What absorbs at 1119 cm⁻¹ in an FTIR spectrum?
A band near 1119 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
快速回答
A band near 1119 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能的官能基指派
| 官能基 | 支持事實 | 引用來源 | 最高信心 |
|---|---|---|---|
| Methacrylate | 4 | 4 | 1.0 |
| C-O single bond | 4 | 4 | 1.0 |
| Acetate | 4 | 4 | 1.0 |
| Alkyl C-H | 3 | 3 | 1.0 |
| Methoxy (OCH3) | 3 | 3 | 1.0 |
| Ester | 2 | 2 | 1.0 |
| Carboxyl (COOH) | 2 | 2 | 1.0 |
| N h | 1 | 1 | 1.0 |
| Phosphate (PO4) | 1 | 1 | 1.0 |
| Ketone | 1 | 1 | 1.0 |
| Carbonyl (C=O) | 1 | 1 | 1.0 |
| Amide | 1 | 1 | 1.0 |
| Hydroxyl (O-H) | 1 | 1 | 1.0 |
| Carbonate | 1 | 0 | 0.5 |
排名反映累積的文獻證據,而非單一權威規則。請務必根據您的樣品背景進行確認。
可能的材料
| 材料 | 支持峰 | 重疊基團 | 引用來源 |
|---|---|---|---|
| polypyrrole | 1119, 1700, 400 | Alkyl C-H, Methacrylate, Acetate | 1 |
| silver nanoparticles | 1119, 1636, 1631 | Alkyl C-H, Methacrylate, Acetate | 1 |
| cotton | 1119, 1030, 1638 | Alkyl C-H, Methacrylate, Acetate | 1 |
僅當同一文獻庫支援此波段以及至少一個額外特徵峰時,才會顯示材料。
光譜邏輯
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 1119 cm⁻¹ is usually not enough for material identification by itself.
實際使用
此類查詢常見於聚合物鑑別、未知塑膠篩選、品管故障排除、再生材料驗證,以及基於文獻的峰值歸屬審查。
常見錯誤
- 將一個孤立的譜帶視為材料的證據,而未檢查至少一兩個支持峰。
- 忽略重疊:多個官能團可能在相同波數附近貢獻。
- 當添加劑、混合物、氧化或污染物可能扭曲譜圖時,跳過驗證。
驗證建議
當仍然存在歧義時,使用DSC、GC-MS或TGA驗證假設,特別是對於混合物、降解樣品和填充聚合物。
這些指派背後的文獻
-
C-O single bond 信心 1.0
“5, the TSX spectra showed a C-O-C band at 1156 and a cm-1 small broad peak at 1119 assigned to the C-OH as previously described [35].”
Sangfai 等 - 2015 - Preparation and characterization of kappa-carragee DOI: 10.1007/s00289-015-1360-1 -
Acetate 信心 1.0
“The band at 1119 M cm-1 is due to the C=O stretching modes arising from the absorption of atmospheric CO on the surface of the nanocrystals.”
Photovoltaic and Antimicrobial Potentials of Electrodeposited Copper Nanoparticle DOI: 10.1016/j.bej.2018.10.009 -
Phosphate (PO4) 信心 1.0
“AC 720cm-1 748cm-1are to associated with the stretching vibration of bridging oxygen cm-1 [17,21].The bands at around 790-815 are due to symmetric stretching vibrations of Pcm-1 1012cm-1 O-P rings [22] .The bands lie around at 1000 to are a”
Yaacob 等 - 2018 - Comprehensive study on compositional modification DOI: 10.1016/j.solidstatesciences.2018.05.006 -
Acetate 信心 1.0
“cm-1 cm-1 characteristics for two adjacent bands of 1119 and 1096 attributed to C-O stretching (ester cm-1 cm-1, group) among these oils.”
Han 等 - 2020 - Rapid Classification and Quantification of Camelli DOI: 10.3390/molecules25092036 -
Acetate 信心 1.0
“1020cm-1 corresponded to the functional The band at Similarly, functional groups such as -C-O-O-, -C-O-, 1119cm-1 corregroup C-O;”
Lakshmi 等 - 2015 - Reduction of Silver Ions by Cell Free Extracts of DOI: 10.1155/2015/539494 -
Alkyl C-H 信心 1.0
“The peak assignedto the C-H stretchingvibration in C-O-CH cm-1canbeassignedtotheC-Ostretching vibrationin at1119 Tablet preparation and characterization cm-1”
Formulation and evaluation of primaquine phosphate taste?masked rapidly disintegrating tablet DOI: 10.1211/jpp/60.10.0003 -
Alkyl C-H 信心 1.0
“The band at 1119 is due cm-1 to in-plane C-H bending modes.”
PANI/TiO<sub>2</sub> nanocomposite‐based chemiresistive gas sensor for the detection of <i>E. Coli</i> bacteria DOI: 10.1049/iet-nbt.2020.0046 -
Alkyl C-H 信心 1.0
“deformation vibration is shown by peaks at 1047 The cm(cid:3)1 C-H peak at 1119 is attributed to in and out of plane N-C ]C-H deformations.”
A novel flexible sensor for respiratory monitoring based on in situ polymerization of polypyrrole and polyurethane coating DOI: 10.1039/c7ra08331a
有包含此波峰的圖譜嗎?
上傳您的FTIR圖譜,幾秒內即可獲得完整的解讀報告——包含帶有文獻引用的峰位指派、圖譜庫比對以及信心等級評估的證據鏈。