What absorbs at 1143 cm⁻¹ in an FTIR spectrum?
A band near 1143 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Risposta rapida
A band near 1143 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Possibili assegnazioni di gruppi funzionali
| Gruppo funzionale | Fatti di supporto | Fonti citate | Affidabilità massima |
|---|---|---|---|
| Methacrylate | 8 | 8 | 1,0 |
| Acetate | 8 | 8 | 1,0 |
| C-O single bond | 8 | 8 | 1,0 |
| Methoxy (OCH3) | 7 | 7 | 1,0 |
| Alkyl C-H | 5 | 5 | 1,0 |
| Aromatic ring | 3 | 3 | 1,0 |
| Amide | 2 | 2 | 1,0 |
| Hydroxyl (O-H) | 2 | 2 | 1,0 |
| Ketone | 1 | 1 | 1,0 |
| Ester | 1 | 1 | 1,0 |
| Carboxyl (COOH) | 1 | 1 | 1,0 |
| Carbonyl (C=O) | 1 | 1 | 1,0 |
| N-O bond | 1 | 1 | 1,0 |
| S eq o | 1 | 1 | 1,0 |
| Ring structure | 1 | 1 | 1,0 |
| Lignin | 1 | 1 | 1,0 |
| Water (H2O) | 1 | 1 | 1,0 |
| Phosphorus | 1 | 1 | 1,0 |
| Phosphate (PO4) | 1 | 1 | 1,0 |
| C c single bond | 1 | 1 | 1,0 |
| N h | 1 | 1 | 1,0 |
| Sulfate (SO4) | 1 | 1 | 0,8 |
La classifica riflette le prove bibliografiche accumulate, non una singola regola autorevole. Conferma sempre nel contesto del tuo campione.
Materiali possibili
| Materiale | Picchi di supporto | Gruppi sovrapposti | Fonti citate |
|---|---|---|---|
| PVA | 1143, 1660, 2930 | Acetate, Methacrylate, C-O single bond | 1 |
| ZnO | 1143, 1400, 3430 | Acetate, Methacrylate, C-O single bond | 1 |
| AuNPs | 1143, 1646, 1721 | Methacrylate, Acetate | 1 |
| methylene blue | 1143, 1745, 1739 | Methacrylate, Acetate | 1 |
| gold nanoparticles | 1143, 1638, 3252 | Methacrylate, Acetate | 1 |
I materiali vengono mostrati solo quando lo stesso pool di letteratura supporta questa banda e almeno un picco caratteristico aggiuntivo.
Logica dello spettro
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1143 cm⁻¹ is usually not enough for material identification by itself.
Utilizzo nel mondo reale
Questo tipo di richiesta è comune nell＇identificazione dei polimeri, nello screening di plastiche sconosciute, nella risoluzione dei problemi di controllo qualità, nella verifica dei materiali riciclati e nella revisione dell＇assegnazione dei picchi supportata dalla letteratura.
Errori comuni
- Trattare una banda isolata come prova di un materiale senza verificare almeno uno o due picchi di supporto.
- Ignorando la sovrapposizione: più gruppi funzionali possono contribuire vicino allo stesso numero d＇onda.
- Saltare la convalida quando additivi, miscele, ossidazione o contaminazione possono distorcere lo spettro.
Consiglio di verifica
Quando permangono ambiguità, convalida l＇ipotesi con DSC, GC-MS o TGA, specialmente per miscele, campioni degradati e polimeri caricati.
Letteratura dietro queste assegnazioni
-
Alkyl C-H affidabilità 1,0
“Major infra-red spectral peaks of PVA (2946.67 stretching of C-H, 1142.72 cm-1;”
Sprayed in-situ synthesis of Polyvinyl alcohol/Chitosan loaded Silver nanocomposite hydrogel for improved antibacterial effects DOI: 10.1016/j.ijbiomac.2019.09.186 -
affidabilità 1,0
“3 Effect of pH (A) and temperature (B) on the decolorization of MB by strain Acinetobacter pittii cm-1, the MB was reported at 2350 while the absorption corresponding to the H-N-H bending cm-1.Thesepeaks werealsosignificantly reducedin thes”
Biodegradation of Methylene Blue as an Evidence of Synthetic Dyes Mineralization during Textile Effluent Biotreatment by Acinetobacter pittii DOI: 10.1007/s40710-020-00443-6 -
Acetate affidabilità 1,0
“are 1143, 1079, 927, and 862 the internal structure of the grain, given that through miThe bands at 1143 and C-O-C C-OH cm-1 croscopy it was found that the granule maintains its 1079 correspond to and stretching”
Roa Acosta 等 - 2020 - Structural and thermal properties of the amaranth DOI: 10.1515/ijfe-2020-0024 -
Phosphate (PO4) affidabilità 1,0
“1143cm-1 phosphate band.”
Spevak 等 - 2013 - Fourier Transform Infrared Spectroscopic Imaging P DOI: 10.1007/s00223-013-9695-9. -
Hydroxyl (O-H) affidabilità 1,0
“cm-1 cm-1 absorption at 1639 of O-H type from bound water molecules and bands at 1143, 1073 and 1024 due vibrations of the C-O-C from glycosidic bonds and O-H of alcohols.”
Vasconcelos Silva 等 - 2019 - Nanostructured polymeric system based of cashew gu DOI: 10.1590/S1517-707620190003.0712 -
affidabilità 1,0
“Energy band gap determination of ZnO films sintered cm-1 The 1143 is attributed to Zn-OH stretching and at different temperatures with diffused reflectance spectra the appearance of this peak shows the adsorption”
Investigation of physical properties of screen printed nanosized ZnO films for optoelectronic applications DOI: 10.1051/epjap/2015150019 -
Acetate affidabilità 1,0
“N C H O cm-1 1032 Aromatic C-H deformation, C-O deformation COS 0,03 46,11 6,00 47,87 cm-1 1143 Vibration in C-O-C Cellulose and Hemicellulose TW1 0,04 47,06 5,99 46,91 cm-1 1226 C= resistance and syringyl ring in lignin and xylan TW2 0,65”
Aytin 等 - 2022 - Chemical, Hygroscopic, and Mechanical Properties o DOI: 10.15376/biores.17.1.785-801 -
Aromatic ring affidabilità 1,0
“A peak at 1143 corresponding to aromatic C-H stretching, and cm-1 the band at 795 are also observed due to the CH rocking of phenolic compounds.”
The “End Life” of the Grape Pomace Waste Become the New Beginning: The Development of a Virtuous Cycle for the Green Synthesis of Gold Nanoparticles and Removal of Emerging Contaminants from Water DOI: 10.3390/antiox11050994
Hai uno spettro con questa banda?
Carica il tuo spettro FTIR e ottieni un report di interpretazione completo — assegnazioni di picchi con citazioni bibliografiche, corrispondenze con librerie e una catena di prove con valutazione di affidabilità — in secondi.