What absorbs at 1301 cm⁻¹ in an FTIR spectrum?
A band near 1301 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
快速回答
A band near 1301 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能的官能基指派
| 官能基 | 支持事實 | 引用來源 | 最高信心 |
|---|---|---|---|
| Secondary amine | 7 | 7 | 1.0 |
| C n single bond | 6 | 6 | 1.0 |
| Amide | 6 | 6 | 1.0 |
| Alkyl C-H | 3 | 3 | 1.0 |
| Methoxy (OCH3) | 3 | 3 | 1.0 |
| Methacrylate | 3 | 3 | 1.0 |
| C-O single bond | 3 | 3 | 1.0 |
| Acetate | 3 | 3 | 1.0 |
| N h | 3 | 3 | 1.0 |
| Ketone | 1 | 1 | 1.0 |
| Protein | 1 | 1 | 1.0 |
| Carboxyl (COOH) | 1 | 1 | 1.0 |
| Ammonium | 1 | 1 | 1.0 |
排名反映累積的文獻證據,而非單一權威規則。請務必根據您的樣品背景進行確認。
可能的材料
| 材料 | 支持峰 | 重疊基團 | 引用來源 |
|---|---|---|---|
| graphite | 1301, 1640, 1326 | Alkyl C-H | 1 |
| PANI | 1301, 2930, 1300 | Alkyl C-H, Secondary amine, Amide | 1 |
僅當同一文獻庫支援此波段以及至少一個額外特徵峰時,才會顯示材料。
光譜邏輯
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1301 cm⁻¹ is usually not enough for material identification by itself.
實際使用
此類查詢常見於聚合物鑑別、未知塑膠篩選、品管故障排除、再生材料驗證,以及基於文獻的峰值歸屬審查。
常見錯誤
- 將一個孤立的譜帶視為材料的證據,而未檢查至少一兩個支持峰。
- 忽略重疊:多個官能團可能在相同波數附近貢獻。
- 當添加劑、混合物、氧化或污染物可能扭曲譜圖時,跳過驗證。
驗證建議
當仍然存在歧義時,使用DSC、GC-MS或TGA驗證假設,特別是對於混合物、降解樣品和填充聚合物。
這些指派背後的文獻
-
Ammonium 信心 1.0
“The band at 1301 sites,32 been assigned to s(NH 3) coordinated to Lewis acid while (cid:228)”
Pena 等 - 2004 - Identification of surface species on titania-suppo DOI: 10.1021/jp0313122 -
信心 1.0
“confirming (CQN CQC (C-N 0.6Zn 0.4Fe 2O composites that the as-prepared PANI/Ni PANI, 1562 and 1481 and stretching), 1301 4 (N-H C-N stretching),1245 bending and asymmetric stretching of 0.6Zn 0.4Fe 2O particles.”
Controlled synthesis and microwave absorption properties of Ni0.6Zn0.4Fe2O4/PANI composite via an in-situ polymerization process DOI: 10.1016/j.jmmm.2014.10.066 -
Acetate 信心 1.0
“Moreover, a band at 1301 revealed cm-1 C-O stretching, suggesting the possible existence of CaCO 3.”
Assiry 等 - 2023 - Microstructural and Elemental Characterization of DOI: 10.3390/app13074517 -
信心 1.0
“The aromatic cm-1 cm-1, cm-1, amine and carbon-associated peaks were located at 1629 1301 and 1032 , amine and carbon-associated peaks were located at 1629 cm-1, 1301 cm-1, and 1032 cm-1, which indicates the bending vibrations of the C-H bo”
Chelliah 等 - 2023 - Photocatalytic Organic Contaminant Degradation of DOI: 10.3390/separations10030156 -
信心 1.0
“Explicitly assigned as D-peak in text.”
Simultaneous Gene Delivery and Tracking through Preparation of Photo-Luminescent Nanoparticles Based on Graphene Quantum Dots and Chimeric Peptides DOI: 10.1038/s41598-017-09890-y -
Amide 信心 1.0
“at about 1737.1 cm(cid:5)1 cm(cid:5)1 C-N attributed to stretching, the bands from 1300.7 1373.1”
Phytochemical screening, polyphenols, flavonoids and tannin content, antioxidant activities and FTIR characterization of Marrubium vulgare L. from 2 different localities of Northeast of Morocco DOI: 10.1016/j.heliyon.2020.e05609 -
Amide 信心 1.0
“The PANI spectrum shows characteristic peaks from benzenoid rings cm-1, N=Q=N 1494 C-N band of an aromatic amine and vibration (Qquinoid ring) at 1301 and”
Kukulski 等 - 2020 - A Polymeric Composite Material (rGOPANI) for Acid DOI: 10.3390/polym12051051 -
Acetate 信心 1.0
“A combination of the characteristics of CH2 1326,1261 C-O stretching Alkyl Ester 1301 CH Carotenoids and COO group vibrations formed the absorption bands at 1500 cm-1, 1476 cm-1, and 1260 2”
Maher 等 - 2021 - Optimization of Ultrasound-Assisted Extraction of DOI: 10.3390/antiox10101612
有包含此波峰的圖譜嗎?
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