What absorbs at 420 cm⁻¹ in an FTIR spectrum?
A band near 420 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
빠른 답변
A band near 420 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
가능한 작용기 할당
| 작용기 | 지원 사실 | 인용 출처 | 최고 신뢰도 |
|---|---|---|---|
| Metal oxygen | 11 | 10 | 1.0 |
| Alkyl C-H | 3 | 3 | 1.0 |
| Aromatic ring | 3 | 2 | 1.0 |
| Hydroxyl (O-H) | 1 | 1 | 1.0 |
| Methoxy (OCH3) | 1 | 1 | 1.0 |
| Methacrylate | 1 | 1 | 1.0 |
| C-O single bond | 1 | 1 | 1.0 |
| Acetate | 1 | 1 | 1.0 |
| C c single bond | 1 | 1 | 1.0 |
| Ring structure | 1 | 1 | 1.0 |
| N n bond | 1 | 1 | 0.6 |
| C-S single bond | 1 | 1 | 0.6 |
| Carbonyl (C=O) | 1 | 1 | 0.6 |
| Amide | 1 | 0 | 1.0 |
| Silicon (Si) | 1 | 0 | 0.7 |
순위는 단일 권위 규칙이 아닌 축적된 문헌 증거를 반영합니다. 항상 샘플 상황에 대해 확인하세요.
가능한 재료
| 재료 | 지원 피크 | 겹치는 그룹 | 인용 출처 |
|---|---|---|---|
| ZnO | 420, 1400, 3430 | Metal oxygen, Hydroxyl (O-H), Alkyl C-H | 2 |
| polyethylene | 420, 1737, 1720 | Alkyl C-H, Hydroxyl (O-H), Aromatic ring | 1 |
| SiO | 420, 800, 1745 | Hydroxyl (O-H) | 1 |
| GO | 420, 1720, 1182 | Hydroxyl (O-H), Alkyl C-H | 1 |
동일한 문헌 풀이 이 밴드와 하나 이상의 추가 특징 피크를 지원하는 경우에만 물질이 표시됩니다.
스펙트럼 로직
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 420 cm⁻¹ is usually not enough for material identification by itself.
실제 사용
이러한 유형의 질의는 고분자 식별, 미지 플라스틱 스크리닝, QC 문제 해결, 재활용 재료 검증 및 문헌 기반 피크 할당 검토에서 일반적입니다.
일반적인 실수
- 하나의 고립된 밴드를 재료의 증거로 취급하고 최소 하나 또는 두 개의 지원 피크를 확인하지 않는 것.
- 겹침 무시: 여러 작용기가 동일한 파수 근처에서 기여할 수 있습니다.
- 첨가제, 혼합물, 산화 또는 오염이 스펙트럼을 왜곡할 수 있는 경우 검증을 건너뜁니다.
검증 조언
모호성이 남아 있는 경우, 특히 혼합물, 분해된 시료 및 충전 폴리머의 경우 DSC, GC-MS 또는 TGA로 가설을 검증하십시오.
이 할당의 배경이 되는 문헌
-
신뢰도 1.0
“peak at 420 may be attributed to the stretching vibration of the Ni-O bond As the AC calcination temperature increased, the absorption peak decreased rapidly and then increased.”
The preparation and characterization of the Ni-NiO/TiO2 hollow composite materials on micro-nano cellulose fibers DOI: 10.1016/j.vacuum.2018.06.044 -
Metal oxygen 신뢰도 1.0
“The corresponding cm-1 cm-1 peak to the Ce-O stretching is observed at 420 and the band at 1080 and 1250”
Biosynthesis, characterization and cytotoxic activity of CeO2 nanoparticles DOI: 10.1016/j.ceramint.2018.04.063 -
Metal oxygen 신뢰도 1.0
“4, AZO 0%, 2%, 3% and 4% gave the same weak absorption spectras at a wavenumber of 420 cm-1 atribute as a bending of Zn-O-Zn.”
conferenceseries.iop.org materials science and engineering open access proceedings IOP Conferences Series: Materials Science and Engineering DOI: 10.1088/1757-899X/176/1/012049 -
Metal oxygen 신뢰도 1.0
“cm-1 1403 1085 and 1040 ZnO nanodrums gives the absorption at the wavenumber of 420 which is cm-1 the vibration of Zn-O-Zn and at 3450 which is the O-H functional group.”
The photocatalytic degradation of methylene blue using graphene oxide (GO)/ZnO nanodrums DOI: 10.1063/1.5054523 -
Alkyl C-H 신뢰도 1.0
“In this present work, the bands due to C-H in-plane ring 280cm-1 420, are assigned to C-C-C stretching and out-of-plane vibration interacting somewhat with C-C stretching vibration are vibrations respectively.”
FTIR and FT Raman, molecular geometry, vibrational assignments, ab initio and density functional theory calculations for 1,5-methylnaphthalene DOI: 10.1016/j.saa.2010.09.002 -
Metal oxygen 신뢰도 1.0
“LLM confirmed rule peak-group candidate”
Abd El-Moneim 等 - 2023 - XRD, FTIR and ultrasonic investigations of cadmium DOI: 10.1038/s41598-023-39489-5 -
Metal oxygen 신뢰도 1.0
“The assignment of bands at 420 cm-1, 580 cm-1 and 650 cm-1 to the stretching vibrations of Zr-O bonds is more probable due to the progressive crystallization of different forms of zirconia in these samples, which agrees with the X-ray analy”
Adamczyk - 2022 - The Study of the Influence of ZrO2 Precursor Type DOI: 10.3390/gels8110724 -
Alkyl C-H 신뢰도 1.0
“Figure 2: ATR-FTIR 375 Comparative study of carbonyl index methods for transmission and 1,420cm-1 C-H as the stretching modes between 1,500 and CI calculations used to compare against the SAUB method Table 3:”
Almond 等 - 2020 - Determination of the carbonyl index of polyethylen DOI: 10.1515/epoly-2020-0041
이 밴드가 있는 스펙트럼이 있나요?
FTIR 스펙트럼을 업로드하면 몇 초 안에 전체 해석 보고서(문헌 인용이 포함된 피크 할당, 라이브러리 매칭, 신뢰도 평가 증거 체인)를 받을 수 있습니다.