What absorbs at 492 cm⁻¹ in an FTIR spectrum?
A band near 492 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 5 cited sources
Quick answer
A band near 492 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
Possíveis atribuições de grupos funcionais
| Grupo funcional | Fatos de suporte | Fontes citadas | Maior confiança |
|---|---|---|---|
| Metal oxygen | 1 | 1 | 1,0 |
| S s | 1 | 1 | 1,0 |
| Methoxy (OCH3) | 1 | 1 | 1,0 |
| Methacrylate | 1 | 1 | 1,0 |
| Acetate | 1 | 1 | 1,0 |
| C-O single bond | 1 | 1 | 1,0 |
| C c single bond | 1 | 1 | 1,0 |
| Hydroxyl (O-H) | 1 | 1 | 1,0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 1,0 |
A classificação reflete a evidência acumulada da literatura, não uma única regra autoritária. Sempre confirme com o contexto da sua amostra.
Possible materials
| Material | Picos de suporte | Overlapping groups | Fontes citadas |
|---|---|---|---|
| magnetite | 492, 1740, 1263 | Metal oxygen, Methacrylate, Methoxy (OCH3) | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 492 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
Literatura por trás destas atribuições
-
Silicon-oxygen (Si-O) confiança 1,0
“The studied quartz was detected with bands at 460.90 cm-1, 491.73 cm-1, 773.68 cm-1, and 1071.43 cm-1.”
Fawzy - 2021 - Separation of fine beryl from quartz via magnetic DOI: 10.37190/ppmp/132329 -
Hydroxyl (O-H) confiança 1,0
“The broad bands at around 3,416, 1,619, 1,181 cm-1 and 492 are the results of the stretching vibration of -OH, C¼C C¼O, C-C C-O S-S or or and functionalities, respectively.”
Liu 等 - 2018 - Preparation, adsorptive properties and chemical re DOI: 10.2166/wh.2018.068 -
confiança 1,0
“As shown in Figure 9, the peaks at 505 cm-1 and 492 cm-1 correspond to the vibration cm-1 cm-1 As shown in Figure 9, the peaks at 505 and 492 correspond to the vibration of of Fe-O bonds [51], which further confirmed the successful loading”
Adsorption Characteristics of Heavy Metals Pb2+ and Zn2+ by Magnetic Biochar Obtained from Modified AMD Sludge DOI: 10.3390/toxics11070590 -
confiança 0,9
“Explicit assignment in text”
Molecular and biological activities of metal oxide-modified bioactive glass DOI: 10.1038/s41598-023-37017-z -
confiança 0,6
“Raman spectrum peak assigned to heterolytic rupture of AlCl oligomers”
Understanding the molecular structure of the elastic and thermoreversible AlCl3:urea/polyethylene oxide gel electrolyte DOI: 10.1002/cssc.202001557
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