What absorbs at 835 cm⁻¹ in an FTIR spectrum?
A band near 835 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
빠른 답변
A band near 835 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
가능한 작용기 할당
| 작용기 | 지원 사실 | 인용 출처 | 최고 신뢰도 |
|---|---|---|---|
| Alkyl C-H | 5 | 4 | 1.0 |
| Alkene (C=C) | 4 | 3 | 1.0 |
| C-O single bond | 3 | 3 | 1.0 |
| Amide | 2 | 2 | 1.0 |
| Ring structure | 2 | 2 | 1.0 |
| Carbohydrate | 2 | 2 | 1.0 |
| Methoxy (OCH3) | 2 | 2 | 1.0 |
| Methacrylate | 2 | 2 | 1.0 |
| Acetate | 2 | 2 | 1.0 |
| Lignin | 2 | 1 | 1.0 |
| Secondary amine | 1 | 1 | 1.0 |
| C n single bond | 1 | 1 | 1.0 |
| Silicon carbon | 1 | 1 | 1.0 |
| Siloxane (Si-O-Si) | 1 | 1 | 1.0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 1.0 |
| Phosphorus | 1 | 1 | 1.0 |
| Phosphate (PO4) | 1 | 1 | 1.0 |
| Aromatic ring | 1 | 1 | 1.0 |
| C c single bond | 1 | 1 | 1.0 |
순위는 단일 권위 규칙이 아닌 축적된 문헌 증거를 반영합니다. 항상 샘플 상황에 대해 확인하세요.
가능한 재료
동일한 문헌 풀이 이 밴드와 하나 이상의 추가 특징 피크를 지원하는 경우에만 물질이 표시됩니다.
스펙트럼 로직
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 835 cm⁻¹ is usually not enough for material identification by itself.
실제 사용
이러한 유형의 질의는 고분자 식별, 미지 플라스틱 스크리닝, QC 문제 해결, 재활용 재료 검증 및 문헌 기반 피크 할당 검토에서 일반적입니다.
일반적인 실수
- 하나의 고립된 밴드를 재료의 증거로 취급하고 최소 하나 또는 두 개의 지원 피크를 확인하지 않는 것.
- 겹침 무시: 여러 작용기가 동일한 파수 근처에서 기여할 수 있습니다.
- 첨가제, 혼합물, 산화 또는 오염이 스펙트럼을 왜곡할 수 있는 경우 검증을 건너뜁니다.
검증 조언
모호성이 남아 있는 경우, 특히 혼합물, 분해된 시료 및 충전 폴리머의 경우 DSC, GC-MS 또는 TGA로 가설을 검증하십시오.
이 할당의 배경이 되는 문헌
-
신뢰도 1.0
“Explicit assignment: IR absorption band at 835 cm-1 reported as result of π-π* interaction”
Influence of Single-Walled Carbon Nanotubes Enriched in Semiconducting and Metallic Tubes on the Electropolymerization of Tetrabromo Ortho-Xylene: Insights on the Synthesis Mechanism of Poly(ortho-phenylenevinylene) DOI: 10.1016/j.eurpolymj.2017.01.015 -
Alkene (C=C) 신뢰도 1.0
“The C=C band of the cm-1 isoprene is shown at 835 [6,7] as a shoulder peak to the epoxide.”
Dahham 等 - 2018 - The Influences of Zirconium Dioxide on ENR-25ZrO2 DOI: 10.1088/1742-6596/1019/1/012055 -
Alkyl C-H 신뢰도 1.0
“cm-1 bending vibrations of C-H are present at 835 and 860 in Raman spectra.”
Dalal 等 - 2015 - Structural, electrical, ferroelectric and mechanic DOI: 10.1039/C5RA10501C. -
C-O single bond 신뢰도 1.0
“In addition, one of the cm-1that 3,200 represents the presence of N-H group chitin compound indication is the occurrence of tug cm-1reflecting on amide and the presence of peak at the wavelength vibration at the wavelength of 834.54 cm-1 of”
Naiu 等 - 2020 - The Effect of HCl-Thermal Pressure Hydrolysis and DOI: 10.12944/CRNFSJ.8.1.18 -
Acetate 신뢰도 1.0
“cm(cid:3)1 (CH rockteristics of vibration peaks at 835 and 930 electrodes.22 2 It is also noticed that the semicircular portion cm(cid:3)1 cm(cid:3)1 (C-O-C stretching), 1220 and 1250 ing), 1116 is reduced and almost disappeared for plastic”
Influence of high and low dielectric constant plasticizers on the ion transport properties of PEO: NH4HF2 polymer electrolytes DOI: 10.1177/0954008319894043 -
C c single bond 신뢰도 1.0
“While the bond C-C rocking noted for PVA 0.1g/ CMC 0.4g 835.00cm-1 only and IR peak corresponds to CMC polymer that acts 1, 4-β Glycoside of cellulose seemed only in (PVA 0.2g /CMC 0.3 g) and (PVA0.25 g / CMC0.25 g) and disappeared in the r”
Abead 等 - 2023 - Study physical characteristics of Polyvinyl Alcoho DOI: 10.15764/pche.2014.02001. -
Alkyl C-H 신뢰도 1.0
“Peaks at 875 cm-1 and 835 cm-1 are attributed to C-H expansion outside the benzene ring, due to the hydroxymethyl synthesis reaction of formaldehyde and phenol.”
Chen 等 - 2020 - Properties of Wood Ceramics Prepared from Thermo-M DOI: 10.3390/f11111204 -
Phosphate (PO4) 신뢰도 1.0
“Band Position (cm-1) No Band Assignments 1 780 Sugar phosphate vibration 2 835 Deoxyribose phosphate Adenine3 938 Thymine base pairs CCC and O of deoxyribose skeletal 4 963 motion PC5 1014 O or O stretching C6 1050 O deoxyribose stretching”
Chemical and Physical Characteristics of Doxorubicin Hydrochloride Drug-Doped Salmon DNA Thin Films DOI: 10.1038/srep12722
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