What absorbs at 814 cm⁻¹ in an FTIR spectrum?
A band near 814 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Brzi odgovor
A band near 814 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Moguće dodjele funkcionalnih skupina
| Funkcionalna skupina | Potporni dokazi | Citirani izvori | Najveća pouzdanost |
|---|---|---|---|
| Methoxy (OCH3) | 2 | 2 | 1,0 |
| Methacrylate | 2 | 2 | 1,0 |
| C-O single bond | 2 | 2 | 1,0 |
| Acetate | 2 | 2 | 1,0 |
| Silicon (Si) | 2 | 2 | 1,0 |
| Alkyl C-H | 2 | 2 | 1,0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 1,0 |
| Alkene (C=C) | 1 | 1 | 1,0 |
| Metal oxygen | 1 | 1 | 1,0 |
| Carboxyl (COOH) | 1 | 1 | 1,0 |
| Silicon carbon | 1 | 0 | 1,0 |
Rangiranje odražava akumulirane literaturne dokaze, a ne jedno autoritativno pravilo. Uvijek provjerite u kontekstu vašeg uzorka.
Mogući materijali
| Materijal | Potporni vrhovi | Preklapajuće skupine | Citirani izvori |
|---|---|---|---|
| TiO2 | 814, 1700, 1093 | Methacrylate, Acetate, C-O single bond | 1 |
| hydrogel | 814, 1632, 1062 | Methacrylate, Acetate | 1 |
| nanocomposite | 814, 2921, 3300 | Methacrylate, Acetate, C-O single bond | 1 |
| copolymer | 814, 2921, 1540 | Methacrylate, Acetate | 1 |
| silver nanoparticles | 814, 1636, 1631 | Methacrylate, Acetate, C-O single bond | 1 |
Materijali su prikazani samo kada ista literatura podržava ovu traku i barem jedan dodatni karakteristični vrh.
Logika spektra
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 814 cm⁻¹ is usually not enough for material identification by itself.
Upotreba u stvarnom svijetu
Ova vrsta upita uobičajena je u identifikaciji polimera, probiru nepoznate plastike, rješavanju problema u kontroli kvalitete, provjeri recikliranog materijala i pregledu dodjele vrhova potkrijepljenom literaturom.
Uobičajene pogreške
- Tretiranje jedne izolirane vrpce kao dokaza materijala bez provjere barem jednog ili dva podržavajuća pika.
- Zanemarivanje preklapanja: više funkcionalnih skupina može doprinositi u blizini istog valnog broja.
- Preskakanje validacije kada aditivi, mješavine, oksidacija ili kontaminacija mogu izobličiti spektar.
Savjet za provjeru
Kada nejasnoća ostane, validirajte hipotezu pomoću DSC, GC-MS ili TGA, posebno za mješavine, degradirane uzorke i punjene polimere.
Literatura iza ovih dodjela
-
Alkyl C-H pouzdanost 1,0
“Meanwhile, the peak of 1160.83 is the fingerprint for stretching the C-O ester At the same time, cm-1 the peak of 813.54 represents the alkane group's fingerprints.”
Synthesis of magnetic nanocarbon using palm oil as the green precursor via microwave-assisted arc for wastewater treatment DOI: 10.1038/s41598-022-21982-y -
Carboxyl (COOH) pouzdanost 1,0
“9 depicts the two possible pathways of formic acid of the H 2BDC Raman ring breathing doublet bands at 814 and cm(cid:3)1”
Embrechts 等 - 2020 - In situ Raman and FTIR spectroscopic study on the DOI: 10.1039/c9ra09968a -
Silicon (Si) pouzdanost 1,0
“cm(cid:4)1 fluorescence (SieO (OeSieO suggests that blueberry extract produces a phenombands at 999 stretching) and 814 enon in clay samples, thus limiting the detection of the spectra asymmetric stretching) due to changes in the Si environ”
Nano-clays from natural and modified montmorillonite with and without added blueberry extract for active and intelligent food nanopackaging materials DOI: 10.1016/j.matchemphys.2017.03.052 -
pouzdanost 1,0
“The peaks at 814 and 473 cm-1 are attributed to the amorphous Al-O stretching vibration cm-1 The peaks at 814 and 473 are attributed to the amorphous Al-O stretching vibration and Si-O-Si flexion, respectively [12].”
Metakaolin-Based Geopolymer with Added TiO2 Particles: Physicomechanical Characteristics DOI: 10.3390/coatings7120233 -
Acetate pouzdanost 1,0
“at 2927 and 1448 (CH2 group) meanwhile the tea tree at 3340 Biotersus spectra show these common bands 2920 (CH2 asymmetric bending), 1452 (CH2 bending), 2047, cm-1 1255 (C-O stretching vibration), 814 (CH), and 658 while YOCOCOIL shows band”
In-Situ Comparative Study of Eucalyptus, Basil, Cloves, Thyme, Pine Tree, and Tea Tree Essential Oil Biocide Efficacy DOI: 10.3390/mps5030037 -
Alkene (C=C) pouzdanost 1,0
“This process is also confirmed cm-1 cm-1 (d [bands at 814 and 936 =C-H), at 1650 by the lack of such a peak in the case of copolymers cm-1 (m (m C=C) and at 3105 =C-H)], aldehydes, especially”
Synthesis and thermal properties of parent and modified DMN–co-GMA copolymers DOI: 10.1007/s10973-018-7162-6 -
Silicon-oxygen (Si-O) pouzdanost 1,0
“Addicm-1 bands at 3400 and 1637 are due to the O-H group on the surface of nano-SiO 2, and tionally, the bands at 471 cm-1 and 814 cm-1 in nano-SiO2 spectrum represent Si-O bending”
Preparation and Characterization of Novel Microgels Containing Nano-SiO2 and Copolymeric Hydrogel Based on Poly (Acrylamide) and Poly (Acrylic Acid): Morphological, Structural and Swelling Studies DOI: 10.3390/ma15144782 -
Acetate pouzdanost 1,0
“The presence of sulfate in both samples is confirmed by the bands at 1249, 1035, and 814 cm-1, which correspond to the vibrations of asymmetric S = O stretching, symmetric C-O associated with a C-O-SO group, and C-O-S of the sulfate groups”
Silver Nanoparticles Containing Fucoidan Synthesized by Green Method Have Anti-Trypanosoma cruzi Activity DOI: 10.3390/nano12122059
Imate li spektar s ovom vrpcom?
Prenesite svoj FTIR spektar i dobijte potpuno izvješće o interpretaciji — dodjele vrhova s literaturnim citatima, podudaranja knjižnice i lanac dokaza s ocjenom pouzdanosti — u sekundama.