What absorbs at 1311 cm⁻¹ in an FTIR spectrum?
A band near 1311 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 5 cited sources
Ateb cyflym
A band near 1311 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Aseiniadau grŵp swyddogaethol posibl
| Grŵp swyddogaethol | Ffeithiau ategol | Ffynonellau a ddyfynnwyd | Hyder uchaf |
|---|---|---|---|
| Secondary amine | 2 | 2 | 1.0 |
| Amide | 2 | 2 | 1.0 |
| Alkyl C-H | 1 | 1 | 1.0 |
| N h | 1 | 1 | 1.0 |
| C-O single bond | 1 | 1 | 1.0 |
| Lignin | 1 | 1 | 1.0 |
| Methacrylate | 1 | 1 | 1.0 |
| Ketone | 1 | 1 | 1.0 |
| Ester | 1 | 1 | 1.0 |
| Carboxyl (COOH) | 1 | 1 | 1.0 |
| Carbonyl (C=O) | 1 | 1 | 1.0 |
| Acetate | 1 | 1 | 1.0 |
| C n single bond | 1 | 1 | 1.0 |
Mae'r safle'n adlewyrchu tystiolaeth llenyddiaeth gronnwyd, nid rheol awdurdodol sengl. Cadarnhewch bob amser yn erbyn eich cyd-destun sampl.
Deunyddiau posibl
| Deunydd | Copaon ategol | Grwpiau sy'n gorgyffwrdd | Ffynonellau a ddyfynnwyd |
|---|---|---|---|
| Chitosan | 1311, 1650, 1655 | Alkyl C-H, Amide, N h | 1 |
| polyurethane | 1311, 2270, 1700 | Alkyl C-H, N h, Amide | 1 |
| CaCO3 | 1311, 1141, 712 | Alkyl C-H | 1 |
Mae deunyddiau'n cael eu dangos dim ond pan fydd yr un gronfa lenyddiaeth yn cefnogi'r band hwn ac o leiaf un brig nodweddiadol ychwanegol.
Rhesymeg sbectrwm
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1311 cm⁻¹ is usually not enough for material identification by itself.
Defnydd yn y byd go iawn
Mae'r math hwn o ymholiad yn gyffredin mewn adnabod polymer, sgrinio plastig anhysbys, datrys problemau QC, dilysu deunydd wedi'i ailgylchu, ac adolygiad o aseiniad copa wedi'i gefnogi gan lenyddiaeth.
Camgymeriadau cyffredin
- Trin un band ynysig fel prawf o ddeunydd heb wirio o leiaf un neu ddau gopa cefnogol.
- Anwybyddu gorgyffwrdd: gall grwpiau swyddogaethol lluosog gyfrannu ger yr un rhif ton.
- Hepgor dilysu pan fo ychwanegion, cymysgeddau, ocsideiddio, neu halogiad yn gallu ystumio'r sbectrwm.
Cyngor dilysu
Pan fo amwysedd yn parhau, dilyswch y rhagdybiaeth gyda DSC, GC-MS, neu TGA, yn enwedig ar gyfer cymysgeddau, samplau dirywiedig, a pholymerau llawn.
Llenyddiaeth y tu ôl i'r aseiniadau hyn
-
Amide hyder 1.0
“The C-O-C 𝑐𝑚-1, stretching vibration appears at 1075.12 while the C-N stretches around 1311.35 𝑐𝑚-1 (Timotius et al., 2022).”
Timotius 等 - 2022 - The Study of Methylene Blue Loading into Chitosan- DOI: 10.14716/ijtech.v13i8.6133 -
Acetate hyder 1.0
“Signals obtained at 1311 are assigned to C=O vibration in lignin and at 1361 associated to deformation of C-H group in cellulose and hemicellulose.”
Diego Mendez-Mejias 和 Moya - 2016 - Effects on density, shrinking, color changing and DOI: 10.18671/scifor.v44n112.03 -
C-O single bond hyder 1.0
“Bands at ~1311 1370 and the C-OH (or C-CH) bending mode.”
2D Correlation Spectroscopy (2DCoS) Analysis of Temperature-Dependent FTIR-ATR Spectra in Branched Polyethyleneimine/TEMPO-Oxidized CelluloseNano-Fiber Xerogels DOI: 10.3390/polym13040528 -
hyder 1.0
“A very sharp peaks at 1311 which refers to N-H stretching is observed due to 4+ the complexation with addition of NH 4NO between the NH ions from salt in the BPEs system.”
Shaffie 和 Khiar - 2018 - Characterization of Chitosan-starch Blend Based Bi DOI: 10.1063/1.5041232 -
Alkyl C-H hyder 1.0
“The peaks at around 1311 cm-1 were due to the twisting mode of -CH2, while that at around 1360 cm-1 corresponded to the methylene groups wagging vibrations [3,12,18].”
Fabrication of Aliphatic Water-Soluble Polyurethane Composites with Silane Treated CaCO3 DOI: 10.3390/polym12040747
Oes gennych sbectrwm gyda'r band hwn?
Llwythwch eich sbectrwm FTIR i fyny a chael adroddiad dehongli llawn — aseiniadau brig gyda chyfeiriadau llenyddiaeth, cyfateb llyfrgell, a chadwyn dystiolaeth â gradd hyder — mewn eiliadau.