What absorbs at 577 cm⁻¹ in an FTIR spectrum?
A band near 577 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
快速回答
A band near 577 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能的官能基指派
| 官能基 | 支持事實 | 引用來源 | 最高信心 |
|---|---|---|---|
| Metal oxygen | 2 | 2 | 1.0 |
| Methacrylate | 2 | 1 | 1.0 |
| Acetate | 2 | 1 | 1.0 |
| Carboxyl (COOH) | 2 | 1 | 1.0 |
| C c single bond | 1 | 1 | 1.0 |
| Methoxy (OCH3) | 1 | 1 | 1.0 |
| C-O single bond | 1 | 1 | 1.0 |
| Protein beta sheet | 1 | 1 | 1.0 |
| Methyl | 1 | 1 | 1.0 |
| Alkyl C-H | 1 | 1 | 1.0 |
| Hydroxyl (O-H) | 1 | 1 | 1.0 |
| Phosphate (PO4) | 1 | 1 | 1.0 |
| Ketone | 1 | 0 | 1.0 |
| Ester | 1 | 0 | 1.0 |
| Carbonyl (C=O) | 1 | 0 | 1.0 |
| Amide | 1 | 0 | 1.0 |
排名反映累積的文獻證據，而非單一權威規則。請務必根據您的樣品背景進行確認。
可能的材料
| 材料 | 支持峰 | 重疊基團 | 引用來源 |
|---|---|---|---|
| starch | 577, 1650, 1540 | Methacrylate, Acetate | 1 |
| silk fibroin | 577, 1050, 1511 | Methacrylate | 1 |
僅當同一文獻庫支援此波段以及至少一個額外特徵峰時，才會顯示材料。
光譜邏輯
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 577 cm⁻¹ is usually not enough for material identification by itself.
實際使用
此類查詢常見於聚合物鑑別、未知塑膠篩選、品管故障排除、再生材料驗證，以及基於文獻的峰值歸屬審查。
常見錯誤
- 將一個孤立的譜帶視為材料的證據，而未檢查至少一兩個支持峰。
- 忽略重疊：多個官能團可能在相同波數附近貢獻。
- 當添加劑、混合物、氧化或污染物可能扭曲譜圖時，跳過驗證。
驗證建議
當仍然存在歧義時，使用DSC、GC-MS或TGA驗證假設，特別是對於混合物、降解樣品和填充聚合物。
這些指派背後的文獻
-
Phosphate (PO4) 信心 1.0
“874.1 P-O-P asymmetric stretching bond 792.0 P-O-P asymmetric stretching bond 577.1 (H-O-) P=O bond (strong absorption) acid phosphates 527.7 (H-O-) P=O bond (strong absorption) acid phosphates Table 2 FT-Raman wavenumbers and vibrations as”
Growth and characterization of calcium hydrogen phosphate dihydrate crystals from single diffusion gel technique DOI: 10.1002/crat.200900700 -
Alkyl C-H 信心 1.0
“LLM confirmed rule peak-group candidate”
Development of New Amphiphilic Catalytic Steam Additives for Hydrothermal Enhanced Oil Recovery Techniques DOI: 10.3390/catal12080921 -
信心 1.0
“cm-1 cm-1 two peaks at 577 and 709 are attributed to RESULTS AND DISCUSSION stretching and bending vibration modes of the Fe-O in Drug Response Study the Fe-O-Si bonds in (Figure 2).”
Attuluri 和 Darwin - 2022 - Drug Bioavailability, Stability and Anticancer Eff DOI: 10.5530/ijper.56.3s.152 -
信心 1.0
“The FTIR peaks at 577 and 913 can be assigned 21-S-O”
Dhumal 等 - 2016 - Molecular Interactions of a Cu-Based Metal-Organic DOI: 10.1021/acs.jpcc.5b10123 -
Protein beta sheet 信心 1.0
“The DTA curve of SF also shows an d extraction59 β-sheet intense peak at 577 °C, originating from the amorphous sericin and the degummed fibroin”
A Hybrid {Silk@Zirconium MOF} Material as Highly Efficient AsIII-sponge DOI: 10.1038/s41598-020-66091-w -
Acetate 信心 1.0
“Inthisstudy, major bands at760 cm-1, cm-1 cm-1 1010, 1080 and 1150 which are associated with the and 577 and minor bands between 577 and 400 in C-O C-C coupled and stretching vibrations of the polysactheinfraredspectra(Fig.1)ofstarchandinul”
Pourfarzad 等 - 2015 - Serish inulin and wheat biopolymers interactions i DOI: 10.1007/s13197-015-1939-4 -
Metal oxygen 信心 0.9
“Text: '577 cm-1 ... Zn-O symmetric stretching vibration in ZnO4'”
Zaid 等 - 2016 - Fabrication and Crystallization of ZnO-SLS Glass D DOI: 10.1155/2016/8084301 -
信心 0.8
“Text: 'peak of CDDP at 568 moved to 577'.”
Hu 等 - 2022 - Flotation Performance and Adsorption Mechanism of DOI: 10.3390/min12040441
有包含此波峰的圖譜嗎？
上傳您的FTIR圖譜，幾秒內即可獲得完整的解讀報告——包含帶有文獻引用的峰位指派、圖譜庫比對以及信心等級評估的證據鏈。