
A band near 1306 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Resposta rápida
A band near 1306 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Possíveis atribuições de grupos funcionais
| Grupo funcional | Fatos de suporte | Fontes citadas | Maior confiança |
|---|---|---|---|
| Amide | 5 | 5 | 1,0 |
| Secondary amine | 4 | 4 | 1,0 |
| C n single bond | 4 | 4 | 1,0 |
| Methacrylate | 2 | 2 | 1,0 |
| Acetate | 2 | 2 | 1,0 |
| Carboxyl (COOH) | 2 | 2 | 1,0 |
| C c single bond | 2 | 2 | 1,0 |
| Carbonyl (C=O) | 2 | 2 | 1,0 |
| Methoxy (OCH3) | 1 | 1 | 1,0 |
| C-O single bond | 1 | 1 | 1,0 |
| Hydroxyl (O-H) | 1 | 1 | 1,0 |
| Alkyl C-H | 1 | 1 | 1,0 |
| Ketone | 1 | 1 | 1,0 |
| Ester | 1 | 1 | 1,0 |
| N h | 1 | 1 | 1,0 |
| Chitosan | 1 | 1 | 1,0 |
| Nucleic acid | 1 | 1 | 1,0 |
A classificação reflete a evidência acumulada da literatura, não uma única regra autoritária. Sempre confirme com o contexto da sua amostra.
Materiais possíveis
| Material | Picos de suporte | Grupos sobrepostos | Fontes citadas |
|---|---|---|---|
| polyurethane | 1306, 2270, 1700 | Methacrylate, Amide | 1 |
| Polypyrrole | 1306, 1700, 400 | Amide, Secondary amine, C n single bond | 1 |
Os materiais são mostrados apenas quando o mesmo conjunto de literatura suporta esta banda e pelo menos um pico característico adicional.
Lógica do espectro
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1306 cm⁻¹ is usually not enough for material identification by itself.
Uso no mundo real
Este tipo de consulta é comum em identificação de polímeros, triagem de plásticos desconhecidos, solução de problemas de CQ, verificação de materiais reciclados e revisão de atribuição de picos apoiada pela literatura.
Erros comuns
- Tratar uma banda isolada como prova de um material sem verificar pelo menos um ou dois picos de suporte.
- Ignorando sobreposição: vários grupos funcionais podem contribuir próximo ao mesmo número de onda.
- Ignorar a validação quando aditivos, misturas, oxidação ou contaminação podem distorcer o espectro.
Conselho de verificação
Quando a ambiguidade persistir, valide a hipótese com DSC, GC-MS ou TGA, especialmente para misturas, amostras degradadas e polímeros carregados.
Literatura por trás destas atribuições
-
Nucleic acid confiança 1,0
“1338cm(cid:2)1, 993cm(cid:2)1 which was not seen in Bacilwhich is due to nucleic acids, and the which located at that reason the peak at 1306 S.”
Use of Fourier transform infrared spectroscopy for rapid comparative analysis of Bacillus and Micrococcus isolates DOI: 10.1016/j.foodchem.2008.08.063 -
Amide confiança 1,0
“The peak at 1306.3cm(cid:1)1(-C-N-) are assigned to the asymmetric and symfibers were washed and dried to obtain chitosan/polypyrrole metric stretching vibration of the polypyrrole (PPy), respectcomposite fibers and coded as CS-PPy1.”
Fabrication and Properties of Conductive Chitosan/Polypyrrole Composite Fibers DOI: 10.1080/03602559.2014.935420 -
Amide confiança 1,0
“As isolated finish enable the peak located at ~2923 Technora fibres contain PPTA sequences similar to Twaron fibres, the spectra display some cm-1 peaks related to the amide functions in common [10]: the peak located at ~1639 is cm-1 is rel”
Derombise 等 - 2009 - Degradation of Technora aramid fibres in alkaline DOI: 10.1016/j.polymdegradstab.2009.07.021 -
Amide confiança 1,0
“As Technora fibres contain PPTA sequences, Technora and Twaron fibres cm-1 spectra have some peaks related to the amide functions in common: the peak located at ~1639 cm-1 is related to the C=O vibration and the peak at ~1306 is related to”
Influence of finish treatment on the durability of aramid fibers aged under an alkaline environment DOI: 10.1002/app.31534 -
Amide confiança 1,0
“chalcone carbonyl carbon symmetrical stretching absorption appeared at 1727 An cm-1 absorption band that appeared around 1306 corresponds to C-N stretching and the cm-1 sharp absorption bands that appeared around 1012 and 771 are due to imi”
Synthesis and In Vitro Antimicrobial Evaluation of Photoactive Multi—Block Chalcone Conjugate Phthalimide and 1,8-Naphthalimide Novolacs DOI: 10.3390/polym13111859 -
Amide confiança 1,0
“Another indication that a trans-form of the secondary cm-1 acyclic amide gives band at 1306 was attributable to amide III band, of (CN)”
Ilic-Stojanovic 等 - 2018 - Thermosensitive hydrogels for modified release of DOI: 10.1080/00914037.2017.1354202 -
C c single bond confiança 1,0
“cm-1 cm-1 V from C-COO stretching, 1098/1065 cm-1 (amorphous/crystalline) from C-O-C stretching, at β-(1→4) β-(1→4) from glycosidic linkage from inulin, at 1059 and 1270 cm-1 from C-O-C, C-O, and C-C glycosidic linkage from inulin, at 1059”
Synthesis and Characterization of Inulin-Based Responsive Polyurethanes for Breast Cancer Applications DOI: 10.3390/polym12040865 -
Hydroxyl (O-H) confiança 1,0
“(C-O)h (O-H)h 1696 (O-H)c stretch (C-O)c bending bending stretch 1306 DP-M”
Somphon 和 Makatan - 2019 - Characterization of donepezil prepared by cogrindi DOI: 10.2306/scienceasia1513-1874.2019.45.028
Tem um espectro com esta banda?
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