What absorbs at 1346 cm⁻¹ in an FTIR spectrum?
Una banda cerca de 1346 cm⁻¹ puede apuntar a varios grupos funcionales. A continuación se muestran las asignaciones más probables, clasificadas por cuánta evidencia publicada respalda cada una — cada una trazable a literatura (DOI) y validada de forma cruzada con nuestros más de 130,000 espectros de referencia y grafo de conocimiento.
Backed by 8 cited sources
Quick answer
A band near 1346 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Posibles asignaciones de grupos funcionales
| Grupo funcional | Hechos de respaldo | Fuentes citadas | Confianza máxima |
|---|---|---|---|
| Alkyl C-H | 4 | 4 | 1,0 |
| Methacrylate | 3 | 3 | 1,0 |
| Acetate | 3 | 3 | 1,0 |
| Methoxy (OCH3) | 2 | 2 | 1,0 |
| C-O single bond | 2 | 2 | 1,0 |
| Fatty acid | 1 | 1 | 1,0 |
| Lipid | 1 | 1 | 1,0 |
| Carbohydrate | 1 | 1 | 1,0 |
| Ketone | 1 | 1 | 1,0 |
| Ester | 1 | 1 | 1,0 |
| Carboxyl (COOH) | 1 | 1 | 1,0 |
| Carbonyl (C=O) | 1 | 1 | 1,0 |
| Amide | 1 | 1 | 1,0 |
| Hydroxyl (O-H) | 1 | 1 | 1,0 |
| N-O bond | 1 | 1 | 1,0 |
| Silicon (Si) | 1 | 1 | 1,0 |
| Nitro (NO2) | 1 | 1 | 0,8 |
La clasificación refleja la evidencia acumulada de la literatura, no una única regla autorizada. Siempre confirme según el contexto de su muestra.
Possible materials
| Material | Supporting peaks | Overlapping groups | Fuentes citadas |
|---|---|---|---|
| pectin | 1346, 1746, 1150 | Methacrylate, Acetate, Alkyl C-H | 1 |
| polyethylene | 1346, 1737, 1720 | Alkyl C-H, Methacrylate, Acetate | 1 |
| polypropylene | 1346, 1030, 1600 | Alkyl C-H, Methacrylate, Acetate | 1 |
| MgO | 1346, 699, 874 | Alkyl C-H, Methoxy (OCH3), Methacrylate | 1 |
| PEG | 1346, 1650, 1342 | Alkyl C-H, Methacrylate, Acetate | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1346 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
Literatura detrás de estas asignaciones
-
Silicon (Si) confianza 1,0
“The Raman signature at the 1346.19 cm1 cm1 1491.78 and 1570.94 bonding correspond to D, G-Si and G peaks respectively.”
Swain - 2022 - Process Dependent Strain Behaviour, Fractal Analys DOI: 10.21203/rs.3.rs-374154/v1 -
N-O bond confianza 1,0
“3ν Figure 2b shows the time-dependent normalized peak areas At the lowest RH of 3.8%, the 3-NO band appears as a cm-1, 3cm-1), ν (833-844 of strong narrow peak at 1346 which is characteristic of 2-NO the signature of the solid phase, cm-1).”
Zhang 等 - 2014 - In Situ Observation on the Dynamic Process of Evap DOI: 10.1021/jp412073c -
confianza 1,0
“The disappearance of the small peak at cm-1 cm-1 1287 was replaced by the appearance of medium peak at 1346 in the Ag/Cts/PEG spectrum, which was due to the complexation between Cts/PEG and AgNO to form metallopolymer 3 [Ag/Cts/PEG]+.”
Green Synthesis and Characterization of Silver/Chitosan/Polyethylene Glycol Nanocomposites DOI: 10.3390/ijms12084872 -
Alkyl C-H confianza 1,0
“LLM confirmed rule peak-group candidate”
Synthesis of MgO Nanoparticles Using Artemisia abrotanum Herba Extract and Their Antioxidant and Photocatalytic Properties DOI: 10.1007/s40995-016-0076-x -
Alkyl C-H confianza 1,0
“The cm-1 The occurrence of the band at 1346 comes probably from bending vibrations of C-H or O-H occurrence of the band at 1346 cm-1 comes probably from bending vibrations of C-H or O-H groups, cm-1 groups, while the presence of distinct ba”
Synthesis and Effect of Structure on Swelling Properties of Hydrogels Based on High Methylated Pectin and Acrylic Polymers DOI: 10.3390/polym11010114 -
Acetate confianza 1,0
“At 1346 a band related to the cm-1, stretching of the C=O bond of hemicellulose components was displayed.”
Bio-Based Composites for Light Automotive Parts: Statistical Analysis of Mechanical Properties; Effect of Matrix and Alkali Treatment in Sisal Fibers DOI: 10.3390/polym14173566 -
Lipid confianza 1,0
“Peaks at cm-1 cm-1 1346 and 1446 were attributed to lipids and, in particular, fatty acids and assign”
Complex Spectroscopic Study for Fusarium Genus Fungi Infection Diagnostics of “Zalp” Cultivar Oat DOI: 10.3390/agronomy11122402 -
Alkyl C-H confianza 1,0
“The the bands at 1517, 1466, 1324 and 1277 which are not present cm-1 band at 1346 is attributed to the bending of the-CH group at oxidation potentials, increase in intensity when the potential 3”
Spectroelectrochemical studies of poly(N-methylaniline) formation, redox behaviour and degradation. A comparison with polyaniline DOI: 10.1016/j.electacta.2013.10.179
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