What absorbs at 3107 cm⁻¹ in an FTIR spectrum?

Ātra atbilde

A band near 3107 cm⁻¹ is usually interpreted by checking which functional groups repeatedly co-occur there in the literature, then confirming at least one or two additional peaks in the same sample. This page ranks those assignments by accumulated evidence rather than by a single fixed textbook rule.

Iespējamie funkcionālo grupu piešķīrumi

Rangs atspoguļo uzkrātos literatūras pierādījumus, nevis vienu autoritatīvu noteikumu. Vienmēr apstipriniet atbilstoši parauga kontekstam.

Iespējamie materiāli

Materiāli tiek parādīti tikai tad, ja šo joslu un vismaz vienu papildu raksturīgo pīķi atbalsta tā pati literatūras kopa.

Spektra loģika

This band becomes meaningful only when read with its neighboring peaks. In practice, analysts first look at the assignments above, then check whether the same sample also shows other peaks expected for the same structural motif. A lone band near 3107 cm⁻¹ is usually not enough for material identification by itself.

Reālās pasaules izmantošana

Šāda veida vaicājums ir izplatīts polimēru identificēšanā, nezināmas plastmasas skrīningā, kvalitātes kontroles problēmu risināšanā, pārstrādāto materiālu pārbaudē un ar literatūru pamatotā pīķu piešķīruma pārskatā.

Biežākās kļūdas

• Vienas izolētas joslas uzskatīšana par materiāla pierādījumu, nepārbaudot vismaz vienu vai divus atbalsta pīķus.
• Ignorējot pārklāšanos: vairākas funkcionālās grupas var dot ieguldījumu tuvu tam pašam viļņa skaitlim.
• Izlaist validāciju, ja piedevas, maisījumi, oksidācija vai piesārņojums var izkropļot spektru.

Verifikācijas padoms

Ja joprojām pastāv neskaidrība, apstipriniet hipotēzi ar DSC, GC-MS vai TGA, īpaši maisījumiem, noārdītiem paraugiem un pildītiem polimēriem.

Literatūra aiz šiem piešķīrumiem

• N-O bond pārliecība 1,0

  “cm-1, 3085.4 For diamonds with no milky features, ~76% of them showed the peak at 3107 cm-1, while only ~8% showed a very weak peak at 3085.4 which is absent in the rest of the 23”

  Gu 和 Wang - 2018 - Optical defects in milky type IaB diamonds DOI: 10.1016/j.diamond.2018.09.010
• pārliecība 1,0

  “4), values very rarely observed globally but Hydrogen impurities in diamond are indicated by an infrared 3107cm-1, absorption peak at characteristic for so-called Group B (high-Ca eclogitic) diamonds attributed to stretching vibrations of”

  The micro-/macro-diamond relationship: A case study from the Artemisia kimberlite (Northern Slave Craton, Canada) DOI: 10.1016/j.lithos.2012.05.031
• pārliecība 1,0

  “cm-1 3.3 Hydrogen-related infrared absorption peak at 3107 cm-1 The hydrogen-related infrared absorption peak at 3107 has been assigned to the structure of three nitrogen atoms and a hydrogen atom surrounding a vacancy (VN 3H) [24].”

  Lai 等 - 2020 - Spectroscopic features of natural and HPHT-treated DOI: 10.1016/j.diamond.2019.107642
• Alkyl C-H pārliecība 1,0

  “2808-2806 C-H in CH3 stretching 3107 3109-3123 C-H aromatic stretching The main changes observed in Figure 4, as a consequence of the reaction of AZA with”

  Photodegradation of Azathioprine in the Presence of Sodium Thiosulfate DOI: 10.3390/ijms23073975
• Alkyl C-H pārliecība 1,0

  “The absorption peaks at gen impurity at 2850, 2920 and 3107 cm-1 sp3-CH 2are responsible for anti-symmetric vi2850 and 2920 sp3-CH 2symmetric vibrations in diamond, respectively brations and Fig.7.ThetypicalFTIRrecordedforthesynthesizeddiam”

  Yan 等 - 2016 - The effect of phosphorus and nitrogen co-doped on DOI: 10.1016/j.ijrmhm.2015.08.009
• C-S single bond pārliecība 1,0

  “υ(HC=N) γ(HC=N) υ(C=N) C-S-C C-O υH2O cm-1 The two bands at 3107, 3103, 3085, and 3100 and at 2979, 2984, 2974, and Compounds υ(Ln-S) υ(Ln-N) Imine Imine Thiazole Thiazole Furane Lattice cm-1 2986 are due to the asymmetric and symmetric str”

  Synthesis, Characterization and Biological Activities of New Schiff Base Compound and Its Lanthanide Complexes DOI: 10.3390/ph15040454
• Alkyl C-H pārliecība 1,0

  “and measuring in one place necessarily includes other cm-1 The peak at 3107 related to C-H vibrations is detected in most of the samples studied.”

  Mashkovtsev 等 - 2021 - Specific spectroscopic features of yellow cuboid d DOI: 10.3190/jgeosci.323
• Alkyl C-H pārliecība 1,0

  “The height (or area) of the band at 3107 cm-1, 58 considered as the major absorption band and related to a C-H bond in the N 3VH defect 59 [23,24], is used to estimate if a diamond is "H rich" [25].”

  Combination of ERDA, FTIR spectroscopy and NanoSIMS for the characterization of hydrogen incorporation in natural diamonds DOI: 10.1016/j.diamond.2023.110007