What absorbs at 933 cm⁻¹ in an FTIR spectrum?
A band near 933 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Quick answer
A band near 933 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
가능한 작용기 할당
| 작용기 | 지원 사실 | 인용 출처 | 최고 신뢰도 |
|---|---|---|---|
| Methoxy (OCH3) | 4 | 4 | 1.0 |
| Methacrylate | 4 | 4 | 1.0 |
| Acetate | 4 | 4 | 1.0 |
| Alkyl C-H | 3 | 3 | 1.0 |
| C-O single bond | 3 | 3 | 1.0 |
| Phosphate (PO4) | 2 | 2 | 1.0 |
| Hydroxyl (O-H) | 2 | 2 | 1.0 |
| Silicon (Si) | 2 | 2 | 1.0 |
| C c single bond | 2 | 2 | 1.0 |
| Metal oxygen | 2 | 1 | 1.0 |
| Methyl | 1 | 1 | 1.0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 1.0 |
| Silanol (Si-OH) | 1 | 1 | 1.0 |
| Aromatic ring | 1 | 1 | 1.0 |
| Carboxyl (COOH) | 1 | 1 | 1.0 |
| Borate | 1 | 1 | 1.0 |
| Nucleic acid | 1 | 1 | 1.0 |
| Ring structure | 1 | 1 | 1.0 |
| Carbohydrate | 1 | 1 | 1.0 |
순위는 단일 권위 규칙이 아닌 축적된 문헌 증거를 반영합니다. 항상 샘플 상황에 대해 확인하세요.
Possible materials
| 재료 | 지원 피크 | Overlapping groups | 인용 출처 |
|---|---|---|---|
| Silica | 933, 1100, 1080 | Alkyl C-H, Methacrylate, Acetate | 1 |
| Polypropylene | 933, 1030, 1600 | Alkyl C-H, Methacrylate, Acetate | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 933 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
이 할당의 배경이 되는 문헌
-
신뢰도 1.0
“It is possible that the new peak of 933.03 eV may be due to Cu (I) species, while the energy band of 935.23 eV could be assumed to be due to Cu”
Ibrahim 等 - 2022 - Effect of Ammonium Sulfide on Sulfidization Flotat DOI: 10.3390/min12101193 -
C c single bond 신뢰도 1.0
“At the length of the wavenumber of 933 another peak also appears, appears, indicating the presence of a C-C bond group.”
Glass Powder Additive on Recycled Polypropylene Filaments: A Sustainable Material in 3D Printing DOI: 10.3390/polym14010005 -
C c single bond 신뢰도 1.0
“The films (C-C in melting temperature is higher for drawn at a higher bands at 933 and 947 (CH rocking);”
Vasanthan 和 Manne - 2013 - Strain-Induced Crystallization and Conformational DOI: 10.1021/ie401783y -
Phosphate (PO4) 신뢰도 1.0
“cm-1, assignments of the phosphate related peaks are as follows: P-O stretching at 776 P-O-C cm-1, cm-1, cmsymmetric stretching at 933 P-O-C assymetric stretching at 1050 P=O at 1240 1.”
An appraisal of the thermal decomposition mechanisms of ILs as potential lubricants DOI: 10.1002/ls.1457 -
Carbohydrate 신뢰도 1.0
“cm-1 (1) Band at 933 (assigned to carbohydrates) is specific for Col fungi (Fig.”
Erukhimovitch 等 - 2010 - Direct identification of potato's fungal phyto-pat DOI: 10.3233/SPE-2010-0483 -
Silicon (Si) 신뢰도 1.0
“XPS A strong peak at 932.54 eV by Cu2p 3/2 EDAX The spectrum revealed the presence of elements like C, N, O, Si and Cu.”
Gupta 等 - 2015 - Silica functionalized Cu(II) catalysed selective o DOI: 10.1007/s12039-015-0902-2 -
Acetate 신뢰도 1.0
“cm-1 cm-1 were observed at 1076 (C-O, axial deformation), 933 cm-1 (characteristic of 3, 6-anhydrogalactose) and 889 (attributed to Fourier transform infrared spectroscopy carbon)[16].”
Hu 等 - 2012 - Preparation of Berbamine Loaded Chitosan-agarose M DOI: 10.1590/S0104-14282012005000073 -
Acetate 신뢰도 1.0
“Firstly in HeLa cells, the band at 933 was assigned to the vibrational mode of the C-O-C ring of deoxyribose in Z-form DNA (Banyay et al., 2003;”
Le Roux 等 - 2015 - Fourier Transform Infrared spectroscopy discloses DOI: 10.1016/S0301-4622
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