What absorbs at 418 cm⁻¹ in an FTIR spectrum?
A band near 418 cm⁻¹ can point to several functional groups. Below are the most likely assignments, ranked by how much published evidence supports each — every one traceable to literature (DOI) and cross-validated against our 130,000+ reference spectra and knowledge graph.
Backed by 7 cited sources
Quick answer
A band near 418 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.
可能的官能团归属
| 官能团 | 支持性事实 | 引用来源 | 最高置信度 |
|---|---|---|---|
| Metal oxygen | 2 | 2 | 1.0 |
| Methacrylate | 1 | 1 | 1.0 |
| Ketone | 1 | 1 | 1.0 |
| Ester | 1 | 1 | 1.0 |
| Carboxyl (COOH) | 1 | 1 | 1.0 |
| Carbonyl (C=O) | 1 | 1 | 1.0 |
| Amide | 1 | 1 | 1.0 |
| Acetate | 1 | 1 | 1.0 |
| Siloxane (Si-O-Si) | 1 | 1 | 1.0 |
| Silicon-oxygen (Si-O) | 1 | 1 | 1.0 |
| Lignin | 1 | 1 | 1.0 |
| Ring structure | 1 | 1 | 1.0 |
排名反映了累积的文献证据，而非单一的权威规则。请始终对照您的样品背景进行确认。
Possible materials
| 材料 | 支持峰 | Overlapping groups | 引用来源 |
|---|---|---|---|
| ZnO NPs | 418, 1664, 875 | Metal oxygen, Methacrylate | 1 |
Materials are shown only when the same literature pool supports this band and at least one additional characteristic peak.
Spectrum logic
This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 418 cm⁻¹ is usually not enough for material identification by itself.
Real-world usage
This type of query is common in polymer identification, unknown plastic screening, QC troubleshooting, recycled-material verification, and literature-backed peak assignment review.
Common mistakes
- Treating one isolated band as proof of a material without checking at least one or two supporting peaks.
- Ignoring overlap: multiple functional groups can contribute near the same wavenumber.
- Skipping validation when additives, blends, oxidation, or contamination may distort the spectrum.
Verification advice
When ambiguity remains, validate the hypothesis with DSC, GC-MS, or TGA, especially for blends, degraded samples, and filled polymers.
这些分配背后的文献
-
Metal oxygen 置信度 1.0
“LLM confirmed rule peak-group candidate”
Green Fabrication of Copper Oxide Nanoparticles: A Comparative Antibacterial Study Against Gram-Positive and Gram-Negative Bacteria DOI: 10.1007/s13369-021-05767-5 -
Ring structure 置信度 1.0
“To each of these solutions cm(cid:0) 1 the band at 418 is due to out-of-plane vibrations of the ring of the PANIDSC@Cr, (previously adsorbed, washed, and dried) was added.”
Efficient removal of Cr(VI) by polyaniline modified biochar from date (Phoenix dactylifera) seed DOI: 10.1016/j.gsd.2021.100653 -
置信度 1.0
“Peak at 418 Infrared Spectra (FTIR) corresponds to Zn-O stretching which confirm the formation of ZnO nanoparticles.”
Vindhya 等 - 2019 - Dielectric properties of Zinc Oxide Nanoparticles DOI: 10.1063/1.5093888 -
Lignin 置信度 1.0
“The weak peak at approximately 418 °C was attributed to the further depolymerization of lignin and secondary reactions induced by lignin.”
Hu 等 - 2021 - Pyrolytic Characteristics and Kinetics of Guanzhon DOI: 10.1016/j.fuel.2014.01.014 -
置信度 1.0
“347 displayed by hexagonal birnessite were shifted upward by ~160 Specifically, the three cm-1 348 calculated high-intensity peaks at 559, 611, and 642 (Table 6) of the triclinic birnessite-like 349 nanocluster (Mn 7O 24H 22), labeled T1, T”
Fourier-transform infrared spectroscopy (FTIR) analysis of triclinic and hexagonal birnessites DOI: 10.1017/CBO9781107415324.004 -
置信度 1.0
“Another confirmation of the pozzolan 416 cm-1, reaction for all proportions is the diminution in intensity of the band at 1035 417 associated with the vibrations of asymmetric stretching of Si - O - Si and Si - O - Al, 418 cm-1, and the app”
Moraes 等 - 2019 - Production of bamboo leaf ash by auto-combustion f DOI: 10.1016/j.conbuildmat.2019.03.007 -
Acetate 置信度 1.0
“The peaks at 1743 1161 1034 and 851 can be 418 related to (-C=O) stretch, (-C-O) stretch;”
Rasul 等 - 2022 - Development of antimicrobialantioxidant nanocompo DOI: 10.21203/rs.3.rs-337479/v1
是否有此波段的光谱？
上传您的FTIR光谱，几秒钟内即可获得完整的解读报告——包含带文献引用的峰分配、库匹配和带有置信度评级的证据链。