What absorbs at 1715 cm⁻¹ in an FTIR spectrum?
A band near 1715 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
快速回答
A band near 1715 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能的官能基指派
| 官能基 | 支持事實 | 引用來源 | 最高信心 |
|---|---|---|---|
| Carbonyl (C=O) | 64 | 56 | 1.0 |
| Carboxyl (COOH) | 44 | 41 | 1.0 |
| Ester | 39 | 37 | 1.0 |
| Methacrylate | 38 | 36 | 1.0 |
| Acetate | 37 | 35 | 1.0 |
| Ketone | 35 | 33 | 1.0 |
| Amide | 35 | 33 | 1.0 |
| Alkene (C=C) | 8 | 8 | 1.0 |
| Alkyl C-H | 7 | 6 | 1.0 |
| C-O single bond | 5 | 5 | 1.0 |
| Methoxy (OCH3) | 4 | 4 | 1.0 |
| Aldehyde (CHO) | 3 | 3 | 1.0 |
| N h | 3 | 2 | 1.0 |
| Imide | 3 | 1 | 1.0 |
| Quinone | 2 | 2 | 1.0 |
| Carbohydrate | 2 | 2 | 1.0 |
| C=n | 1 | 1 | 1.0 |
| Metal oxygen | 1 | 1 | 1.0 |
| Water (H2O) | 1 | 1 | 1.0 |
| Hydroxyl (O-H) | 1 | 1 | 1.0 |
| Hydrogen bond | 1 | 1 | 0.8 |
排名反映累積的文獻證據,而非單一權威規則。請務必根據您的樣品背景進行確認。
可能的材料
| 材料 | 支持峰 | 重疊基團 | 引用來源 |
|---|---|---|---|
| PET | 1715, 1408, 800 | Methacrylate, Carbonyl (C=O) | 1 |
| water | 1715, 1018, 2945 | Carbonyl (C=O), Methacrylate | 1 |
| glycerol | 1715, 1585, 1630 | Methacrylate, Carbonyl (C=O), Carboxyl (COOH) | 1 |
僅當同一文獻庫支援此波段以及至少一個額外特徵峰時,才會顯示材料。
光譜邏輯
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1715 cm⁻¹ is usually not enough for material identification by itself.
實際使用
此類查詢常見於聚合物鑑別、未知塑膠篩選、品管故障排除、再生材料驗證,以及基於文獻的峰值歸屬審查。
常見錯誤
- 將一個孤立的譜帶視為材料的證據,而未檢查至少一兩個支持峰。
- 忽略重疊:多個官能團可能在相同波數附近貢獻。
- 當添加劑、混合物、氧化或污染物可能扭曲譜圖時,跳過驗證。
驗證建議
當仍然存在歧義時,使用DSC、GC-MS或TGA驗證假設,特別是對於混合物、降解樣品和填充聚合物。
這些指派背後的文獻
-
Alkene (C=C) 信心 1.0
“2, it is possible to observe an intense band in cm-1 the region of 1715 associated with the cis double bonds.”
Ariza Ortega 等 - 2012 - Analysis of trans fatty acids production and squal DOI: 10.2478/s11532-012-0104-4 -
Ester 信心 1.0
“are assigned to ester pectin polymer chains and the methyl group of the methyl ester The bands at 1715 and 1632 -COO(cid:0) CO-CH3”
Optimization of citron peel pectin and glycerol concentration in the production of edible film using response surface methodology DOI: 10.1016/j.heliyon.2023.e13724 -
Carbonyl (C=O) 信心 1.0
“At peak ~1715 cm-1, stretching of C=O bond were appeared indicated the conjugated ester group in the chemical”
Aziz 等 - 2018 - The effect of Pineapple Leaf Fiber (PALF) incorpor DOI: 10.1088/1755-1315/105/1/012082 -
Carbonyl (C=O) 信心 1.0
“cm-1 blends.21 the 1715 peak, corresponding to the carbonyl tration and DC in dimethacrylate C=O bond, showed reliable results.”
Collares 等 - 2014 - Discrepancies in degree of conversion measurements DOI: 10.1590/S1806-83242013000600002 -
Acetate 信心 1.0
“At wavenumber 1715.25 shows the presence of vibration C=O stretching and this oC, absorption band does not appear in the annealed sample 700 this is because the bond is broken due cm-1 to increasing temperatures.”
Fabiani 等 - 2020 - Green synthesis and characterization of Zinc Ferri DOI: 10.1088/1755-1315/599/1/012066 -
Ester 信心 1.0
“methylundecenoatesinceaslightsurfaceoxidationispresent:a 1715cm-1 2200cm-1, On this basis the band at can be univocally band at due to O ySi-H stretching vibration, and a x O ester stretching and the low frequency can assigned to the C sign”
Giovannozzi 和 Rocchia - 2008 - Effect of the reaction time, reagent concentration DOI: 10.1016/j.snb.2007.10.043 -
Acetate 信心 1.0
“The peaks at 1675cm-1 1715 and belong to the C O stretching bands of”
Iwai 等 - 2006 - Measurement of entrainer effects of water and etha DOI: 10.1016/j.supflu.2005.12.005 -
Acetate 信心 1.0
“The as-burnt and calcined 2 cm-1 BCZT powders with pH7 showed peaks at 1715, 1741, 1710 and 1742 assigned to the ACCEPTED MANUSCRIPT cm-1 C=O stretching [13].”
Influence of pH values on the surface and properties of BCZT nanopowders synthesized via sol-gel auto-combustion method DOI: 10.1016/j.surfcoat.2016.03.091
有包含此波峰的圖譜嗎?
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