What absorbs at 1203 cm⁻¹ in an FTIR spectrum?
A band near 1203 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
빠른 답변
A band near 1203 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
가능한 작용기 할당
| 작용기 | 지원 사실 | 인용 출처 | 최고 신뢰도 |
|---|---|---|---|
| C-O single bond | 8 | 7 | 1.0 |
| Hydroxyl (O-H) | 6 | 6 | 1.0 |
| Methoxy (OCH3) | 6 | 5 | 1.0 |
| Methacrylate | 6 | 5 | 1.0 |
| Acetate | 6 | 5 | 1.0 |
| Alkyl C-H | 3 | 3 | 1.0 |
| Phosphate (PO4) | 3 | 2 | 1.0 |
| C c single bond | 2 | 2 | 1.0 |
| Ring structure | 1 | 1 | 1.0 |
| Alkene (C=C) | 1 | 1 | 1.0 |
| Carbonyl (C=O) | 1 | 1 | 1.0 |
| Ester | 1 | 1 | 1.0 |
| Hydrogen bond | 1 | 1 | 1.0 |
| Phosphorus | 1 | 1 | 1.0 |
| N h | 1 | 1 | 1.0 |
| Carbohydrate | 1 | 1 | 1.0 |
순위는 단일 권위 규칙이 아닌 축적된 문헌 증거를 반영합니다. 항상 샘플 상황에 대해 확인하세요.
가능한 재료
| 재료 | 지원 피크 | 겹치는 그룹 | 인용 출처 |
|---|---|---|---|
| chitosan | 1203, 1650, 1655 | Methacrylate, Hydroxyl (O-H), C-O single bond | 1 |
| Cellulose | 1203, 1735, 1650 | Methacrylate, C-O single bond, Hydroxyl (O-H) | 1 |
| GO | 1203, 1720, 1182 | Methacrylate, Hydroxyl (O-H), C-O single bond | 1 |
| RGO | 1203, 2358, 2930 | Methacrylate, Hydroxyl (O-H), C-O single bond | 1 |
동일한 문헌 풀이 이 밴드와 하나 이상의 추가 특징 피크를 지원하는 경우에만 물질이 표시됩니다.
스펙트럼 로직
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1203 cm⁻¹ is usually not enough for material identification by itself.
실제 사용
이러한 유형의 질의는 고분자 식별, 미지 플라스틱 스크리닝, QC 문제 해결, 재활용 재료 검증 및 문헌 기반 피크 할당 검토에서 일반적입니다.
일반적인 실수
- 하나의 고립된 밴드를 재료의 증거로 취급하고 최소 하나 또는 두 개의 지원 피크를 확인하지 않는 것.
- 겹침 무시: 여러 작용기가 동일한 파수 근처에서 기여할 수 있습니다.
- 첨가제, 혼합물, 산화 또는 오염이 스펙트럼을 왜곡할 수 있는 경우 검증을 건너뜁니다.
검증 조언
모호성이 남아 있는 경우, 특히 혼합물, 분해된 시료 및 충전 폴리머의 경우 DSC, GC-MS 또는 TGA로 가설을 검증하십시오.
이 할당의 배경이 되는 문헌
-
Carbohydrate 신뢰도 1.0
“pennacea In addition, the band at 1203 is associated to oligo FTIR spectra of and corals and polysaccharide with C-O-C, C-O-P, P-O-P symsamples show the presence of chitin.”
Juarez-de la Rosa 等 - 2012 - Effects of thermal treatments on the structure of DOI: 10.1007/s10853-011-5878-9 -
Hydroxyl (O-H) 신뢰도 1.0
“All the bands attributed to 1203cm-1 OH bending at 1455, 1336 and are reduced in inten1035cm-1, related to sity.”
Characterization of depolymerized residues from extremely low acid hydrolysis (ELA) of sugarcane bagasse cellulose: Effects of degree of polymerization, crystallinity and crystallite size on thermal decomposition DOI: 10.1016/j.indcrop.2011.11.009 -
Acetate 신뢰도 1.0
“Moreover, the cm-1 peak at 1203 is due to the C-O-H vibrations.”
Reduced graphene oxide-intercalated graphene oxide nano-hybrid for enhanced photoelectrochemical water reduction DOI: 10.1007/s40097-019-00324-x -
Alkyl C-H 신뢰도 1.0
“The non-polarized FTIR spectrum of the red class depicted an increased absorbance of β-sheet structures (amide I: 1697 and 1634 cm-1) and bands at 1338, 1283, 1238, and 1203 cm-1 attributed to the δ(CH2), δ(CH3), ν(C-N), and δ(N-H) absorpti”
Fourier Transform Infrared Polarization Contrast Imaging Recognizes Proteins Degradation in Lungs upon Metastasis from Breast Cancer DOI: 10.3390/cancers13020162 -
Acetate 신뢰도 1.0
“Additional bands appear at 1203 and 3030 that refer to C-O-H bending and N-H stretching, respectively [15].”
Delgado-Mellado 等 - 2018 - Thermal stability of choline chloride deep eutecti DOI: 10.1016/j.molliq.2018.03.076 -
Phosphate (PO4) 신뢰도 1.0
“The bands at 1203, 1128, 1095, and 880 recorded in FTIR spectra ascribed to the phosphate groups (P=O, -PO 2, -PO 3, and P-O-P, respectively) confirmed the successful cross-linking between CS, MC, and STMP.”
Application of Vibrational Spectroscopic Techniques in the Study of the Natural Polysaccharides and Their Cross-Linking Process DOI: 10.3390/ijms24032630 -
Hydrogen bond 신뢰도 1.0
“The strong absorption of the OH groups linked by hydrogen bonds of the glycosidic ring and the absorption band at 1203 cm-1 suggests the existence cm-1, cm-1, bonds at 3407 -CH, and -CH stretching vibrations at 2901 and C=O and C-C 2 of sul”
Malyar 等 - 2023 - Microfibrillated Cellulose with a Lower Degree of DOI: 10.3390/polym15040904 -
C c single bond 신뢰도 1.0
“C-H stretching vibration of methoxyl group 2926 C=C ring stretch (conjugated) in aromatic 1612 O-H bend of carboxylic acids 1444 C-C stretch in ketones 1342 C-C(O)-C stretch of esters 1203 cm-1 A strong band at 3404 was discovered and assig”
Nwosu 和 Amusat - 2021 - DOI: 10.4152/pea.2021390605
이 밴드가 있는 스펙트럼이 있나요?
FTIR 스펙트럼을 업로드하면 몇 초 안에 전체 해석 보고서(문헌 인용이 포함된 피크 할당, 라이브러리 매칭, 신뢰도 평가 증거 체인)를 받을 수 있습니다.