What absorbs at 845 cm⁻¹ in an FTIR spectrum?
A band near 845 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
빠른 답변
A band near 845 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
가능한 작용기 할당
| 작용기 | 지원 사실 | 인용 출처 | 최고 신뢰도 |
|---|---|---|---|
| Methoxy (OCH3) | 3 | 2 | 1.0 |
| Silicon-oxygen (Si-O) | 2 | 2 | 1.0 |
| Alkyl C-H | 2 | 2 | 1.0 |
| Silicon carbon | 2 | 2 | 1.0 |
| Metal oxygen | 2 | 2 | 1.0 |
| C c single bond | 2 | 2 | 1.0 |
| Carbohydrate | 2 | 2 | 1.0 |
| Methacrylate | 2 | 2 | 1.0 |
| Acetate | 2 | 2 | 1.0 |
| C-O single bond | 2 | 2 | 1.0 |
| Fluorine (C-F) | 1 | 1 | 1.0 |
| Silicon (Si) | 1 | 1 | 1.0 |
| Hydroxyl (O-H) | 1 | 1 | 1.0 |
| Phosphate (PO4) | 1 | 1 | 1.0 |
| Secondary amine | 1 | 1 | 1.0 |
| C n single bond | 1 | 1 | 1.0 |
| Amide | 1 | 1 | 1.0 |
| Ring structure | 1 | 1 | 1.0 |
| Aromatic ring | 1 | 1 | 1.0 |
| Sulfate (SO4) | 1 | 1 | 1.0 |
| N n bond | 1 | 1 | 1.0 |
| Oxygen heterocycle | 1 | 1 | 0.9 |
순위는 단일 권위 규칙이 아닌 축적된 문헌 증거를 반영합니다. 항상 샘플 상황에 대해 확인하세요.
가능한 재료
| 재료 | 지원 피크 | 겹치는 그룹 | 인용 출처 |
|---|---|---|---|
| polypyrrole | 845, 1700, 400 | Alkyl C-H | 1 |
| PPy | 845, 1043, 910 | Alkyl C-H, Methoxy (OCH3) | 1 |
| PVA | 845, 1660, 2930 | Alkyl C-H, Methoxy (OCH3) | 1 |
동일한 문헌 풀이 이 밴드와 하나 이상의 추가 특징 피크를 지원하는 경우에만 물질이 표시됩니다.
스펙트럼 로직
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 845 cm⁻¹ is usually not enough for material identification by itself.
실제 사용
이러한 유형의 질의는 고분자 식별, 미지 플라스틱 스크리닝, QC 문제 해결, 재활용 재료 검증 및 문헌 기반 피크 할당 검토에서 일반적입니다.
일반적인 실수
- 하나의 고립된 밴드를 재료의 증거로 취급하고 최소 하나 또는 두 개의 지원 피크를 확인하지 않는 것.
- 겹침 무시: 여러 작용기가 동일한 파수 근처에서 기여할 수 있습니다.
- 첨가제, 혼합물, 산화 또는 오염이 스펙트럼을 왜곡할 수 있는 경우 검증을 건너뜁니다.
검증 조언
모호성이 남아 있는 경우, 특히 혼합물, 분해된 시료 및 충전 폴리머의 경우 DSC, GC-MS 또는 TGA로 가설을 검증하십시오.
이 할당의 배경이 되는 문헌
-
Acetate 신뢰도 1.0
“Raw MPF spectrum shows a broad peak at cm-1 cm-1 at 845 is due to the deformation vibration of C-O-C 3395 of O-H stretching.”
Graft copolymerization of methyl methacrylate on Meizotropis Pellita fibres and their applications in oil absorbency DOI: 10.1007/s13726-020-00869-7 -
N n bond 신뢰도 1.0
“The bands at (n n cm-1 845 and 971 and are due to stretching vibrations of SiO and 3) and bands at 486 and N 4 1”
Driving the photoluminescent and structural properties of X2-Y2SiO5 by varying the dopant Dy3+ concentration towards cool wLED applications DOI: 10.1016/j.solidstatesciences.2017.05.008 -
Metal oxygen 신뢰도 1.0
“The FTIR spectrum showed the absorption band at 845 cm-1 that is due to the stretching mode of is attributed to Bi-O-Bi bond, and the strong absorption band recorded at 424 Bi-O.”
Zulkifli 等 - 2017 - Effect of Hydrothermal Reaction Time on Size of Bi DOI: 10.1063/1.5010448 -
C-O single bond 신뢰도 1.0
“PVAL was observed via its C-O stretching vibrations and contributed as vibrations and contributed as a shoulder of the band at 1170 cm-1 with its C-C-O cm-1 cm-1 a shoulder of the band at 1170 with its C-C-O stretching at 845 [26].”
Polypyrrole Aerogels: Efficient Adsorbents of Cr(VI) Ions from Aqueous Solutions DOI: 10.3390/gels9070582 -
Sulfate (SO4) 신뢰도 1.0
“Vibration bands at 830 and 845 cm-1 have previously been associated with 4-Oand 2-O-sulfate groups in agar-type polysaccharides [46].”
Exopolysaccharides Production by Cultivating a Bacterial Isolate from the Hypersaline Environment of Salar de Uyuni (Bolivia) in Pretreatment Liquids of Steam-Exploded Quinoa Stalks and Enzymatic Hydrolysates of Curupaú Sawdust DOI: 10.3390/fermentation7010033 -
Aromatic ring 신뢰도 1.0
“and aromatic ring vibrations at 971, 870 and 845 cm-1 (Figcm-1;”
Advantages of External Reflection and Transflection over ATR in the Rapid Material Characterization of Negatives and Films via FTIR Spectroscopy DOI: 10.3390/polym14040808 -
신뢰도 1.0
“The IR band at 845 shows the Leal et al.”
Fernando 等 - 2017 - FTIR characterization and antioxidant activity of DOI: 10.4490/algae.2017.32.12.1 -
C c single bond 신뢰도 1.0
“cm-1 C-C C-O 1140 is due to the stretching of the and groups [53,54], the 1092 signal corresponds cm-1 C-O to the stretching of the group and the 845 stretch vibration corresponds to the C-C [54].”
Judith Valdez-Alegria 等 - 2020 - Synthesis of Chitosan-Polyvinyl Alcohol Biopolymer DOI: 10.3390/biom10010156
이 밴드가 있는 스펙트럼이 있나요?
FTIR 스펙트럼을 업로드하면 몇 초 안에 전체 해석 보고서(문헌 인용이 포함된 피크 할당, 라이브러리 매칭, 신뢰도 평가 증거 체인)를 받을 수 있습니다.