What absorbs at 1262 cm⁻¹ in an FTIR spectrum?
A band near 1262 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Hiter odgovor
A band near 1262 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Možne dodelitve funkcionalnih skupin
| Funkcionalna skupina | Podporna dejstva | Citirani viri | Najvišje zaupanje |
|---|---|---|---|
| C-O single bond | 8 | 7 | 1,0 |
| Methoxy (OCH3) | 7 | 6 | 1,0 |
| Methacrylate | 7 | 6 | 1,0 |
| Acetate | 7 | 6 | 1,0 |
| Secondary amine | 3 | 2 | 1,0 |
| Amide | 3 | 2 | 1,0 |
| Phosphate (PO4) | 2 | 2 | 1,0 |
| C n single bond | 2 | 1 | 1,0 |
| Alkyl C-H | 2 | 1 | 1,0 |
| Hydroxyl (O-H) | 1 | 1 | 1,0 |
| N h | 1 | 1 | 1,0 |
| Lipid | 1 | 1 | 1,0 |
| Carboxyl (COOH) | 1 | 1 | 1,0 |
| Nucleic acid | 1 | 1 | 1,0 |
| Oxygen heterocycle | 1 | 1 | 1,0 |
| Carbohydrate | 1 | 1 | 1,0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 0,9 |
| Methyl | 1 | 0 | 1,0 |
| Silicon carbon | 1 | 0 | 1,0 |
| Silicon (Si) | 1 | 0 | 1,0 |
Razvrstitev odraža zbrane literaturne dokaze, ne enega avtoritativnega pravila. Vedno preverite glede na kontekst vašega vzorca.
Možni materiali
| Material | Podporni vrhovi | Prekrivajoče se skupine | Citirani viri |
|---|---|---|---|
| MWCNTs | 1262, 3396, 1735 | Methacrylate, Acetate, C-O single bond | 1 |
| polyethylene | 1262, 1737, 1720 | Methacrylate, Acetate, Methoxy (OCH3) | 1 |
Materiali so prikazani le, ko ista literaturna podlaga podpira ta pas in vsaj en dodatni karakteristični vrh.
Logika spektra
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1262 cm⁻¹ is usually not enough for material identification by itself.
Uporaba v resničnem svetu
Ta vrsta poizvedbe je pogosta pri identifikaciji polimerov, pregledovanju neznanih plastičnih mas, odpravljanju težav pri QC, preverjanju recikliranih materialov in literaturno podprtem pregledu dodelitev vrhov.
Pogoste napake
- Obravnavanje enega izoliranega pasu kot dokaza o materialu brez preverjanja vsaj enega ali dveh podpornih vrhov.
- Ignoriranje prekrivanja: več funkcionalnih skupin lahko prispeva blizu istega valovnega števila.
- Izpuščanje validacije, ko lahko dodatki, mešanice, oksidacija ali kontaminacija popačijo spekter.
Nasvet za preverjanje
Ko ostaja dvoumnost, potrdite hipotezo z DSC, GC-MS ali TGA, zlasti za mešanice, degradirane vzorce in polnjene polimere.
Literatura za temi dodelitvami
-
Carbohydrate zaupanje 1,0
“The band at 1262 is assigned as -COH in the plane at C-2 and C-3 in cellulose-I and cellulose-II, and it indicates the coexistence of cellulose-I and cellulose-II cm-1 cm-1 in ANFs and RCFs.”
Bian 等 - 2021 - Crystalline Structure Analysis of All-cellulose Na DOI: 10.1007/s10570-017-1259-0 -
Phosphate (PO4) zaupanje 1,0
“Furthermore, the asymmetric stretching vibration band of P-O-P (at 1262 265 initially shifted to a higher wavenumber (1273 cm-1) when the 266 concentration of yttrium is 0.5 mol.”
Bouabdalli 等 - 2023 - First examination of the influence of Y3+ ions on DOI: 10.21203/rs.3.rs-2052185/v1 -
Acetate zaupanje 1,0
“The band at 1262 is attributed to the asymmetric and symmetric stretching vibration of (C-O-C) groups belonging to 2-substituted furan rings.”
Edwards 等 - 2018 - Analysis of chemical polymerization between functi DOI: 10.1590/0104-1428.07016 -
Amide zaupanje 1,0
“stretching of C-N and C=C from acrylic acid at 1262 cm-1.”
Synthesis and in vitro characterizations of porous carboxymethyl cellulose-poly(ethylene oxide) hydrogel film DOI: 10.1186/s40824-015-0033-3 -
C-O single bond zaupanje 1,0
“ester -C-O-C stretch1262, 1255125512601260ing vinyl 1259 1259 1262 1263, 1229 1236 1236 1227 1229 1229 1238 1238”
Mikolaszek 等 - 2022 - Microscopic and Spectroscopic Imaging and Thermal DOI: 10.3390/polym14142888 -
Nucleic acid zaupanje 1,0
“The peak at 1262 ternal (IEL) and external elastic lamina (EEL) that could facilitate acthat corresponds to nucleic acid and lipid content has also been assoconfidence.”
Label-Free Discrimination Analysis of De-Differentiated Vascular Smooth Muscle Cells, Mesenchymal Stem Cells and Their Vascular and Osteogenic Progeny Using Vibrational Spectroscopy DOI: 10.1016/j.bbamcr.2017.11.006 -
Acetate zaupanje 1,0
“In figure 4 (product-B), peak cm-1 C-O value approximately at 1262 corresponds to the stretching mode of bond in the cm-1 32(cid:2) CO group [40].”
Molla 等 - 2022 - Facile extraction and characterization of calcium DOI: 10.1098/rsos.220681 -
Acetate zaupanje 1,0
“• On addition of MWCNTs and further irradiation, appearance of additional peak at cm-1 1262 is observed which belongs to C-O stretching absorption.”
A Multi-Attribute Decision-Making Model for the Selection of Polymer-Based Biomaterial for Orthopedic Industrial Applications DOI: 10.3390/polym14051020
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