What absorbs at 706 cm⁻¹ in an FTIR spectrum?
A band near 706 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 8 cited sources
Réponse rapide
A band near 706 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Attributions possibles de groupes fonctionnels
| Groupe fonctionnel | Faits à l＇appui | Sources citées | Confiance maximale |
|---|---|---|---|
| Metal oxygen | 3 | 3 | 1,0 |
| Amide | 2 | 2 | 1,0 |
| Methacrylate | 1 | 1 | 1,0 |
| Ketone | 1 | 1 | 1,0 |
| Ester | 1 | 1 | 1,0 |
| Carboxyl (COOH) | 1 | 1 | 1,0 |
| Carbonyl (C=O) | 1 | 1 | 1,0 |
| Acetate | 1 | 1 | 1,0 |
| Silicon (Si) | 1 | 1 | 1,0 |
| Alkyl C-H | 1 | 1 | 1,0 |
| Borate | 1 | 1 | 1,0 |
| Carbonate | 1 | 1 | 0,9 |
| Boron nitrogen | 1 | 0 | 0,9 |
Le classement reflète les preuves bibliographiques accumulées, et non une règle faisant autorité. Confirmez toujours dans le contexte de votre échantillon.
Matériaux possibles
| Matériel | Pics de support | Groupes chevauchants | Sources citées |
|---|---|---|---|
| AuNPs | 706, 1646, 1721 | Amide, Methacrylate | 1 |
| nanocomposite | 706, 2921, 3300 | Methacrylate, Metal oxygen | 1 |
| cellulose | 706, 1735, 1650 | Methacrylate, Amide | 1 |
| biochar | 706, 1640, 1115 | Methacrylate | 1 |
| wood | 706, 1740, 1730 | Methacrylate | 1 |
| calcite | 706, 2850, 2864 | Methacrylate, Amide | 1 |
Les matériaux sont affichés uniquement lorsque le même ensemble de littérature soutient cette bande et au moins un pic caractéristique supplémentaire.
Logique du spectre
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 706 cm⁻¹ is usually not enough for material identification by itself.
Utilisation réelle
Ce type de requête est courant dans l＇identification des polymères, le criblage des plastiques inconnus, le dépannage du contrôle qualité, la vérification des matériaux recyclés et l＇examen de l＇attribution des pics appuyée par la littérature.
Erreurs courantes
- Traiter une bande isolée comme preuve d＇un matériau sans vérifier au moins un ou deux pics de support.
- Ignorer le chevauchement : plusieurs groupes fonctionnels peuvent contribuer près du même nombre d＇onde.
- Sauter la validation lorsque des additifs, des mélanges, l＇oxydation ou la contamination peuvent déformer le spectre.
Conseil de vérification
Lorsque l＇ambiguïté persiste, validez l＇hypothèse avec DSC, GC-MS ou TGA, en particulier pour les mélanges, les échantillons dégradés et les polymères chargés.
Bibliographie derrière ces attributions
-
confiance 1,0
“The FT-IR cm-1 spectrum showed a broad peak at 706 due to Ti-O”
Anjum 等 - 2023 - Photocatalytic degradation of reactive violet 1 by DOI: 10.30955/gnj.004281 -
Borate confiance 1,0
“The absorption band [8], 706cm-1 is assigned to B-O-B bending vibration, the at (cid:5) Bexp(cid:4) cm-1 is due to the stretching band between 1100 and 800 hν , α (ν) = 4]- [BO (3) tetrahedral borons and broad absorption modes of (cid:2)E c”
Kolavekar 等 - 2017 - Characterization and optical properties of Pr2O3-d DOI: 10.1007/s12034-017-1400-6 -
Amide confiance 1,0
“FTIR spectra of CNF/AuNPs/anti-colistin Ab, and exhibited Validation study cm-1, cm-1, cm-1 transmittance peaks at 706 1246 and 1514 corresponding to amide IV, due to presence of OCN banding;”
Kumar 等 - 2022 - Electrochemical immunosensor for the detection of DOI: 10.1007/s13205-022-03252-w -
Alkyl C-H confiance 1,0
“The peak at 706 is assigned to alkyl bendbiochars from unmixed substrates at 650 °C are more stabi-”
Biochar from co-pyrolysis of urban organic wastes—investigation of carbon sink potential using ATR-FTIR and TGA DOI: 10.1007/s13399-020-01000-9 -
Silicon (Si) confiance 1,0
“cm-1 symmetric stretching vibrations of inner Si/Al-O structure, respectively), 1180 and ZY characteristic peaks were found at 1050 cm-1 and 706 cm-1 (asymmetric and sym4 cm-1 788 (asymmetric and symmetric stretching vibrations of external”
Novel Biocomposite Films Based on High Methoxyl Pectin Reinforced with Zeolite Y for Food Packaging Applications DOI: 10.3390/foods11030360 -
Acetate confiance 1,0
“The band at 1,706 cm-1 is ascribed to the stretching vibration C=O, wavenumber of 3460 [47,48].”
Xu 等 - 2019 - New Perspective on Wood Thermal Modification Rele DOI: 10.3390/polym11071145 -
Metal oxygen confiance 0,9
“attributed to Ag-O stretching vibration”
Al-Qahtani 等 - 2022 - Structural, morphological, optical and electrochem DOI: 10.15251/JOR.2022.182.187 -
Carbonate confiance 0,9
“V4 mode of calcite”
Loy 等 - 2016 - Effects of Calcination on the Crystallography and DOI: 10.1155/2016/2914368
Avez-vous un spectre avec cette bande ?
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