What absorbs at 933 cm⁻¹ in an FTIR spectrum?
A band near 933 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Resposta rápida
A band near 933 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Possíveis atribuições de grupos funcionais
| Grupo funcional | Fatos de suporte | Fontes citadas | Maior confiança |
|---|---|---|---|
| Methoxy (OCH3) | 4 | 4 | 1,0 |
| Methacrylate | 4 | 4 | 1,0 |
| Acetate | 4 | 4 | 1,0 |
| Alkyl C-H | 3 | 3 | 1,0 |
| C-O single bond | 3 | 3 | 1,0 |
| Phosphate (PO4) | 2 | 2 | 1,0 |
| Hydroxyl (O-H) | 2 | 2 | 1,0 |
| Silicon (Si) | 2 | 2 | 1,0 |
| C c single bond | 2 | 2 | 1,0 |
| Metal oxygen | 2 | 1 | 1,0 |
| Methyl | 1 | 1 | 1,0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 1,0 |
| Silanol (Si-OH) | 1 | 1 | 1,0 |
| Aromatic ring | 1 | 1 | 1,0 |
| Carboxyl (COOH) | 1 | 1 | 1,0 |
| Borate | 1 | 1 | 1,0 |
| Nucleic acid | 1 | 1 | 1,0 |
| Ring structure | 1 | 1 | 1,0 |
| Carbohydrate | 1 | 1 | 1,0 |
A classificação reflete a evidência acumulada da literatura, não uma única regra autoritária. Sempre confirme com o contexto da sua amostra.
Materiais possíveis
| Material | Picos de suporte | Grupos sobrepostos | Fontes citadas |
|---|---|---|---|
| Silica | 933, 1100, 1080 | Alkyl C-H, Methacrylate, Acetate | 1 |
| Polypropylene | 933, 1030, 1600 | Alkyl C-H, Methacrylate, Acetate | 1 |
Os materiais são mostrados apenas quando o mesmo conjunto de literatura suporta esta banda e pelo menos um pico característico adicional.
Lógica do espectro
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 933 cm⁻¹ is usually not enough for material identification by itself.
Uso no mundo real
Este tipo de consulta é comum em identificação de polímeros, triagem de plásticos desconhecidos, solução de problemas de CQ, verificação de materiais reciclados e revisão de atribuição de picos apoiada pela literatura.
Erros comuns
- Tratar uma banda isolada como prova de um material sem verificar pelo menos um ou dois picos de suporte.
- Ignorando sobreposição: vários grupos funcionais podem contribuir próximo ao mesmo número de onda.
- Ignorar a validação quando aditivos, misturas, oxidação ou contaminação podem distorcer o espectro.
Conselho de verificação
Quando a ambiguidade persistir, valide a hipótese com DSC, GC-MS ou TGA, especialmente para misturas, amostras degradadas e polímeros carregados.
Literatura por trás destas atribuições
-
confiança 1,0
“It is possible that the new peak of 933.03 eV may be due to Cu (I) species, while the energy band of 935.23 eV could be assumed to be due to Cu”
Ibrahim 等 - 2022 - Effect of Ammonium Sulfide on Sulfidization Flotat DOI: 10.3390/min12101193 -
C c single bond confiança 1,0
“At the length of the wavenumber of 933 another peak also appears, appears, indicating the presence of a C-C bond group.”
Glass Powder Additive on Recycled Polypropylene Filaments: A Sustainable Material in 3D Printing DOI: 10.3390/polym14010005 -
C c single bond confiança 1,0
“The films (C-C in melting temperature is higher for drawn at a higher bands at 933 and 947 (CH rocking);”
Vasanthan 和 Manne - 2013 - Strain-Induced Crystallization and Conformational DOI: 10.1021/ie401783y -
Phosphate (PO4) confiança 1,0
“cm-1, assignments of the phosphate related peaks are as follows: P-O stretching at 776 P-O-C cm-1, cm-1, cmsymmetric stretching at 933 P-O-C assymetric stretching at 1050 P=O at 1240 1.”
An appraisal of the thermal decomposition mechanisms of ILs as potential lubricants DOI: 10.1002/ls.1457 -
Carbohydrate confiança 1,0
“cm-1 (1) Band at 933 (assigned to carbohydrates) is specific for Col fungi (Fig.”
Erukhimovitch 等 - 2010 - Direct identification of potato's fungal phyto-pat DOI: 10.3233/SPE-2010-0483 -
Silicon (Si) confiança 1,0
“XPS A strong peak at 932.54 eV by Cu2p 3/2 EDAX The spectrum revealed the presence of elements like C, N, O, Si and Cu.”
Gupta 等 - 2015 - Silica functionalized Cu(II) catalysed selective o DOI: 10.1007/s12039-015-0902-2 -
Acetate confiança 1,0
“cm-1 cm-1 were observed at 1076 (C-O, axial deformation), 933 cm-1 (characteristic of 3, 6-anhydrogalactose) and 889 (attributed to Fourier transform infrared spectroscopy carbon)[16].”
Hu 等 - 2012 - Preparation of Berbamine Loaded Chitosan-agarose M DOI: 10.1590/S0104-14282012005000073 -
Acetate confiança 1,0
“Firstly in HeLa cells, the band at 933 was assigned to the vibrational mode of the C-O-C ring of deoxyribose in Z-form DNA (Banyay et al., 2003;”
Le Roux 等 - 2015 - Fourier Transform Infrared spectroscopy discloses DOI: 10.1016/S0301-4622
Tem um espectro com esta banda?
Carregue seu espectro FTIR e obtenha um relatório de interpretação completo — atribuições de picos com citações da literatura, correspondências de biblioteca e uma cadeia de evidências com nível de confiança — em segundos.