What absorbs at 1211 cm⁻¹ in an FTIR spectrum?
A band near 1211 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Hiter odgovor
A band near 1211 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Možne dodelitve funkcionalnih skupin
| Funkcionalna skupina | Podporna dejstva | Citirani viri | Najvišje zaupanje |
|---|---|---|---|
| C-O single bond | 5 | 5 | 1,0 |
| Acetate | 5 | 5 | 1,0 |
| Methoxy (OCH3) | 4 | 4 | 1,0 |
| Methacrylate | 4 | 4 | 1,0 |
| Amide | 4 | 4 | 1,0 |
| Secondary amine | 3 | 3 | 1,0 |
| C n single bond | 3 | 3 | 1,0 |
| Hydroxyl (O-H) | 2 | 2 | 1,0 |
| Water (H2O) | 2 | 2 | 1,0 |
| Nitrate | 1 | 1 | 1,0 |
| Ketone | 1 | 1 | 1,0 |
| Ester | 1 | 1 | 1,0 |
| Carboxyl (COOH) | 1 | 1 | 1,0 |
| Carbonyl (C=O) | 1 | 1 | 1,0 |
| Chlorine | 1 | 1 | 1,0 |
| S eq o | 1 | 1 | 1,0 |
| Alkyl C-H | 1 | 1 | 1,0 |
Razvrstitev odraža zbrane literaturne dokaze, ne enega avtoritativnega pravila. Vedno preverite glede na kontekst vašega vzorca.
Možni materiali
| Material | Podporni vrhovi | Prekrivajoče se skupine | Citirani viri |
|---|---|---|---|
| AuNPs | 1211, 1646, 1721 | Methacrylate, Acetate | 1 |
| rGO | 1211, 2358, 2930 | Methacrylate, Acetate, C-O single bond | 1 |
| hydrogels | 1211, 3281, 1700 | Methacrylate, Acetate | 1 |
| PVDF | 1211, 1160, 840 | Methacrylate, Acetate | 1 |
| gold nanoparticles | 1211, 1638, 3252 | Methacrylate, Acetate | 1 |
Materiali so prikazani le, ko ista literaturna podlaga podpira ta pas in vsaj en dodatni karakteristični vrh.
Logika spektra
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1211 cm⁻¹ is usually not enough for material identification by itself.
Uporaba v resničnem svetu
Ta vrsta poizvedbe je pogosta pri identifikaciji polimerov, pregledovanju neznanih plastičnih mas, odpravljanju težav pri QC, preverjanju recikliranih materialov in literaturno podprtem pregledu dodelitev vrhov.
Pogoste napake
- Obravnavanje enega izoliranega pasu kot dokaza o materialu brez preverjanja vsaj enega ali dveh podpornih vrhov.
- Ignoriranje prekrivanja: več funkcionalnih skupin lahko prispeva blizu istega valovnega števila.
- Izpuščanje validacije, ko lahko dodatki, mešanice, oksidacija ali kontaminacija popačijo spekter.
Nasvet za preverjanje
Ko ostaja dvoumnost, potrdite hipotezo z DSC, GC-MS ali TGA, zlasti za mešanice, degradirane vzorce in polnjene polimere.
Literatura za temi dodelitvami
-
Amide zaupanje 1,0
“The free scavenging effect of crude cm-1 vs at 1211.30 shows C-N stretching and peak extract synthesized AuNPs is shown in the Table”
Bawazeer 等 - 2021 - Synthesis, Characterization and Bioactivity Profil DOI: 10.22207/JPAM.15.2.11 -
Water (H2O) zaupanje 1,0
“Two discrete populations of supramolecular structures were evident from the infrared spectroscopy: water-rich cm-1) structures, predominant below a PG volume fraction (f PG) of 0.4 (unmoving water bending vibration at 1211 and PG-rich C-H s”
Benaouda 等 - 2012 - Discriminating the Molecular Identity and Function DOI: 10.1021/mp300127f -
Alkyl C-H zaupanje 1,0
“CH bending aldehyde cm-1 1069 S=O stetching sulfoxide S=O stetching sulfoxide cm-1 1211 C-O stretching vinyl ether”
Leemarose 等 - 2021 - Sustainable Synthesis of Gold Nanoparticles and it DOI: 10.13005/ojc/370216 -
zaupanje 1,0
“SEM cm-1, CQ displayed N-H stretch at 3300 C-N stretch at cm-1, cm-1, C=C aromatic stretch at 1612 and C-Cl 1211 cm-1 peaks between 600 and 800 (Fig.”
Owonubi 等 - 2018 - Characterization and in vitro release kinetics of DOI: 10.1007/s40090-018-0139-2 -
Acetate zaupanje 1,0
“cm-1 1506 (C=C aromatic skeletal stretching vibration), 1453 (C-H deformation), cm-1 cm-1 cm-1 1420 (C-H deformation (aromatic ring)), 1260 (C-O stretching), 1211 (Ccm-1 cm-1 C, C-O and C=O stretching), 1154 (C-O-C vibrations), and 1021 (C-”
Altuntas 等 - 2017 - Biodegradation Properties of Wood-plastic Composit DOI: 10.1002/app.24358 -
Acetate zaupanje 1,0
“The principal peaks found after KK transformation cm-1) correspond to the signals of acetate (1736, 1365 and 1211 and nitrate (1635, 1273 and roughly correspond to the signals of acetate (1736, 1365 and 1211 cm-1) and nitrate (1635, cm-1) 8”
Advantages of External Reflection and Transflection over ATR in the Rapid Material Characterization of Negatives and Films via FTIR Spectroscopy DOI: 10.3390/polym14040808 -
C-O single bond zaupanje 1,0
“Additionally, in the finger print region, below cm-1, cm-1 1700 other vibration bands of C-O bonds at 1211 and of C=C at 1579 in the SA spectra are shifted to higher wavenumbers in the eutectic mixtures, showing participation”
Georgescu 等 - 2021 - Thermal Behavior of the Nimesulide-Salicylic Acid DOI: 10.3390/ma14247715 -
Water (H2O) zaupanje 1,0
“Effect of additive content Generally, the IR absorption bands at approximately cm-1 1211, 1149, 1069, 975, 854, 794, and 763 represent the characteristic spectrum of an α phase PVDF Due to the water solubility of IL, PVDF membranes precryst”
Poly(vinylidene fluoride) (PVDF) membrane fabrication with an ionic liquid via non-solvent thermally induced phase separation (N-TIPs) DOI: 10.1007/s13201-021-01499-x
Imate spekter s tem pasom?
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